公开(公告)号：US5605985A

公开(公告)日：1997-02-25

申请号：US256891

申请日：1994-08-10

申请人： Josef Rademacher ,  Udo Reiter ,  Peter Lessmeister

发明人： Josef Rademacher ,  Udo Reiter ,  Peter Lessmeister

IPC分类号： C08G59/18 ,  C08G59/62 ,  C09D5/03 ,  C09D163/00 ,  C08F283/00 ,  C08G8/28 ,  C08L61/00

CPC分类号： C09D163/00 ,  Y10S525/934 ,  Y10T428/31511 ,  Y10T428/31529

摘要： The present invention relates to a powder coating, in particular for internal coating of packaging containers, which is characterized in that it1.) comprises at least one epoxy resin having an epoxide equivalent weight of from 300 to 5500 and at least one hardener having more than one phenolic hydroxyl group per molecule and a hydroxyl equivalent weight, based on the phenolic OH groups, of from 100 to 500, and2.) has a particle size distribution such that at least 90 percent by weight of the powder coating particles have a particle size of between 1 and 60 .mu.m, the maximum particle size of the powder coating particles is .ltoreq.100 .mu.m, the mean particle size of the powder coating particles is between 5 and 20 .mu.m and the gradient of the particle distribution curve at the point of inflexion is .gtoreq.100.

摘要翻译： PCT No.PCT / EP93 / 00243 Sec。 371日期：1994年8月10日 102（e）日期1994年8月10日PCT提交1993年2月3日PCT公布。 第WO93 / 16141号公报 日期：1993年8月19日本发明涉及一种粉末涂料，特别是用于包装容器的内部涂层，其特征在于：1）包含至少一种环氧树脂，其环氧当量为300至5500， 至少一种每分子具有多于一个酚羟基的固化剂和基于酚OH基团的羟基当量为100至500和2.）具有使得至少90重量％ 粉末涂料颗粒的粒度为1〜60μm，粉末涂料颗粒的最大粒径为100μm，粉末涂料颗粒的平均粒径为5〜20μm， 拐点处的粒子分布曲线的梯度为> / = 100。

公开(公告)号：US5451305A

公开(公告)日：1995-09-19

申请号：US955703

申请日：1994-02-09

申请人： Gunther Ott ,  Udo Reiter ,  Walter Jouck

发明人： Gunther Ott ,  Udo Reiter ,  Walter Jouck

IPC分类号： C08G18/80 ,  C09D5/44 ,  C25D13/10

CPC分类号： C08G18/8064 ,  C08G18/8009 ,  C09D5/4496

摘要： The invention relates to a cathodic electro-dipping process wherein the electro-dipping primer employed contains a crosslinking agent which can be obtained by reactinga) a diol and/or a triol or a mixture of diols and/or a mixture of triols,b) diphenylmethane 4,4'-diisocyanate the melting point of which has been depressed, by partial reaction with a monool and/or polyol or a mixture of monools and/or a mixture of polyols, so far that it is liquid at room temperature andc) a masking agent or a mixture of masking agentsto give a crosslinking agent which is free from isocyanate groups.

摘要翻译： PCT No.PCT / EP91 / 01012 Sec。 371日期1994年2月9日 102（e）1994年2月9日PCT PCT 1991年5月31日PCT公布。 出版物WO92 / 00358 日本1992年1月9日。本发明涉及一种阴极电浸法，其中所用的电浸渍底物含有交联剂，其可通过使a）二醇和/或三醇或二醇和/ 或三醇的混合物，b）二苯基甲烷4,4'-二异氰酸酯，其熔点已经被抑制，通过与一元醇和/或多元醇或单醇和/或多元醇的混合物的混合物的部分反应，至目前为止 在室温下为液体，c）掩蔽剂或掩蔽剂混合物，得到不含异氰酸酯基团的交联剂。

公开(公告)号：US5262465A

公开(公告)日：1993-11-16

申请号：US777339

申请日：1991-12-11

申请人： Gunther Ott ,  Ulrich Heimann ,  David J. Santure ,  Udo Reiter

发明人： Gunther Ott ,  Ulrich Heimann ,  David J. Santure ,  Udo Reiter

IPC分类号： C08G18/58 ,  C08G18/10 ,  C08G59/14 ,  C08G59/40 ,  C09D5/44 ,  C09D163/00 ,  C09D175/00 ,  C08L63/02

CPC分类号： C09D5/4434 ,  C08G18/10 ,  C09D163/00

摘要： The invention relates to a cathodic electro-dipcoating process, wherein the electro-dipcoating composition used contains a cationic, amine-modified epoxy resin, which is obtainable by reacting(A) a polyepoxide,(B) an amine and(C) an adduct, which is obtainable by . . . (sic)(c1) a polyether- or polyester-polyol,(c2) a polyisocyanate and(c3) a compound which contains at least one hydrogen atom which is reactive towards isocyanate groups and at least one ketimine group in the molecule, and/or(D) a hydrolysis product of (C)with one another in a relative proportion such that 20 to 90% of the epoxy groups of component (A) are reacted with component (B) and the remaining epoxy groups are reacted with component (C) and/or (D), and--if still necessary--at least partially protonating the reaction product thus obtained.

摘要翻译： PCT No.PCT / EP90 / 00843 Sec。 371日期1991年12月11日 102（e）日期1991年12月11日PCT 1990年5月25日PCT PCT。 出版物WO90 / 15108 日本1990年12月13日。本发明涉及一种阴极电沉积工艺，其中所用的电沉积涂料组合物含有阳离子胺改性环氧树脂，其可通过使（A）聚环氧化物，（B） 胺和（C）加合物，其可通过以下方式获得。 。 。 （c1）（c1）聚醚或聚酯多元醇，（c2）多异氰酸酯和（c3）含有至少一个对分子中的异氰酸酯基团和至少一个酮亚胺基具有反应性的氢原子的化合物和/ 或（D）（C）的水解产物相对比例使得组分（A）的20-90％的环氧基与组分（B）反应，剩余的环氧基与组分（ C）和/或（D），以及 - 如果仍然是必要的 - 至少部分质子化由此获得的反应产物。

公开(公告)号：US4997865A

公开(公告)日：1991-03-05

申请号：US327964

申请日：1989-02-14

申请人： Karl-Heinz Scherping ,  Hans-Jorg Holscher ,  Uwe Reichelt ,  Udo Reiter

发明人： Karl-Heinz Scherping ,  Hans-Jorg Holscher ,  Uwe Reichelt ,  Udo Reiter

IPC分类号： C09D151/08 ,  C08F283/10 ,  C09D4/06 ,  C09D5/02 ,  C09D155/00 ,  C09D163/00 ,  C09D163/10 ,  C09D167/00 ,  C09D167/08

CPC分类号： C08F283/10 ,  C09D4/06

摘要： The invention relates to an aqueous coating agent, obtained from an epoxy resin, ethylenically unsaturated monomers, some of which contain carboxyl groups, a peroxide initiator in a proportion of at least 2% by weight, relative to the total weight of the monomers, a crosslinking agent, a neutralizing agent, organic solvents, and, if appropriate, further conventional additives, such as plasticizers, stabilizers, wetting agents, dispersion auxiliaries, catalysts and pigments. The coating agent is based on a binder (a) which is obtainable from(A) 20 to 80% by weight of an epoxy resin having an average of more than one epoxy group per molecule and having an average molecular weight of at least 500,(B) 1 to 60% by weight of polyester polycarboxylic acids having an average molecular weight of 500 to 5,000 and having an acid number of 30 to 150, and(C) 10 to 50% by weight of ethylenically unsaturated monomers, 10 to 50% by weight of the monomers containing carboxyl groups,where the sum of (A), (B) and (C) is 100% by weight, the binder (a) has an acid number of 20 to 150, and the crosslinking agents (b) used are phenolic and/or amino resins, with the proviso that the coating agent contains(a) 30 to 70% by weight of the binder (a),(b) 2 to 30% by weight, preferably 5 to 16% by weight, of the crosslinking agent (b),(c) 1 to 7% by weight, preferably 2 to 5% by weight, of ammonia and/or amine as neutralizing agent, and(d) 20 to 60% by weight of organic solvents,where the sum of (a), (b), (c) and (d) is 100% by weight. The present invention also relates to a process for the preparation of the coating agents, and the use thereof for coating of cans.

公开(公告)号：US4429072A

公开(公告)日：1984-01-31

申请号：US419494

申请日：1982-09-17

申请人： Udo Reiter ,  Helmut Lehmann

发明人： Udo Reiter ,  Helmut Lehmann

IPC分类号： C08G73/00 ,  C08G73/16 ,  C09D5/25 ,  C09D179/08 ,  H01B3/30 ,  B32B15/00 ,  C09D3/64 ,  H01B3/42

CPC分类号： C08G73/16 ,  H01B3/306 ,  H01B3/308 ,  Y10T428/31681

摘要： A process for the preparation of aqueous thermosetting electrical insulating varnishes, wherein polyester-imide precondensates are prepared by condensing aromatic tricarboxylic acid monoanhydrides, diamines, diols, triols containing an isocyanurate ring, and cyclic trimerization products of diisocyanates, whose free isocyanate groups are blocked, with or without aromatic dicarboxylic acids or their esterifiable derivatives, and are reacted, at from 50.degree. to 200.degree. C., with or without addition of from 1 to 10% by weight, based on polyester-imide, of a polar organic solvent, with ammonia or an organic amine, and then diluted with fully demineralized water, with or without addition of a water-soluble curing catalyst. The novel electrical insulating varnishes are used as wire enamels or impregnating varnishes.

摘要翻译： 一种制备水性热固性电绝缘清漆的方法，其中聚酰亚胺预缩合物是通过使芳族三羧酸一酸酐，二胺，二醇，含有异氰脲酸酯环的三醇缩合而得到的，并且游离异氰酸酯基被封闭的二异氰酸酯的环状三聚产物， 具有或不具有芳族二羧酸或其可酯化的衍生物，并且在50℃至200℃下，加入或不加入1-10重量％的基于聚酯 - 酰亚胺的极性有机溶剂， 用氨或有机胺，然后用完全软化水稀释，加入或不加入水溶性固化催化剂。 新型电绝缘清漆用作线釉或浸渍清漆。

公开(公告)号：US4384061A

公开(公告)日：1983-05-17

申请号：US304269

申请日：1981-09-21

申请人： Udo Reiter ,  Helmut Lehmann ,  Walter Disteldorf ,  Hans-Uwe Schenck

发明人： Udo Reiter ,  Helmut Lehmann ,  Walter Disteldorf ,  Hans-Uwe Schenck

IPC分类号： C08G73/00 ,  C08G73/10 ,  C08G73/14 ,  C09D5/25 ,  H01B3/30 ,  C08K5/34 ,  C08L79/08

CPC分类号： C08G73/1053 ,  Y10S525/926 ,  Y10S525/928 ,  Y10T428/2938 ,  Y10T428/294

摘要： Thermosetting polycondensates containing amide and imide groups which are obtained by reacting 1,2,3,4-butanetetracarboxylic acid or its anhydride with one or more aliphatic, cycloaliphatic or aromatic diamines and one or more oxadicarboxylic acids or oxadicarboxylic acid esters of the general formulaROOC--CH.sub.2 --O--(CH.sub.2).sub.2 --O--.sub.n CH.sub.2 --COORwhere R is hydrogen or alkyl of 1 to 6 carbon atoms and n is 0 or an integer from 1 to 10, in a water-soluble organic solvent and/or water, at from 80.degree. to 200.degree. C. These polycondensates are useful as wire enamels, impregnating agents and adhesives.

摘要翻译： 通过使1,2,3,4-丁烷四羧酸或其酸酐与一种或多种脂族，脂环族或芳族二胺和一种或多种通式为ROOC的氧化二羧酸或氧化二羧酸酯反应得到的含有酰胺和酰亚胺基团的热固性缩聚物 -CH 2 -O-（CH 2）2 -O-nCH 2 -COOR，其中R为氢或1至6个碳原子的烷基，n为0或1至10的整数，在水溶性有机溶剂和/或水 ，80〜200℃。这些缩聚物可用作线釉，浸渍剂和粘合剂。

公开(公告)号：US5324402A

公开(公告)日：1994-06-28

申请号：US956763

申请日：1993-02-04

申请人： Gunther Ott ,  Ulrich Heimann ,  Walter Jouck ,  Udo Reiter ,  David J. Santure

发明人： Gunther Ott ,  Ulrich Heimann ,  Walter Jouck ,  Udo Reiter ,  David J. Santure

IPC分类号： C08G18/65 ,  C08G18/10 ,  C08G18/28 ,  C08G18/80 ,  C09D5/44 ,  C09D175/04 ,  C25D13/06 ,  C25D13/10

CPC分类号： C09D5/4496 ,  C08G18/10 ,  C08G18/8009

摘要： The invention relates to a cathodic electro-dipping process wherein the electro-dipping primer employed contains a crosslinking agent which can be obtained by(I) reacting, in a first stage,(a) diphenylmethane diisocyanate and(b) a monoalcohol or a mixture of monoalcohols to give an intermediate product (A) containing isocyanate groups, and(II) reacting this intermediate product (A) in a second stage with(c) a polyol or a mixture of polyols to give an intermediate product (B) containing hydroxyl groups which(III) is reacted in a third stage either with(d) a cycloaliphatic, aliphatic or araliphatic polyisocyanate or a mixture of such polyisocyanates and(e) a monofunctional masking agent or a mixture of such masking agents or with(f) a partially-masked polyisocyanate prepared from (d) and (e)to give a crosslinking agent which is free from isocyanate groups.

摘要翻译： PCT No.PCT / EP91 / 01011 Sec。 371日期：1993年2月4日 102（e）日期1993年2月4日PCT PCT 1991年5月31日PCT公布。 WO91 / 18952 PCT出版物 日本1991年12月12日。本发明涉及一种阴极电浸法，其中使用的电浸渍底物含有交联剂，其可以通过（I）在第一阶段中使（a）二苯基甲烷二异氰酸酯和（ b）一元醇或一元醇的混合物，得到含有异氰酸酯基团的中间产物（A），和（II）使该中间产物（A）在第二阶段与（c）多元醇或多元醇混合物反应，得到 含有羟基的中间产物（B）（III）在第三阶段与（d）脂环族，脂族或芳脂族多异氰酸酯或这些多异氰酸酯的混合物和（e）单官能掩蔽剂或这种掩蔽剂的混合物 （f）由（d）和（e）制备的部分掩蔽的多异氰酸酯，得到不含异氰酸酯基团的交联剂。

公开(公告)号：US5410001A

公开(公告)日：1995-04-25

申请号：US216864

申请日：1994-03-23

申请人： Gunther Ott ,  Ulrich Heimann ,  Walter Jouck ,  Udo Reiter ,  David J. Santure

发明人： Gunther Ott ,  Ulrich Heimann ,  Walter Jouck ,  Udo Reiter ,  David J. Santure

IPC分类号： C08G18/65 ,  C08G18/10 ,  C08G18/28 ,  C08G18/80 ,  C09D5/44 ,  C09D175/04 ,  C25D13/06 ,  C08F283/04

CPC分类号： C09D5/4496 ,  C08G18/10 ,  C08G18/8009

摘要： The invention relates to a cathodic electro-dipping process wherein the electro-dipping primer employed contains a crosslinking agent which can be obtained by(I) reacting, in a first stage,(a) diphenylmethane diisocyanate and(b) a monoalcohol or a mixture of monoalcohols to give an intermediate product (A) containing isocyanate groups, and(II) reacting this intermediate product (A) in a second stage with(c) a polyol or a mixture of polyols to give an intermediate product (B) containing hydroxyl groups which(III) is reacted in a third stage either with(d) a cycloaliphatic, aliphatic or araliphatic polyisocyanate or a mixture of such polyisocyanates and(e) a monofunctional masking agent or a mixture of such masking agents or with(f) a partially-masked polyisocyanate prepared from (d) and (e)to give a crosslinking agent which is free from isocyanate groups.

摘要翻译： 本发明涉及一种阴极电浸渍方法，其中所用的电浸渍底物含有交联剂，其可以通过（I）在（a）二苯基甲烷二异氰酸酯和（b）一元醇或混合物 的一元醇，得到含有异氰酸酯基团的中间产物（A），和（II）使该中间产物（A）在第二阶段与（c）多元醇或多元醇的混合物反应，得到含羟基的中间产物（B） （III）在第三阶段与（d）脂环族，脂族或芳脂族多异氰酸酯或这些多异氰酸酯的混合物和（e）单官能掩蔽剂或这种掩蔽剂的混合物或与（f） 由（d）和（e）制备的部分掩蔽的多异氰酸酯得到不含异氰酸酯基团的交联剂。

公开(公告)号：US5374340A

公开(公告)日：1994-12-20

申请号：US127102

申请日：1993-09-24

申请人： Gunther Ott ,  Udo Reiter ,  Walter Jouck ,  David J. Santure ,  Dieter Ruhl

发明人： Gunther Ott ,  Udo Reiter ,  Walter Jouck ,  David J. Santure ,  Dieter Ruhl

IPC分类号： C08G59/14 ,  C08L63/00 ,  C09D5/44 ,  C25D13/04

CPC分类号： C09D5/4492 ,  C08G59/1444 ,  C08G59/1483 ,  C08L63/00 ,  C09D5/4457 ,  Y10S524/901

摘要： The invention relates to a process for a cathodic electrocoating process, wherein the electrocoating bath contains at least 7.5% by weight of a polyoxyalkylenepolyamine or a mixture consisting of several polyoxyalkylenepolyamines of different chemical structures, the percentage by weight referring to the total amount of binders contained in the electrocoating bath.

摘要翻译： 本发明涉及一种阴极电泳方法的方法，其中电泳浴含有至少7.5重量％的聚氧亚烷基多胺或由几种具有不同化学结构的聚氧亚烷基多胺组成的混合物，重量百分数是指所含的粘合剂的总量 在电泳浴中。

公开(公告)号：US5174874A

公开(公告)日：1992-12-29

申请号：US635176

申请日：1991-01-11

申请人： Klaus Cibura ,  Udo Reiter ,  Walter Jouck

发明人： Klaus Cibura ,  Udo Reiter ,  Walter Jouck

IPC分类号： C08G59/14 ,  C09D5/44 ,  C09D163/00

CPC分类号： C09D163/00 ,  C08G59/14 ,  C09D5/4434

摘要： The invention relates to water-dispersible binders for cationic electrocoating paints, a process for the preparation of these binders and a process for electrophoretic coating of an electrically conducting substrate, connected as cathode, from an aqueous bath based on this binder.The water-dispersible binders are reaction products of(A) epoxy resins containing low-molecular, preferably aromatic groups, having an epoxide equivalent weight below 750,(B) 10% to 60% by weight, prerferably 20% to 40% by weight, based on the total binder, of a prepolymer having a molecular weight (mass average) of 500 to 5000 and an average content per molecule of 0.1 to 1.9 hydroxyl groups and 0.1 to 1.0 carboxyl groups, the total of the hydroxyl and carboxyl groups being between 1 and 2, with an aromatic groups content of 10% to 45% by weight, calculated as phenylene groups contained in the resin solids in % by weight. In order to achieve water dispersibility, these reaction products are modified with(C) primary, secondary and/or tertiary amines and/or their salts or a sulfide/acid mixture or a phosphine/acid mixture.

摘要翻译： 本发明涉及用于阳离子电泳涂料的水分散性粘合剂，这些粘合剂的制备方法以及由基于该粘合剂的水浴中作为阴极连接的导电基材的电泳涂覆方法。 水分散性粘合剂是（A）含有低分子量，优选芳基的环氧树脂的反应产物，其环氧当量重量低于750，（B）为10％至60％重量，最好为20％至40％重量 基于总粘合剂，分子量（质量平均）为500〜5000，平均含量为0.1〜1.9个羟基和0.1〜1.0个羧基的预聚物为基准，羟基和羧基的总数为 1至2之间，芳族基团含量为10重量％至45重量％，以树脂固体中所含的亚苯基计为重量％。 为了实现水分散性，这些反应产物用（C）伯，仲和/或叔胺和/或其盐或硫化物/酸混合物或膦/酸混合物进行改性。