Water-soluble pyrazolone-imide containing azo dyestuffs
    2.
    发明授权
    Water-soluble pyrazolone-imide containing azo dyestuffs 失效
    含有偶氮染料的水溶性吡唑啉酮酰亚胺

    公开(公告)号:US4210582A

    公开(公告)日:1980-07-01

    申请号:US818682

    申请日:1977-07-25

    IPC分类号: C09B62/008 C09B29/38

    CPC分类号: C09B62/0088

    摘要: Monoazo compounds of the formula ##STR1## wherein Y is phenyl, or phenyl substituted by Z--NH--, sulfo, chloro or methyl; andZ is .alpha.,.beta.-dibromopropionyl or .alpha.-bromoacryloyl, are excellent dyes and are suitable for dyeing and printing materials of the most diverse kind.

    摘要翻译: 其中Y是苯基或被Z-NH-,磺基,氯或甲基取代的苯基的式“IMAGE”的单偶氮化合物; Z是α,β-二溴丙酰基或α-溴丙烯酰基,是优异的染料,适用于最不同种类的染色和印刷材料。

    Process for the manufacture of chromium complexes from metallizable azo
or azo methine dyes
    3.
    发明授权
    Process for the manufacture of chromium complexes from metallizable azo or azo methine dyes 失效
    从金属化偶氮或偶氮次甲基染料制造铬络合物的方法

    公开(公告)号:US4085097A

    公开(公告)日:1978-04-18

    申请号:US647268

    申请日:1976-01-07

    CPC分类号: C09B45/01

    摘要: A process is described for the manufacture of chromium complexes of metallizable dyes in the form of solid dyestuff powders of low salt to salt-free content, or of concentrated solutions of low salt or salt-free content in which a metallizable dye, or a mixture of metallizable dyes, in an organic solvent which is immiscible or sparingly miscible with water, or reacted with a chromium compound, in the course of which any water which is liberated is removed by azeotropic distillation, and the resulting chromium complex, provided it is a 1:1 complex, is then optionally reacted in the presence of a base with a further mol of a metallizable dye, or of a colorless, complexforming compound, then isolated from undissolved constituents, and the resulting dye solution of low salt or salt-free content is optionally concentrated or evaporated to dryness, whereby it is possible the manufacture of 1:1 or 1:2 chromium complexes without the handicap of effluent pollution, and to isolate the dyes without using salt. The dyes obtained are especially suitable for the manufacture of concentrated solutions without the necessity of having to increase the solubility by means of extenders.

    摘要翻译: 描述了一种制备以低盐至无盐含量的固体染料粉末形式的可镀金属染料的铬络合物的方法,或其中可镀金属染料或混合物的低浓度或无盐含量的浓缩溶液 的可镀金属染料,在与水不混溶或微量混溶的有机溶剂中或与铬化合物反应,在此过程中,通过共沸蒸馏除去任何释放的水,以及所得的铬络合物,只要它是 然后任选地在碱的存在下与另外的摩尔的可镀金属染料或无色的复合形成化合物反应,然后从未溶解的组分中分离出所得到的低盐或无盐的染料溶液 含量可选地浓缩或蒸发至干,由此可能制造1:1或1:2铬配合物,而不会造成污染物的污染,并将染料与 使用盐。 所得到的染料特别适用于制备浓缩溶液,而不需要通过增量剂增加溶解度。

    Unsymmetrical mono-sulfo containing chromium complexes of azo dyes
    5.
    发明授权
    Unsymmetrical mono-sulfo containing chromium complexes of azo dyes 失效
    含有偶氮染料铬配合物的不对称单磺基

    公开(公告)号:US3970615A

    公开(公告)日:1976-07-20

    申请号:US536059

    申请日:1974-12-24

    CPC分类号: C09B45/16

    摘要: Chromium complex dyes of the formula ##SPC1##Wherein one of the symbols X.sub.1, X.sub.2 and X.sub.3 is hydrogen and each of the others is hydrogen, a halogen atom, a nitro group, a methyl or a methoxy group, R is a phenyl radical which is optionally substituted by halogen, low molecular alkoxy, alkyl or nitro and Me.sup.+ is a cation are disclosed; said dyes being useful in dyeing synthetic and natural polyamides to produce dyeings which are level and have good fastness to light, washing, fulling, decatizing and carbonizing.

    摘要翻译: 符号为X1,X2和X3的式的铬络合物染料是氢,并且其中每一个都是氢,卤素原子,硝基,甲基或甲氧基,R是任选被取代的苯基 通过卤素,低分子量烷氧基,烷基或硝基和Me +是阳离子; 所述染料可用于染色合成和天然聚酰胺以产生水平且具有良好的耐光牢度,洗涤,充满,脱脂和碳化的染色。

    Sulfo-substituted fibre-reactive 1:2-chromium complex azo dyes
    7.
    发明授权
    Sulfo-substituted fibre-reactive 1:2-chromium complex azo dyes 失效
    磺基取代纤维反应性1:2-铬复合偶氮染料

    公开(公告)号:US4432898A

    公开(公告)日:1984-02-21

    申请号:US199789

    申请日:1980-10-23

    摘要: Chromium complex dyes are disclosed which have the formula ##STR1## wherein S.sub.1 represents a hydrogen or halogen atom, a nitro group, a sulpho group, an alkyl or alkoxy radical, an acylamino or arylazo group,S.sub.2 represents a hydrogen or halogen atom, a nitro group, a sulpho group, an alkyl or alkoxy radical,S.sub.3 represents a hydrogen atom, a nitro group or a halogen atom,P is 1 or 2,R represents a fluorochloropyrimidyl or fluorotriazinyl radical, a chloroacetyl, bromoacetyl, .alpha.-chloro- or .alpha.-bromoacryloyl radical or an .alpha.,.beta.-dichloro- or .alpha., .beta.-dibromopropionyl radical, andM.sup..sym. represents a cation.

    摘要翻译: 公开了具有式“IMAGE”的铬络合物染料,其中S1表示氢或卤素原子,硝基,磺基,烷基或烷氧基,酰氨基或芳基偶氮基,S2表示氢或卤素原子, 硝基,磺基,烷基或烷氧基,S3表示氢原子,硝基或卤素原子,P为1或2,R表示氟氯嘧啶基或氟三嗪基,氯乙酰基,溴乙酰基,α-氯 - 或α-溴丙烯酰基或α,β-二氯或α,β-二溴丙酰基,M(+)​​表示阳离子。

    Pyridyl azo aryl metal complex dyes
    8.
    发明授权
    Pyridyl azo aryl metal complex dyes 失效
    吡啶基偶氮芳基金属配合物染料

    公开(公告)号:US4092307A

    公开(公告)日:1978-05-30

    申请号:US670310

    申请日:1976-03-25

    摘要: Heavy metal complexes of azo dyes of the formula ##STR1## wherein D is the radical of a diazo component of the benzene or naphthalene series that carries the group --[CO].sub.p-1 OH in ortho-position to the azo group, p is 1 or 2, X.sub.1 is an unsubstituted or substituted amino, alkoxy, aryloxy, alkylmercapto, arylmercapto or aralkoxy group, X.sub.2 is an unsubstituted or substituted amino group or a low molecular alkyl radical, X.sub.3 is an unsubstituted or substituted amino group and Y is a cyano or carbonamido group, said azo dyes of the formula (1) containing at least one of the following groups: a sulpho or sulphonamido group, a sulphonamido group which is substituted by low molecular alkyl, phenyl or phenyl which carries non-ionogenic substituents, a low molecular alkylsulphonyl group or a phenylsulphonyl group which is unsubstituted or substituted by non-ionogenic substituents.

    摘要翻译: 式(1)的偶氮染料的重金属配合物,其中D是在与偶氮基相邻的位置上携带基团 - [CO] p-1OH的苯或萘系列的重氮组分的基团, p是1或2,X 1是未取代或取代的氨基,烷氧基,芳氧基,烷基巯基,芳基巯基或芳烷氧基,X 2是未取代或取代的氨基或低分子烷基,X 3是未取代或取代的氨基,Y 所述式(1)的偶氮染料含有以下基团中的至少一个:磺基或磺酰胺基,被低分子烷基取代的磺酰胺基,苯基或苯基,其携带非离子型 取代基,低分子烷基磺酰基或苯基磺酰基,其未被取代或被非离子型取代基取代。