公开(公告)号：US20120071689A1

公开(公告)日：2012-03-22

申请号：US13024836

申请日：2011-02-10

申请人： Janet Boggs ,  Stephan Brandstadter ,  John Chien ,  Vimal Sharma ,  E. Bradley Edwards ,  Vicki Hedrick ,  Andrew Jackson ,  Gregory Leman ,  Edward Norman ,  Robert Kaufman

发明人： Janet Boggs ,  Stephan Brandstadter ,  John Chien ,  Vimal Sharma ,  E. Bradley Edwards ,  Vicki Hedrick ,  Andrew Jackson ,  Gregory Leman ,  Edward Norman ,  Robert Kaufman

IPC分类号： C07C311/05

CPC分类号： C07C311/09 ,  C07C69/653 ,  C07C311/13 ,  C07C311/24 ,  C07C311/48 ,  C07C323/12 ,  C11D1/004

摘要： Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohol's, reacting olefins and a saturated compounds, reacting reactants having at least two —CF3 groups with reactants having cyclic groups, RF-compositions such as RF-intermediates, RF-surfactants, RF-monomers, RF-monomer units, RF-metal complexes, RF-phosphate esters, RF-glycols, RF-urethanes, and or RF-foam stabilizers. The RF portion can include at least two groups —CF3 groups, at least three —CF3 groups, and/or at least two —CF3 groups and at least two —CH2 groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the RF-surfactant composition are provided. Acrylics, resins, and polymers are provided that include a RF-monomer unit. Compositions are provided that include a substrate having a RF-composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include RF-surfactants and/or RF-foam stabilizers are provided.

摘要翻译： 提供了生产方法和系统，其包括使卤代化合物，脱卤化合物，醇反应，烯烃和饱和化合物反应，使具有至少两个-CF 3基团的反应物与具有环状基团的反应物反应，RF组合物如RF-中间体，RF 表面活性剂，RF单体，RF单体单元，RF-金属配合物，RF-磷酸酯，RF-二醇，RF-聚氨酯和/或RF-泡沫稳定剂。 RF部分可以包括至少两个基团-CF 3基团，至少三个-CF 3基团和/或至少两个-CF 3基团和至少两个-CH 2基团。 提供了洗涤剂，乳化剂，油漆，粘合剂，油墨，润湿剂，起泡剂和消泡剂，包括RF-表面活性剂组合物。 提供了包括RF单体单元的丙烯酸树脂，树脂和聚合物。 提供了包括其上具有RF组成的基底的组合物。 提供了可以包括RF-表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。

公开(公告)号：US07884255B2

公开(公告)日：2011-02-08

申请号：US11661166

申请日：2005-08-26

申请人： Vicki Hedrick

发明人： Vicki Hedrick

IPC分类号： C07C21/18 ,  C07C17/10

CPC分类号： C07C17/25 ,  B01J2219/00006 ,  C07C17/04 ,  C07C17/21 ,  C07C17/23 ,  C07C17/263 ,  C07C21/20 ,  C07C19/14 ,  C07C19/12 ,  C07C21/18

摘要： Chemical Production Processes and Systems. Chemical production processes are provided that include replacing a halogen of an unsaturated halocarbon to produce an unsaturated hydrohalocarbon. Chemical production systems are provided that include a reaction zone coupled to first and second reservoirs, the first reservoir containing an unsaturated halocarbon and the second reservoir containing a hydrogenating reagent with the system being configured to expose the unsaturated halocarbon of the first reservoir to the hydrogenating agent of the second reservoir within the reaction zone.

摘要翻译： 化学生产过程和系统。 提供了化学生产方法，包括替代不饱和卤代烃的卤素以产生不饱和氢卤烃。 提供化学生产系统，其包括耦合到第一和第二储存器的反应区域，第一储存器包含不饱和卤代烃，第二储存器包含氢化试剂，该系统构造成将第一储存器的不饱和卤代烃暴露于氢化剂 的反应区内的第二储层。

公开(公告)号：US20070282115A1

公开(公告)日：2007-12-06

申请号：US10587724

申请日：2005-01-28

申请人： Janet Boggs ,  Stephan Brandstadter ,  John Chien ,  Mitchel Cohn ,  E. Edwards ,  Vicki Hedrick ,  Andrew Jackson ,  Gregory Leman ,  Bruno Ameduri ,  George Kostov

发明人： Janet Boggs ,  Stephan Brandstadter ,  John Chien ,  Mitchel Cohn ,  E. Edwards ,  Vicki Hedrick ,  Andrew Jackson ,  Gregory Leman ,  Bruno Ameduri ,  George Kostov

IPC分类号： C07C19/08 ,  C07C19/16 ,  C07C21/18 ,  C07C31/38 ,  C07C43/205 ,  C07C43/215 ,  C07C69/62 ,  C07C69/635 ,  C07C69/78 ,  C07D303/02 ,  C07D307/935

CPC分类号： C07C17/278 ,  C07C19/08 ,  C07C19/10 ,  C07C19/14 ,  C07C19/16 ,  C07C21/18

摘要： Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two —CF3 groups with reactants having cyclic groups. RF-compositions such as RF-intermediates, RF-surfactants, RF-monomers, RF-monomer units, RF-metal complexes, RF-phosphate esters, RF-glycols, RF-urethanes, and/or RF-foam stabilizers. The RF portion can include at least two —CF3 groups, at least three —CF3 groups, and/or at least two —CF3 groups and at least two —CH2— groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the RF-surfactant composition are provided. Acrylics, resins, and polymers are provided that include a RF-monomer unit. Compositions are provided that include a substrate having a RF-composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include RF-surfactants and/or RF-foam stabilizers are provided.

摘要翻译： 提供了生产方法和系统，其包括卤代化合物，脱卤化合物，醇反应，烯烃与饱和化合物的反应，使具有至少两个-CF 3 N 3基团的反应物与具有环状基团的反应物反应。 R F - 如R 1 - 中间体，R 1 F - 表面活性剂，R 1 F - 单体，R 单 - 单体单元，R 1 F - 金属络合物，R 1 F - 磷酸酯，R 1 - 二醇， R F - 氨基甲酸酯，和/或R F - 泡沫稳定剂。 R 1 F 3部分可以包括至少两个-CF 3 N 3基团，至少三个-CF 3 N 3基团和/或至少两个 - CF 3个基团和至少两个-CH 2 - 基团。 提供了洗涤剂，乳化剂，油漆，粘合剂，油墨，润湿剂，起泡剂和消泡剂，包括R 1 F - 表面活性剂组合物。 提供了包括R 1 F单体单元的丙烯酸树脂，树脂和聚合物。 提供了包含其上具有R 1 -F 3 - 组成的底物的组合物。 提供了可以包括R 1 F - 表面活性剂的水性成膜泡沫（“AFFF”）制剂和/或提供的R 3 F泡沫体稳定剂。

公开(公告)号：US08318656B2

公开(公告)日：2012-11-27

申请号：US13024836

申请日：2011-02-10

申请人： Janet Boggs ,  Stephan Brandstadter ,  John Chien ,  Vimal Sharma ,  E. Bradley Edwards ,  Vicki Hedrick ,  Andrew Jackson ,  Gregory Leman ,  Edward Norman ,  Robert Kaufman

发明人： Janet Boggs ,  Stephan Brandstadter ,  John Chien ,  Vimal Sharma ,  E. Bradley Edwards ,  Vicki Hedrick ,  Andrew Jackson ,  Gregory Leman ,  Edward Norman ,  Robert Kaufman

IPC分类号： C11D1/00 ,  C11D3/24 ,  C07C17/00 ,  C07C19/08 ,  C07C21/18 ,  C07C22/08

CPC分类号： C07C311/09 ,  C07C69/653 ,  C07C311/13 ,  C07C311/24 ,  C07C311/48 ,  C07C323/12 ,  C11D1/004

摘要： Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohol's, reacting olefins and a saturated compounds, reacting reactants having at least two —CF3 groups with reactants having cyclic groups, RF-compositions such as RF-intermediates, RF-surfactants, RF-monomers, RF-monomer units, RF-metal complexes, RF-phosphate esters, RF-glycols, RF-urethanes, and or RF-foam stabilizers. The RF portion can include at least two groups —CF3 groups, at least three —CF3 groups, and/or at least two —CF3 groups and at least two —CH2 groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the Rf-surfactant composition are provided. Acrylics, resins, and polymers are provided that include a RF-monomer unit. Compositions are provided that include a substrate having a RF-composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include RF-surfactants and/or RF-foam stabilizers are provided.

摘要翻译： 提供了生产方法和系统，其包括使卤代化合物，脱卤化合物，醇反应，烯烃和饱和化合物反应，使具有至少两个-CF 3基团的反应物与具有环状基团的反应物反应，RF组合物如RF-中间体，RF 表面活性剂，RF单体，RF单体单元，RF-金属配合物，RF-磷酸酯，RF-二醇，RF-聚氨酯和/或RF-泡沫稳定剂。 RF部分可以包括至少两个基团-CF 3基团，至少三个-CF 3基团和/或至少两个-CF 3基团和至少两个-CH 2基团。 提供了包括Rf-表面活性剂组合物的洗涤剂，乳化剂，油漆，粘合剂，油墨，润湿剂，起泡剂和消泡剂。 提供了包括RF单体单元的丙烯酸树脂，树脂和聚合物。 提供了包括其上具有RF组成的基底的组合物。 提供了可以包括RF-表面活性剂和/或RF-泡沫稳定剂的水性成膜泡沫（AFFF）制剂。

公开(公告)号：US20080300432A1

公开(公告)日：2008-12-04

申请号：US11661167

申请日：2005-08-26

申请人： Vicki Hedrick ,  Stephan Brandstadter ,  Janet Boggs ,  Mitchel Cohn ,  Venkat Reddy Ghojala ,  P.V. Ramachandran

发明人： Vicki Hedrick ,  Stephan Brandstadter ,  Janet Boggs ,  Mitchel Cohn ,  Venkat Reddy Ghojala ,  P.V. Ramachandran

IPC分类号： C07C21/18 ,  B01J19/00

CPC分类号： C07C17/25 ,  B01J2219/00006 ,  C07C17/04 ,  C07C17/21 ,  C07C17/23 ,  C07C17/263 ,  C07C21/20 ,  C07C19/14 ,  C07C19/12 ,  C07C21/18

摘要： Chemical production processes are provided that include reacting a metal comprising olefin to form a conjugated olefin; reacting a heterohalogenated olefin to form a conjugated olefin; reacting a halogenated alkane to form a conjugated olefin; and/or reacting a hydrohalogenated olefin to form a conjugated olefin. Chemical production systems are also provided that can include: a first reactant reservoir configured to house a perhalogenated olefin; a second reactant reservoir configured to house a catalyst mixture; a first reactor coupled to both the first and second reservoirs, the first reactor configured to house a metal-comprising mixture and receive both the perhalogenated olefin form the first reactant reservoir and the reactant mixture from the second reactant reservoir; and a product collection reservoir coupled to the first reactor and configured to house a conjugated olefin.

摘要翻译： 提供化学生产方法，包括使包含烯烃的金属反应形成共轭烯烃; 使杂卤化烯烃反应形成共轭烯烃; 使卤代烷烃反应形成共轭烯烃; 和/或使氢卤代烯烃反应形成共轭烯烃。 还提供了化学生产系统，其可以包括：构造成容纳全卤代烯烃的第一反应物储存器; 构造成容纳催化剂混合物的第二反应物储存器; 耦合到第一和第二储存器的第一反应器，第一反应器被配置为容纳含金属的混合物并且从第二反应物储存器接收来自第一反应物储存器和反应物混合物的全卤代烯烃; 以及与第一反应器耦合并构造成容纳共轭烯烃的产品收集容器。

公开(公告)号：US20050288536A1

公开(公告)日：2005-12-29

申请号：US11218055

申请日：2005-08-31

申请人： Yuichi Iikubo ,  Vicki Hedrick ,  Stephen Brandstadter ,  Mitchel Cohn

发明人： Yuichi Iikubo ,  Vicki Hedrick ,  Stephen Brandstadter ,  Mitchel Cohn

IPC分类号： C07C17/10 ,  C07C17/23 ,  C07C17/269 ,  C07C17/275 ,  C07C21/18 ,  C07C21/185 ,  C07C17/00

CPC分类号： C07C21/185 ,  C07C17/10 ,  C07C17/23 ,  C07C17/275 ,  C07C21/18 ,  C07C19/10 ,  C07C19/12

摘要： Methods and materials are disclosed for the recovery of valuable hydrofluorocarbons and subsequent conversion to environmentally inert compounds. More specifically methods and materials are provided for recovering hydrofluorocarbons such as HFC-227, HFC-236, HFC-245, HFC-125, HFC-134, HFC-143, HFC-152, HFC-32, HFC-23 and their respective isomers. Processes are provided for converting hydrofluorocarbons such as these to fluoromonomer precursors such as CFC-217, CFC-216, CFC-215, CFC-115, CFC-114, CFC-113, CFC-112, HCFC-22, CFC-12, CFC-13 and their respective isomers. Materials, methods and schemes are provided for the conversion of these fluoromonomer precursors to fluoromonomers such as HFP, PFP, TFP, TFE, and VDF.

摘要翻译： 公开了用于回收有价值氢氟烃并随后转化为环境惰性化合物的方法和材料。 更具体地提供方法和材料用于回收氢氟烃如HFC-227，HFC-236，HFC-245，HFC-125，HFC-134，HFC-143，HFC-152，HFC-32，HFC-23及其各自的 异构体。 提供了将这些氢氟烃转化成氟单体前体如CFC-217，CFC-216，CFC-215，CFC-115，CFC-114，CFC-113，CFC-112，HCFC-22，CFC-12， CFC-13及其各自的异构体。 提供材料，方法和方案用于将这些含氟单体前体转化成含氟单体如HFP，PFP，TFP，TFE和VDF。

公开(公告)号：US20050148804A1

公开(公告)日：2005-07-07

申请号：US11069180

申请日：2005-02-28

申请人： Vicki Hedrick ,  Janet Boggs ,  Stephan Brandstadter ,  Mitchel Cohn

发明人： Vicki Hedrick ,  Janet Boggs ,  Stephan Brandstadter ,  Mitchel Cohn

IPC分类号： B01J23/89 ,  B01J27/08 ,  B01J27/128 ,  B01J27/13 ,  B01J35/00 ,  C07C17/23 ,  C07C17/354 ,  C07C17/25

CPC分类号： C07C17/354 ,  B01J23/8926 ,  B01J27/08 ,  B01J27/128 ,  B01J27/13 ,  B01J35/0006 ,  C07C17/23 ,  C07C19/08 ,  C07C21/18 ,  C07C19/10

摘要： Systems and methods for producing fluorocarbons are provided that include contacting a saturated halogenated fluorocarbon with hydrogen and catalyst to produce a saturated hydrofluorocarbon and an unsaturated fluorocarbon. Aspects of the present invention describe systems and methods for contacting saturated halogenated fluorocarbons such as CF3CClFCF3 and/or CF3CCl2CF3 with hydrogen and catalyst. Systems and methods of the present invention also describe contacting saturated halogenated fluorocarbons with catalysts having one or more of K, Zr, Na, Ni, Cu, Ni, Zn, Fe, Mn, Co, Ti, and Pd. Aspects of the present invention also describe contacting saturated halogenated fluorocarbons with hydrogen under pressure. Saturated hydroflourocarbons and unsaturated fluorocarbons produced in accordance with the systems and methods of the present invention can include one or more of CF3CFHCF3, CF3CH2CF3, CF3CHClCF3, CF3CF═CF2, CF3CH═CF2, and CF3CCl═CF2.

摘要翻译： 提供了制备碳氟化合物的系统和方法，包括使饱和卤代碳氟化合物与氢气和催化剂接触以产生饱和氢氟碳化合物和不饱和氟碳化合物。 本发明的方面描述了用于使饱和卤代碳氟化合物如CF 3 CClFC 3 3和/或CF 3 CCl 3和/ 2 CO 3与氢气和催化剂反应。 本发明的系统和方法还描述了使饱和卤代碳氟化合物与具有一种或多种K，Zr，Na，Ni，Cu，Ni，Zn，Fe，Mn，Co，Ti和Pd的催化剂接触。 本发明的方面还描述了在压力下使饱和卤代碳氟化合物与氢接触。 根据本发明的系统和方法生产的饱和氢氟烃和不饱和碳氟可以包括一种或多种CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3，CF 3，CF 3 CF 3，CF 3 CF 3，CF 3，CF 3 CF 3， CF 2，CF 3，CH-CF 2，CF 3，CCl-CF 2， SUB>。

公开(公告)号：US08148584B2

公开(公告)日：2012-04-03

申请号：US11559330

申请日：2006-11-13

申请人： Vicki Hedrick ,  John Chien ,  Janet Boggs ,  Andrew Jackson ,  E. Bradley Edwards ,  Stephan Brandstadter

发明人： Vicki Hedrick ,  John Chien ,  Janet Boggs ,  Andrew Jackson ,  E. Bradley Edwards ,  Stephan Brandstadter

IPC分类号： C07C17/093

CPC分类号： A62D1/00 ,  A62D1/005 ,  A62D1/0057 ,  A62D1/0085 ,  C07C17/25 ,  C07C17/278 ,  C07C21/18 ,  C09K3/30 ,  C09K21/08 ,  C07C19/16

摘要： Compositions comprising are provided wherein RF is a fluorine containing moiety comprising (CF3)2CFCH2(CF3)CH—, (CF3)2CFCH2((CF3)2CF)CH—, (CF3)2CFCH2((CF3)2CH)CH—, (CF3)2CHCH2((CF3)2CF)CH—, ((CF3)2CFCH2)2CH—, (CF3)2CFCH2CF—, (CF3)2CF—, (CF3)2CH—, CF3—, or CnF2n+1—, n being an integer from 2 to 20; R1 is F or H; R2 comprises (CF3)2CF—, (CF3)2CH—, CF3—, F, or H; and R3 comprises (CF3)2CF—, (CF3)2CH—, CF3—, F, or H, such compositions can produced according to processes, and utilized to prevent combustion utilizing systems.

摘要翻译： 提供包含的组合物，其中RF是包含（CF 3）2 CFF 2（CF 3）CH - ，（CF 3）2 CFF 2（（CF 3）2 CF 3）CH - ，（CF 3）2 CFF 2（（CF 3）2 CH）CH - ，（CF 3） ）2CHCH2（（CF3）2CFCH2）2 - ，（CF3）2CFCH2CF-，（CF3）2CF-，（CF3）2CH-，CF3-或CnF2n + 2〜20的整数; R1为F或H; R2包含（CF3）2CF-，（CF3）2CH-，CF3-，F或H; 并且R 3包含（CF 3）2 CF-，（CF 3）2 CH-，CF 3 - ，F或H，这样的组合物可以根据方法制备，并用于防止燃烧利用系统。

公开(公告)号：US20110213113A1

公开(公告)日：2011-09-01

申请号：US13102563

申请日：2011-05-06

申请人： Andrew Jackson ,  Vimal Sharma ,  E. Bradley Edwards ,  Janet Boggs ,  Vicki Hedrick ,  Stephan Brandstadter ,  John Chien ,  Edward Norman ,  Robert Kaufman ,  Bruno Ameduri ,  George K. Kostov

发明人： Andrew Jackson ,  Vimal Sharma ,  E. Bradley Edwards ,  Janet Boggs ,  Vicki Hedrick ,  Stephan Brandstadter ,  John Chien ,  Edward Norman ,  Robert Kaufman ,  Bruno Ameduri ,  George K. Kostov

IPC分类号： C08F120/22 ,  C07C229/06 ,  C07C311/03 ,  C07F9/141 ,  C07C43/04 ,  C08G18/28 ,  C07C17/00

CPC分类号： C07C311/09 ,  C07C69/653 ,  C07C317/18 ,  C07F9/091 ,  C08F220/24 ,  C11D1/004 ,  C11D3/0031 ,  C11D3/32 ,  C11D3/349

摘要： RF-compositions including surfactants, foam stabilizers, monomers, polymers, urethanes, intermediates, metal complexes, phosphate esters as well as telomerization methods are provided.

摘要翻译： 提供了包括表面活性剂，泡沫稳定剂，单体，聚合物，聚氨酯，中间体，金属络合物，磷酸酯以及调聚方法的RF组合物。

公开(公告)号：US07943567B2

公开(公告)日：2011-05-17

申请号：US10587444

申请日：2005-01-28

申请人： Janet Boggs ,  Stephan Brandstadter ,  John Chien ,  Vimal Sharma ,  E. Bradley Edwards ,  Vicki Hedrick ,  Andrew Jackson ,  Gregory Leman ,  Edward Norman ,  Robert Kaufman

发明人： Janet Boggs ,  Stephan Brandstadter ,  John Chien ,  Vimal Sharma ,  E. Bradley Edwards ,  Vicki Hedrick ,  Andrew Jackson ,  Gregory Leman ,  Edward Norman ,  Robert Kaufman

IPC分类号： C11D1/00 ,  C11D3/24 ,  C07C17/00 ,  C07C19/08 ,  C07C21/18 ,  C07C22/08

CPC分类号： C07C17/278 ,  C07C19/08 ,  C07C19/10 ,  C07C19/14 ,  C07C19/16 ,  C07C21/18 ,  C11D1/004 ,  C11D3/0026 ,  C11D3/0094

摘要： Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohol's, reacting olefins and a saturated compounds, reacting reactants having at least two —CF3 groups with reactants having cyclic groups. RF-compositions such as RF-intermediates, RF-surfactants, RF-monomers, RF-monomer units, RF-metal complexes, RF-phosphate esters, RF-glycols, RF-urethanes, and/or RF-foam stabilizers. The RF portion can include at least two —CF3 groups, at least three —CF3 groups, and/or at least two —CF3 groups and at least two —CH2— groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the RF-surfactant composition are provided. Acrylics, resins, and polymers are provided that include a RF-monomer unit. Compositions are provided that include a substrate having a RF-composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include RF-surfactants and/or RF-foam stabilizers are provided.

摘要翻译： 提供了生产方法和系统，其包括卤代化合物，脱卤化合物，醇反应，烯烃与饱和化合物的反应，使具有至少两个-CF 3基团的反应物与具有环状基团的反应物反应。 RF组合物如RF-中间体，RF-表面活性剂，RF单体，RF单体单元，RF-金属络合物，RF-磷酸酯，RF-二醇，RF-聚氨酯和/或RF-泡沫稳定剂。 RF部分可以包括至少两个-CF 3基团，至少三个-CF 3基团和/或至少两个-CF 3基团和至少两个-CH 2 - 基团。 提供了洗涤剂，乳化剂，油漆，粘合剂，油墨，润湿剂，起泡剂和消泡剂，包括RF-表面活性剂组合物。 提供了包括RF单体单元的丙烯酸树脂，树脂和聚合物。 提供了包括其上具有RF组成的基底的组合物。 提供了可以包括RF-表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。