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公开(公告)号：US4650596A
公开(公告)日：1987-03-17
申请号：US745375
申请日：1985-06-17
IPC分类号： E21B43/22 , C09K8/524 , C10L1/236 , C10M133/16
CPC分类号： C10L1/2364 , C09K8/524
摘要： An ester/amide copolymer useful as a pour-point depressant, wherein: the ester comonomer is at least one acrylic acid or methacrylic acid--C.sub.16-24 aliphatic alcohol ester; the amide comonomer is at least one acrylamide or methacrylamide, unsubstituted or substituted at the nitrogen atom; and the mol ratio of ester to amide is about 2-10:1.
摘要翻译： 用作倾点抑制剂的酯/酰胺共聚物，其中：酯共聚单体为至少一种丙烯酸或甲基丙烯酸-C16-24脂族醇酯; 酰胺共聚单体是至少一种未被取代或在氮原子上取代的丙烯酰胺或甲基丙烯酰胺; 酯与酰胺的摩尔比为约2-10:1。
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2.发明授权
公开(公告)号：US5403822A
公开(公告)日：1995-04-04
申请号：US68563
申请日：1993-05-27
申请人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Michael Neuss , Wolfgang Zoellner , Frank Burbach
发明人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Michael Neuss , Wolfgang Zoellner , Frank Burbach
IPC分类号： C09K8/32 , C09K20060101 , C09K8/34 , C09K7/02 , C09K7/06
CPC分类号： C09K8/34
摘要： The invention describes the use of selected esters, fluid at room temperature and with flash points above 80.degree. C., from monocarboxylic acids of synthetic and/or natural origin with 6 to 11 carbon atoms and mono- and/or polyfunctional alcohols as the oil phase or a component of the oil phase of invert drilling muds, which are suitable for environment-friendly development of petroleum and natural gas deposits and in a continuous oil phase contain a dispersed aqueous phase together with emulsifiers, weighting agents, fluid-loss additives and preferably further conventional additives. In a further embodiment the invention relates to invert-drilling fluids of the types mentioned, which are characterized in that the oil phase contains esters of monocarboxylic acids of synthetic and/or natural origin with 6 to 11 carbon atoms and with mono- and/or polyfunctional alcohols preferably in admixture with other components from the class of ecologically acceptable compounds.
摘要翻译： 本发明描述了在室温下和闪点高于80℃的选择的酯，来自合成和/或天然来源的具有6至11个碳原子的一元羧酸和单和/或多官能醇作为油的用途 相位或反相钻井泥浆油相的组分，适用于石油和天然气沉积物的环境友好型开发，连续油相中含有分散的水相以及乳化剂，增重剂，流体损失添加剂和 优选进一步的常规添加剂。 在另一个实施方案中，本发明涉及所述类型的反向钻井液，其特征在于油相含有合成和/或天然来源的具有6至11个碳原子的一元羧酸酯和单 - 和/或 多官能醇优选与来自生态可接受的化合物类的其它组分混合。
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公开(公告)号：US5039432A
公开(公告)日：1991-08-13
申请号：US320122
申请日：1989-03-07
申请人： Wolfgang Ritter , Claudia Meyer , Wolfgang Zoellner , Claus-Peter Herold , Stephan V. Tapavicza
发明人： Wolfgang Ritter , Claudia Meyer , Wolfgang Zoellner , Claus-Peter Herold , Stephan V. Tapavicza
IPC分类号： E21B43/22 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/12 , C10L1/192 , C10L1/196 , C10L10/16
CPC分类号： C10L10/16 , C10L1/1963 , Y10S507/93 , Y10S507/931 , Y10T137/0391
摘要： Method of reducing the pour-point and improving the flowability of petroleum oil or a fraction thereof by adding thereto a flowability-improving quantity of at least one copolymer of (a) an acrylic acid ester, a methacrylic acid ester, or a mixture of an acrylic acid ester and a methacrylic acid ester, and (b) not more than 20% by weight, based on the weight of the copolymer, of acrylic acid, methacrylic acid, or a mixture of acrylic acid and methacrylic acid, and wherein said esters in component (a) are esters of a C.sub.16 or higher alcohol or an alcohol mixture wherein at least 75% by weight thereof is one or more alcohols containing at least 16 carbon atoms; and the compositions resulting therefrom.
摘要翻译： 通过向其中加入至少一种（a）丙烯酸酯，甲基丙烯酸酯或其混合物的共聚物的流动性提高量来降低石油油或其馏分的流动性和改善流动性的方法 丙烯酸酯和甲基丙烯酸酯，和（b）基于共聚物的重量，不超过20重量％的丙烯酸，甲基丙烯酸或丙烯酸和甲基丙烯酸的混合物，并且其中所述酯 在组分（a）中是C16或更高级醇或醇混合物的酯，其中至少75％重量是一种或多种含有至少16个碳原子的醇; 和由此得到的组合物。
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4.发明授权Co-polymers of long chain alkyl acrylates with N-containing olefins and their use as flow improvers for crude oils 失效长链烷基丙烯酸酯与含N烯烃的共聚物及其作为原油流动改进剂的用途
公开(公告)号：US5006621A
公开(公告)日：1991-04-09
申请号：US326598
申请日：1989-03-21
申请人： Bernd Wahle , Claus-Peter Herold , Wolfgang Zoellner , Ludwig Schieferstein , Doris Oberkobusch
发明人： Bernd Wahle , Claus-Peter Herold , Wolfgang Zoellner , Ludwig Schieferstein , Doris Oberkobusch
IPC分类号： C08F220/10 , C08F20/34 , C08F22/36 , C08F220/18 , C08F220/26 , C08F220/34 , C08F220/36 , C08F222/40 , C09K3/00 , C10L1/236
CPC分类号： C10L1/2366 , C08F220/18 , C08F220/26 , C10L1/2368
摘要： Copolymers of long-chain alkyl acrylates or methacrylates of the formulaCH.sub.2 .dbd.CR.sup.1 --CO--OR.sup.2 (I)in which R.sup.1 is a hydrogen atom or a methyl group and OR.sup.2 is a fatty alcohol radical with 16 to 34 carbon atoms and nitrogen-containing olefins can be used as flow improvers for crude oils.
摘要翻译： 式CH2 = CR1-CO-OR2（Ⅰ）的长链烷基丙烯酸酯或甲基丙烯酸酯的共聚物，其中R1是氢原子或甲基，OR2是具有16至34个碳原子的脂肪醇基团和含氮的 烯烃可以用作原油的流动改进剂。
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5.发明授权Use of selected inhibitors against the formation of solid organo-based incrustations from fluid hydrocarbon mixtures 失效使用选定的抑制剂来防止流体烃混合物形成固体有机基结垢公开(公告)号：US06344431B1
公开(公告)日：2002-02-05
申请号：US08256199
申请日：1994-09-01
IPC分类号： C09K700
CPC分类号： C10L1/224 , C09K8/524 , C10G9/16 , C10L1/14 , C10L1/143 , C10L1/1641 , C10L1/1963 , C10L1/1973 , C10L1/2641 , C10L1/2658 , C10L1/2683 , C10L10/04 , F17D1/17
摘要： The invention relates to the use of (A) esters of phosphoric acid and/or partial salts thereof with alkoxylated aliphatic, cycloaliphatic and/or aromatic alcohols and/or (B) fatty acid oligo-dialkanolamides as inhibitors against the formation of incrustations based on organic solids from liquid and/or gaseous hydrocarbon mixtures which are fluid and prone to form such incrustations. Preferred inhibitors having a surface-active character are capable of wetting, and especially of spreading on, solid work material surfaces also in the presence of the fluid hydrocarbon phase. They are particularly suitable as additives to crude oils and/or oil fractions susceptible of forming incrustations.
摘要翻译： 本发明涉及（A）磷酸和/或其部分盐与烷氧基化脂族，脂环族和/或芳族醇和/或（B）脂肪酸低聚二烷醇酰胺的酯的用途，用于抑制基于 来自液态和/或气态烃混合物的有机固体是流体并易于形成这种结垢。 具有表面活性特征的优选抑制剂能够在流体烃相的存在下润湿，特别是在固体工作材料表面上扩散。 它们特别适合作为易形成结垢的原油和/或油馏分的添加剂。
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公开(公告)号：US4762946A
公开(公告)日：1988-08-09
申请号：US851981
申请日：1986-04-14
申请人： Wolfgang Ritter , Wolfgang Zoellner
发明人： Wolfgang Ritter , Wolfgang Zoellner
CPC分类号： C10L1/1963 , C08F20/28 , C10L1/1983 , C10L1/2364
摘要： Polymeric pour point depressants are described which are prepared from new esters of .alpha.,.beta.-olefinically unsaturated carboxylic acids of the formulaR.sub.1 --CO--[--O--A--CO--]--.sub.n ORwhereinR.sub.1 --CO-- is an .alpha.,.beta.-olefinically unsaturated carboxylic acid residue containing from 3 to 6 carbon atoms,R is a saturated or unsaturated hydrocarbon radical containing from 10 to 24 carbon atoms,--[--O--A--CO--]-- is a residue of a hydroxycarboxylic acid having from 2 to 6 carbon atoms,A is an aliphatic radical having from 1 to 5 carbon atoms, andn is a number having a value of from 1 to 18.
摘要翻译： 描述了由式R1-CO - [ - OA-CO - ] - nOR的α，β-烯属不饱和羧酸的新酯制备的聚合倾点下降剂，其中R1-CO-是α，β-烯属不饱和的 含有3至6个碳原子的羧酸残基，R是含有10至24个碳原子的饱和或不饱和烃基， - [ - OA-CO - ] - 是具有2至6个碳原子的羟基羧酸的残基 A是具有1至5个碳原子的脂族基团，n是1至18的数值。
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公开(公告)号：US4668733A
公开(公告)日：1987-05-26
申请号：US844912
申请日：1986-03-27
CPC分类号： C08C19/40 , C08G59/1438
摘要： A pour point depressant composition and a method for its use. The pour point depressant is a predominantly butadiene polymer epoxidized and then ring-opened with a C.sub.12-24 carboxylic acid, or ring-opened with an alcohol followed by esterification.
摘要翻译： 一种倾点下降剂组合物及其使用方法。 倾点下降剂主要是环氧化的丁二烯聚合物，然后用C12-24羧酸开环，或用醇开环酯化。
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8.发明授权Esters of unsaturated carboxylic acids, preparation of their oil-soluble homo- and copolymers and use thereof as pour point depressants 失效不饱和羧酸的酯，它们的油溶性均聚物和共聚物的制备以及作为倾点下降剂的用途
公开(公告)号：US4906702A
公开(公告)日：1990-03-06
申请号：US187183
申请日：1988-04-28
申请人： Wolfgang Ritter , Wolfgang Zoellner
发明人： Wolfgang Ritter , Wolfgang Zoellner
IPC分类号： C07C69/527 , C08F20/28 , C10L1/196 , C10L1/198 , C10L1/236
CPC分类号： C10L1/1963 , C08F20/28 , C10L1/1983 , C10L1/2364
摘要： Polymeric pour point depressants are described which are prepared from new esters of .alpha.,.beta.-olefinically unsaturated carboxylic acids of the formulaR.sub.1 --CO--[--O--A--CO--]--.sub.n ORwhereinR.sub.1 --CO-- is an .alpha.,.beta.-olefinically unsaturated carboxylic acid residue containing from 3 to 6 carbon atoms,R is a saturated or unsaturated hydrocarbon radical containing from 10 to 24 carbon atoms,--[--O--A--CO--]-- is a residue of a hydroxycarboxylic acid having from 2 to 6 carbon atoms,A is an aliphatic radical having from 1 to 5 carbon atoms, andn is a number having a value of from 1 to 18.
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