摘要:
Copolymers of long-chain alkyl acrylates or methacrylates of the formulaCH.sub.2 .dbd.CR.sup.1 --CO--OR.sup.2 (I)in which R.sup.1 is a hydrogen atom or a methyl group and OR.sup.2 is a fatty alcohol radical with 16 to 34 carbon atoms and nitrogen-containing olefins can be used as flow improvers for crude oils.
摘要:
The invention describes the use of selected esters, fluid at room temperature and with flash points above 80.degree. C., from monocarboxylic acids of synthetic and/or natural origin with 6 to 11 carbon atoms and mono- and/or polyfunctional alcohols as the oil phase or a component of the oil phase of invert drilling muds, which are suitable for environment-friendly development of petroleum and natural gas deposits and in a continuous oil phase contain a dispersed aqueous phase together with emulsifiers, weighting agents, fluid-loss additives and preferably further conventional additives. In a further embodiment the invention relates to invert-drilling fluids of the types mentioned, which are characterized in that the oil phase contains esters of monocarboxylic acids of synthetic and/or natural origin with 6 to 11 carbon atoms and with mono- and/or polyfunctional alcohols preferably in admixture with other components from the class of ecologically acceptable compounds.
摘要:
Method of reducing the pour-point and improving the flowability of petroleum oil or a fraction thereof by adding thereto a flowability-improving quantity of at least one copolymer of (a) an acrylic acid ester, a methacrylic acid ester, or a mixture of an acrylic acid ester and a methacrylic acid ester, and (b) not more than 20% by weight, based on the weight of the copolymer, of acrylic acid, methacrylic acid, or a mixture of acrylic acid and methacrylic acid, and wherein said esters in component (a) are esters of a C.sub.16 or higher alcohol or an alcohol mixture wherein at least 75% by weight thereof is one or more alcohols containing at least 16 carbon atoms; and the compositions resulting therefrom.
摘要:
The invention relates to the use of (A) esters of phosphoric acid and/or partial salts thereof with alkoxylated aliphatic, cycloaliphatic and/or aromatic alcohols and/or (B) fatty acid oligo-dialkanolamides as inhibitors against the formation of incrustations based on organic solids from liquid and/or gaseous hydrocarbon mixtures which are fluid and prone to form such incrustations. Preferred inhibitors having a surface-active character are capable of wetting, and especially of spreading on, solid work material surfaces also in the presence of the fluid hydrocarbon phase. They are particularly suitable as additives to crude oils and/or oil fractions susceptible of forming incrustations.
摘要:
A pour point depressant composition and a method for its use. The pour point depressant is a predominantly butadiene polymer epoxidized and then ring-opened with a C.sub.12-24 carboxylic acid, or ring-opened with an alcohol followed by esterification.
摘要:
A process useful for protecting metal surfaces against corrosion in is presented involving: (a) forming a corrosion inhibitor having a compound corresponding to formula (I): where R1, R2 and R3 independently of one another represent an alkyl or hydroxyalkyl group containing 1 to 4 carbon atoms, an aryl or alkylaryl group or a group corresponding to formula (II): A− is an anion, n is the number 2 or 3, p is a number of 1 to 3 and R5 is an alkyl or alkenyl group containing 7 to 23 carbon atoms and 0, 1, 2 or 3 double bonds, and R4 is a group corresponding to formula (II) or (III): where R1, R2 and R3 are as defined above and Z is a group —(CH2)m— or a group corresponding to formula (IV): m is an integer of 1 to 6, X is a group NH or an oxygen atom and D is a dimer fatty acid residue containing on average 36 to 54 carbon atoms; (b) combining the corrosion inhibitor with liquid aqueous, liquid non-aqueous or gaseous media; and (c) contacting the corrosion inhibitor with metal. The corrosion inhibitor used in the is biodegradable and shows low aquatic toxicity.
摘要:
The invention relates to a process for facilitating the disposal of flowable and pumpable working fluids based on emulsifiers containing W/O invert emulsions--more particularly corresponding auxiliaries of the type used in geological exploration, such as oil-based w/o invert drilling muds--and for the simplified cleaning of solid surfaces soiled therewith, if desired using flowable spraying aids, the process being characterized in that, by selecting and adapting the emulsifiers/emulsifier systems to the oil phase of the invert emulsion, temperature-controlled phase inversion is achieved at temperatures below the in-use temperatures of the w/o invert emulsions, but above the freezing point of the aqueous phase and in that disposal and cleaning are carried out at temperatures in and/or below the phase inversion temperature range. The invention also relates to the use of this process for the cleaning and disposal of roc cuttings covered with residual drilling mud from geological exploration during and/or preferably before their on-shore or off-shore dumping
摘要:
The invention relates to the use of at least predominantly linear hydrocarbon compounds olefinically unsaturated in the alpha-position with flashpoints of at least about 80.degree. as the oil phase or as part of the oil phase of oil- or water-based free-flowing borehole servicing preparations. Particular significance is attributed to corresponding drilling fluids which, together with the alpha-olefins, contain other oil phases from the field of borehole servicing preparations and are distinguished by ecological compatibility, being degradable under both aerobic and anaerobic conditions. Suitable mixture components for the oil phase are, in particular, oleophilic alcohols, ethers and corresponding esters selected from carboxylic acid esters and/or carbonic acid esters.
摘要:
A process is described for rock consolidation, e.g. in tunnel construction and mining, by injection of aqueous preparations of melamine resin condensates and/or urea formaldehyde condensates together with an acid curing agent. The process is characterized by the use of aqueous solutions of hydrogen sulfate salts, especially solutions of alkali and/or ammonium bisulfates, as curing agents. The curing agent solutions can contain additional auxiliary agents and active substances such as corrosion inhibitors, structurizers and adhesion agents. Preferred resin solutions for consolidation with these aqueous curing agents contain added zeolite NaA and/or hydrosodalite for increasing their serviceability, and especially for prolonging their storage life.
摘要:
Powder-form lubricant additives for water-based drilling fluids which contain from 95 to 30% by weight, based on the total weight of the powder, of highly disperse silicas, from 5 to 70% by weight, based on the total weight of the powder, of one or more fatty acid alkyl esters corresponding to the following general formula.R.sup.1 COOR.sup.2 (I)in which R.sup.1 is a straight-chain or branched, saturated or mono- or polyunsaturated C.sub.9 -C.sub.21 alkyl or alkenyl radical and R.sup.2 is a straight-chain or branched C.sub.1 -C.sub.12 alkyl radical, and/or polyesters obtainable by reaction of di-, oligo- or poly-hydroxy compounds with carboxylic acids and/or distillation residues from the transesterification of native fatty acid esters and, optionally, other additives known for lubricating purposes in quantities of from 0 to 20% by weight, based on the total weight of the powder, and to the use of these powder-form additives in drilling fluids for oil well and mine drilling in quantities of from 0.01 to 5% by weight, based on the total weight of the drilling fluid.