Esters of carboxylic acids of medium chain-length as a component of the
oil phase in invert drilling muds
    2.
    发明授权
    Esters of carboxylic acids of medium chain-length as a component of the oil phase in invert drilling muds 失效
    中链长度的羧酸酯作为反相钻井泥浆中油相的组分

    公开(公告)号:US5403822A

    公开(公告)日:1995-04-04

    申请号:US68563

    申请日:1993-05-27

    CPC分类号: C09K8/34

    摘要: The invention describes the use of selected esters, fluid at room temperature and with flash points above 80.degree. C., from monocarboxylic acids of synthetic and/or natural origin with 6 to 11 carbon atoms and mono- and/or polyfunctional alcohols as the oil phase or a component of the oil phase of invert drilling muds, which are suitable for environment-friendly development of petroleum and natural gas deposits and in a continuous oil phase contain a dispersed aqueous phase together with emulsifiers, weighting agents, fluid-loss additives and preferably further conventional additives. In a further embodiment the invention relates to invert-drilling fluids of the types mentioned, which are characterized in that the oil phase contains esters of monocarboxylic acids of synthetic and/or natural origin with 6 to 11 carbon atoms and with mono- and/or polyfunctional alcohols preferably in admixture with other components from the class of ecologically acceptable compounds.

    摘要翻译: 本发明描述了在室温下和闪点高于80℃的选择的酯,来自合成和/或天然来源的具有6至11个碳原子的一元羧酸和单和/或多官能醇作为油的用途 相位或反相钻井泥浆油相的组分,适用于石油和天然气沉积物的环境友好型开发,连续油相中含有分散的水相以及乳化剂,增重剂,流体损失添加剂和 优选进一步的常规添加剂。 在另一个实施方案中,本发明涉及所述类型的反向钻井液,其特征在于油相含有合成和/或天然来源的具有6至11个碳原子的一元羧酸酯和单 - 和/或 多官能醇优选与来自生态可接受的化合物类的其它组分混合。

    Method for protecting metal surfaces against corrosion in liquid or gaseous media
    6.
    发明授权
    Method for protecting metal surfaces against corrosion in liquid or gaseous media 失效
    保护金属表面免受液体或气体介质腐蚀的方法

    公开(公告)号:US06261346B1

    公开(公告)日:2001-07-17

    申请号:US09319144

    申请日:1999-07-29

    IPC分类号: C23F1114

    摘要: A process useful for protecting metal surfaces against corrosion in is presented involving: (a) forming a corrosion inhibitor having a compound corresponding to formula (I): where R1, R2 and R3 independently of one another represent an alkyl or hydroxyalkyl group containing 1 to 4 carbon atoms, an aryl or alkylaryl group or a group corresponding to formula (II): A− is an anion, n is the number 2 or 3, p is a number of 1 to 3 and R5 is an alkyl or alkenyl group containing 7 to 23 carbon atoms and 0, 1, 2 or 3 double bonds, and R4 is a group corresponding to formula (II) or (III): where R1, R2 and R3 are as defined above and Z is a group —(CH2)m— or a group corresponding to formula (IV):  m is an integer of 1 to 6, X is a group NH or an oxygen atom and D is a dimer fatty acid residue containing on average 36 to 54 carbon atoms; (b) combining the corrosion inhibitor with liquid aqueous, liquid non-aqueous or gaseous media; and (c) contacting the corrosion inhibitor with metal. The corrosion inhibitor used in the is biodegradable and shows low aquatic toxicity.

    摘要翻译: 提出了一种用于保护金属表面免受腐蚀的方法,涉及:(a)形成具有对应于式(I)的化合物的腐蚀抑制剂:其中R 1,R 2和R 3彼此独立地表示含有1至 4个碳原子,芳基或烷基芳基或对应于式(II)的基团:A-是阴离子,n是数2或3,p是1至3的数,R 5是含有 7至23个碳原子和0,1,2或3个双键,R4是与式(II)或(III)相应的基团:其中R1,R2和R3如上定义,Z是基团 - (CH2 )m-或对应于式(IV)的基团:m是1至6的整数,X是NH或氧原子,D是含有平均36至54个碳原子的二聚脂肪酸残基; (b)将腐蚀抑制剂与液体水性,液体非水性或气态介质结合; 和(c)使腐蚀抑制剂与金属接触。 所用的腐蚀抑制剂是可生物降解的,水生毒性低。

    Process for the facilitated waste disposal of working substances based
on water-in-oil invert emulsions
    7.
    发明授权
    Process for the facilitated waste disposal of working substances based on water-in-oil invert emulsions 失效
    基于油包水反相乳液促进废物处理工作物质的方法

    公开(公告)号:US6165946A

    公开(公告)日:2000-12-26

    申请号:US297481

    申请日:1999-04-30

    摘要: The invention relates to a process for facilitating the disposal of flowable and pumpable working fluids based on emulsifiers containing W/O invert emulsions--more particularly corresponding auxiliaries of the type used in geological exploration, such as oil-based w/o invert drilling muds--and for the simplified cleaning of solid surfaces soiled therewith, if desired using flowable spraying aids, the process being characterized in that, by selecting and adapting the emulsifiers/emulsifier systems to the oil phase of the invert emulsion, temperature-controlled phase inversion is achieved at temperatures below the in-use temperatures of the w/o invert emulsions, but above the freezing point of the aqueous phase and in that disposal and cleaning are carried out at temperatures in and/or below the phase inversion temperature range. The invention also relates to the use of this process for the cleaning and disposal of roc cuttings covered with residual drilling mud from geological exploration during and/or preferably before their on-shore or off-shore dumping

    摘要翻译: PCT No.PCT / EP97 / 05798 Sec。 371日期1999年4月30日 102(e)1999年4月30日PCT PCT 1997年10月21日PCT公布。 第WO98 / 18882号公报 日期1998年5月7日本发明涉及一种促进基于含有W / O反相乳液的乳化剂处理可流动和可泵送的工作流体的方法,更具体地说涉及在地质勘探中使用的类型的相应助剂,例如油基w / o 反转钻井泥浆 - 并且为了简化清洁其中污染的固体表面,如果需要,使用可流动的喷洒助剂,该方法的特征在于通过选择和适应乳化剂/乳化剂体系到反相乳液的油相,温度控制 在低于w / o反相乳液的使用温度但高于水相的凝固点的温度下实现相转化,并且处理和清洗在相转变温度范围内和/或低于相转变温度范围的温度下进行 。 本发明还涉及这种方法用于清洁和处理在其在岸或离岸倾倒期间和/或优选在其岸上倾倒之前的地质勘探中覆盖有残留钻井泥浆的罗切切割

    Free-flowing borehole servicing preparations containing linear
.alpha.-olefins, more patricularly corresponding drilling fluids
    8.
    发明授权
    Free-flowing borehole servicing preparations containing linear .alpha.-olefins, more patricularly corresponding drilling fluids 失效
    自由流动的钻孔维护准备,包含线性α-烯烃,更多的是相应的钻井液

    公开(公告)号:US5869434A

    公开(公告)日:1999-02-09

    申请号:US750829

    申请日:1996-12-13

    CPC分类号: C09K8/34 C09K8/26 Y10S507/905

    摘要: The invention relates to the use of at least predominantly linear hydrocarbon compounds olefinically unsaturated in the alpha-position with flashpoints of at least about 80.degree. as the oil phase or as part of the oil phase of oil- or water-based free-flowing borehole servicing preparations. Particular significance is attributed to corresponding drilling fluids which, together with the alpha-olefins, contain other oil phases from the field of borehole servicing preparations and are distinguished by ecological compatibility, being degradable under both aerobic and anaerobic conditions. Suitable mixture components for the oil phase are, in particular, oleophilic alcohols, ethers and corresponding esters selected from carboxylic acid esters and/or carbonic acid esters.

    摘要翻译: PCT No.PCT / EP95 / 02143 Sec。 371日期1996年12月13日第 102(e)日期1996年12月13日PCT归档1995年6月6日PCT公布。 公开号WO95 / 34610 日期1995年12月21日本发明涉及至少主要是在α-位上烯属不饱和的烃类化合物的使用,其中至少约80℃的闪点为油相或作为油相或水 - 油的油相的一部分, 基于自由流动的钻孔维修准备。 特别的意义归因于相应的钻井液,其与α-烯烃一起含有来自钻孔维修制剂领域的其他油相,并且通过生态相容性来区分,在有氧和无氧条件下都是可降解的。 用于油相的合适的混合物组分特别是亲油醇,醚和选自羧酸酯和/或碳酸酯的相应的酯。

    Process for rock consolidation and/or cavity filling e.g. in tunnel
construction and mining
    9.
    发明授权
    Process for rock consolidation and/or cavity filling e.g. in tunnel construction and mining 失效
    用于岩石固结和/或空腔填充的方法,例如 在隧道施工和采矿

    公开(公告)号:US5322392A

    公开(公告)日:1994-06-21

    申请号:US853755

    申请日:1992-07-29

    CPC分类号: C09K8/5086 C09K17/48

    摘要: A process is described for rock consolidation, e.g. in tunnel construction and mining, by injection of aqueous preparations of melamine resin condensates and/or urea formaldehyde condensates together with an acid curing agent. The process is characterized by the use of aqueous solutions of hydrogen sulfate salts, especially solutions of alkali and/or ammonium bisulfates, as curing agents. The curing agent solutions can contain additional auxiliary agents and active substances such as corrosion inhibitors, structurizers and adhesion agents. Preferred resin solutions for consolidation with these aqueous curing agents contain added zeolite NaA and/or hydrosodalite for increasing their serviceability, and especially for prolonging their storage life.

    摘要翻译: PCT No.PCT / EP90 / 02026 Sec。 371日期:1992年7月29日 102(e)日期1992年7月29日PCT 1990年11月26日PCT PCT。 公开号WO91 / 08271 日期1991年6月13日。描述了用于岩石固结的方法,例如 在隧道施工和采矿中,通过与酸固化剂一起注入三聚氰胺树脂缩合物和/或脲甲醛缩合物的水性制剂。 该方法的特征在于使用硫酸氢盐的水溶液,特别是碱和/或硫酸铵铵的溶液作为固化剂。 固化剂溶液可以含有另外的辅助剂和活性物质如腐蚀抑制剂,结构剂和粘合剂。 用于与这些水性固化剂固结的优选树脂溶液含有添加的沸石NaA和/或氢硅酸盐以提高其可使用性,特别是延长其储存寿命。

    Powder-form lubricant additives for water-based drilling fluids
    10.
    发明授权
    Powder-form lubricant additives for water-based drilling fluids 失效
    用于水性钻井液的粉末状润滑剂添加剂

    公开(公告)号:US4802998A

    公开(公告)日:1989-02-07

    申请号:US70858

    申请日:1987-07-08

    IPC分类号: C09K8/06 C09K7/02

    CPC分类号: C09K8/06

    摘要: Powder-form lubricant additives for water-based drilling fluids which contain from 95 to 30% by weight, based on the total weight of the powder, of highly disperse silicas, from 5 to 70% by weight, based on the total weight of the powder, of one or more fatty acid alkyl esters corresponding to the following general formula.R.sup.1 COOR.sup.2 (I)in which R.sup.1 is a straight-chain or branched, saturated or mono- or polyunsaturated C.sub.9 -C.sub.21 alkyl or alkenyl radical and R.sup.2 is a straight-chain or branched C.sub.1 -C.sub.12 alkyl radical, and/or polyesters obtainable by reaction of di-, oligo- or poly-hydroxy compounds with carboxylic acids and/or distillation residues from the transesterification of native fatty acid esters and, optionally, other additives known for lubricating purposes in quantities of from 0 to 20% by weight, based on the total weight of the powder, and to the use of these powder-form additives in drilling fluids for oil well and mine drilling in quantities of from 0.01 to 5% by weight, based on the total weight of the drilling fluid.

    摘要翻译: 水基钻井液的粉末状润滑剂添加剂,基于粉末的总重量为95〜30重量%,高分散二氧化硅为5〜70重量%,以总重量计 一种或多种脂肪酸烷基酯对应于下列通式的粉末。 R1COOR2(I)其中R1是直链或支链饱和或单或多不饱和C 9 -C 21烷基或烯基,R 2是直链或支链C 1 -C 12烷基,和/或可通过反应获得的聚酯 的二羟基,低聚或多羟基化合物与羧酸和/或来自天然脂肪酸酯和任选的其它已知用于润滑目的的其它添加剂的酯交换反应的羧酸和/或蒸馏残余物,其量为0至20重量%,基于 基于钻井液的总重量,粉末的总重量以及这些粉末形式的添加剂在油井和钻井钻井液中的使用量为0.01至5重量%。