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1.发明授权公开(公告)号：US08742000B2
公开(公告)日：2014-06-03
申请号：US13002302
申请日：2009-11-26
Applicant: Zhefeng Xu , Dongsheng Mei , Taixiong Guo , Quan Xu , Yong Chen , Xingde Cheng , Guoan Li , Aiping Zhang
Inventor： Zhefeng Xu , Dongsheng Mei , Taixiong Guo , Quan Xu , Yong Chen , Xingde Cheng , Guoan Li , Aiping Zhang
CPC classification number: C23C22/23 , C08K3/36 , C09D5/08 , C09D5/18 , C09D7/61 , C09D7/67 , C23C22/17 , C23C22/36 , C23C2222/20
Abstract: A coating composition is provided, the starting materials of which comprise nano SiO2, film-forming substance, film-forming aid, accelerator, acid, and water. The composition has pH of 3-9. A passivated zinc-plated material is also provided. The zinc-plated material comprises zinc-plated substrate and passivated coat adhered to the surface of the zinc-plated substrate, wherein the passivated coat is formed by curing the coating composition. The coating composition can impart to the zinc-plated material excellent corrosion resistance, water resistance, high temperature resistance, surface conductivity, and adhesion to the zinc-plated substrate. Additionally, the coating composition contains no Cr6+, and satisfies the requirement of EU RoHS Directive.
Abstract translation: 提供了一种涂料组合物，其原料包括纳米SiO2，成膜物质，成膜助剂，促进剂，酸和水。 该组合物的pH值为3-9。 还提供钝化镀锌材料。 镀锌材料包括镀锌基板和附着在镀锌基板表面上的钝化涂层，其中通过固化涂层组合物形成钝化涂层。 涂料组合物可以赋予镀锌材料优异的耐腐蚀性，耐水性，耐高温性，表面导电性和与镀锌基材的粘附性。 此外，涂料组合物不含Cr6 +，并且满足欧盟RoHS指令的要求。
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Patent Agency Ranking
2.发明申请公开(公告)号：US20120052312A1
公开(公告)日：2012-03-01
申请号：US13002302
申请日：2009-11-26
Applicant: Zhefeng Xu , Dongsheng Mei , Taixiong Guo , Quan Xu , Yong Chen , Xingde Cheng , Guoan Li , Aiping Zhang
Inventor： Zhefeng Xu , Dongsheng Mei , Taixiong Guo , Quan Xu , Yong Chen , Xingde Cheng , Guoan Li , Aiping Zhang
CPC classification number: C23C22/23 , C08K3/36 , C09D5/08 , C09D5/18 , C09D7/61 , C09D7/67 , C23C22/17 , C23C22/36 , C23C2222/20
Abstract: A coating composition is provided, the starting materials of which comprise nano SiO2, film-forming substance, film-forming aid, accelerator, acid, and water. The composition has pH of 3-9. A passivated zinc-plated material is also provided. The zinc-plated material comprises zinc-plated substrate and passivated coat adhered to the surface of the zinc-plated substrate, wherein the passivated coat is formed by curing the coating composition. The coating composition can impart to the zinc-plated material excellent corrosion resistance, water resistance, high temperature resistance, surface conductivity, and adhesion to the zinc-plated substrate. Additionally, the coating composition contains no Cr6+, and satisfies the requirement of EU RoHS Directive.
Abstract translation: 提供了一种涂料组合物，其原料包括纳米SiO2，成膜物质，成膜助剂，促进剂，酸和水。 该组合物的pH值为3-9。 还提供钝化镀锌材料。 镀锌材料包括镀锌基板和附着在镀锌基板表面上的钝化涂层，其中通过固化涂层组合物形成钝化涂层。 涂料组合物可以赋予镀锌材料优异的耐腐蚀性，耐水性，耐高温性，表面导电性和与镀锌基材的粘附性。 此外，涂料组合物不含Cr6 +，并且满足欧盟RoHS指令的要求。
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3.发明授权Metal protection coating, hot-dip Zn metallic material and hot-dip Al—Zn metallic material using the same 有权金属保护涂层，热浸Zn金属材料和使用其的热浸Al-Zn金属材料公开(公告)号：US09181447B2
公开(公告)日：2015-11-10
申请号：US13619002
申请日：2012-09-14
Applicant: Zhefeng Xu , Dongsheng Mei , Yong Chen , Quan Xu , Yan Lou , Yilin Zhou
Inventor： Zhefeng Xu , Dongsheng Mei , Yong Chen , Quan Xu , Yan Lou , Yilin Zhou
IPC: C09D101/28 , C09D127/12 , C09D167/00 , C23C2/06 , C23C2/12 , C23C2/26 , C23C2/28 , C23C26/00 , C09D5/08 , C09D5/16 , C09D7/12 , B05D5/00
CPC classification number: C09D101/28 , B05D5/00 , B05D2202/10 , B05D2350/65 , C09D5/084 , C09D5/1618 , C09D5/1675 , C09D7/61 , C09D7/65 , C09D7/67 , C09D101/284 , C09D101/286 , C09D127/12 , C09D167/00 , C23C2/06 , C23C2/12 , C23C2/26 , C23C2/28 , C23C26/00 , Y10T428/265 , C08K3/36 , C08K5/5435 , C08L1/26 , C08K5/54 , C08L1/08
Abstract: A metal protective coating is provided, which is obtained by mixing homogeneously a raw mixture, which contains water soluble silicate, promoter, silane coupling agent, silicon oxide packing, water soluble film formation resin, and water; wherein, the promoter is at least one selected from the group consisting of methyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, carboxymethyl-hydroxyethyl cellulose, and their soluble salts; the silane coupling agent contains a first silane derivative shown in formula (1), wherein, R1, R2, and R3 are methoxyl or ethyoxyl respectively, and n is an integer with the range of 1-4. A hot-dip Zn metallic material and a hot-dip Al—Zn alloy metallic material are further provided. The protective film formed by the metal protective coating as provided has outstanding corrosion resistance, water resistance, thermal resistance, and fingerprint resistance properties.
Abstract translation: 提供金属保护涂层，其通过均匀混合含有水溶性硅酸盐，促进剂，硅烷偶联剂，氧化硅填料，水溶性成膜树脂和水的原料混合物获得; 其中，助催化剂是选自甲基纤维素，羧甲基纤维素，羧乙基纤维素，羧甲基羟乙基纤维素及其可溶性盐中的至少一种; 硅烷偶联剂含有式（1）所示的第一硅烷衍生物，其中，R1，R2和R3分别是甲氧基或乙氧基，n是1-4的整数。 还提供热浸锌金属材料和热浸Al-Zn合金金属材料。 由金属保护涂层形成的保护膜具有优异的耐腐蚀性，耐水性，耐热性和耐指纹性。
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4.发明授权Passivant for hot-dip Al-Zn-coated sheet and preparation method and use thereof 有权热浸镀铝锌板的钝化剂及其制备方法和用途公开(公告)号：US08728628B2
公开(公告)日：2014-05-20
申请号：US13126751
申请日：2010-04-07
Applicant: Ping Yuan , Taixiong Guo , Quan Xu , Dan Yu , Yong Zhang , Zhefeng Xu , Yilin Zhou
Inventor： Ping Yuan , Taixiong Guo , Quan Xu , Dan Yu , Yong Zhang , Zhefeng Xu , Yilin Zhou
Abstract: The present invention provides a passivant for hot-dip Al—Zn-coated sheet of which the raw materials include: 2˜6 parts by weight of water soluble molybdate, 4˜12 parts by weight of water soluble manganese salt, 50˜100 parts by weight of basic silica sol and 50˜100 parts by weight of water soluble organic resin. The present invention also provides a method to prepare the passivant for hot-dip Al—Zn-coated sheet including the following steps: adding and dissolving water soluble molybdate and water soluble manganese salt into deionized water; adding basic silica sol into the solution and mixing well; adding water soluble organic resin into the solution and mixing well; regulating the pH value of the solution to 5˜8 by using phosphoric acid. The present invention also provides a hot-dip Al—Zn-coated sheet treated with the present passivant and a method to passivate hot-dip Al—Zn-coated sheet.
Abstract translation: 本发明提供一种热浸镀铝锌板的钝化剂，其原料包括：2〜6重量份水溶性钼酸盐，4〜12重量份水溶性锰盐，50〜100份 的碱性二氧化硅溶胶和50〜100重量份的水溶性有机树脂。 本发明还提供了一种制备用于热浸镀铝锌板的钝化剂的方法，包括以下步骤：将水溶性钼酸盐和水溶性锰盐加入并溶解于去离子水中; 将碱性硅溶胶加入溶液中并充分混合; 将水溶性有机树脂加入溶液中并充分混合; 通过使用磷酸将溶液的pH值调节至5〜8。 本发明还提供了用本发明的钝化剂处理的热浸镀铝锌镀层以及钝化热镀Al-Zn涂层的方法。
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5.发明申请METAL PROTECTION COATING, HOT-DIP ZN METALLIC MATERIAL AND HOT-DIP AL-ZN METALLIC MATERIAL USING THE SAME 有权金属保护涂层，热镀锌ZN金属材料和热镀铝合金材料公开(公告)号：US20130078456A1
公开(公告)日：2013-03-28
申请号：US13619002
申请日：2012-09-14
Applicant: Zhefeng Xu , Dongsheng Mei , Yong Chen , Quan Xu , Yan Lou , Yilin Zhou
Inventor： Zhefeng Xu , Dongsheng Mei , Yong Chen , Quan Xu , Yan Lou , Yilin Zhou
IPC: C09D133/04 , B32B33/00 , C09D175/04 , B32B15/08 , C08K3/34 , C09D133/08
CPC classification number: C09D101/28 , B05D5/00 , B05D2202/10 , B05D2350/65 , C09D5/084 , C09D5/1618 , C09D5/1675 , C09D7/61 , C09D7/65 , C09D7/67 , C09D101/284 , C09D101/286 , C09D127/12 , C09D167/00 , C23C2/06 , C23C2/12 , C23C2/26 , C23C2/28 , C23C26/00 , Y10T428/265 , C08K3/36 , C08K5/5435 , C08L1/26 , C08K5/54 , C08L1/08
Abstract: A metal protective coating is provided, which is obtained by mixing homogeneously a raw mixture, which contains water soluble silicate, promoter, silane coupling agent, silicon oxide packing, water soluble film formation resin, and water; wherein, the promoter is at least one selected from the group consisting of methyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, carboxymethyl-hydroxyethyl cellulose, and their soluble salts; the silane coupling agent contains a first silane derivative shown in formula (1), wherein, R1, R2, and R3 are methoxyl or ethyoxyl respectively, and n is an integer with the range of 1-4. A hot-dip Zn metallic material and a hot-dip Al—Zn alloy metallic material are further provided. The protective film formed by the metal protective coating as provided has outstanding corrosion resistance, water resistance, thermal resistance, and fingerprint resistance properties.
Abstract translation: 提供金属保护涂层，其通过均匀混合含有水溶性硅酸盐，促进剂，硅烷偶联剂，氧化硅填料，水溶性成膜树脂和水的原料混合物获得; 其中，助催化剂是选自甲基纤维素，羧甲基纤维素，羧乙基纤维素，羧甲基羟乙基纤维素及其可溶性盐中的至少一种; 硅烷偶联剂含有式（1）所示的第一硅烷衍生物，其中，R1，R2和R3分别是甲氧基或乙氧基，n是1-4的整数。 还提供热浸锌金属材料和热浸Al-Zn合金金属材料。 由金属保护涂层形成的保护膜具有优异的耐腐蚀性，耐水性，耐热性和耐指纹性。
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6.发明申请PASSIVANT FOR HOT-DIP AL-ZN-COATED SHEET AND PREPARATION METHOD AND USE THEREOF 有权热镀铝合金薄片及其制备方法及其用途公开(公告)号：US20120135267A1
公开(公告)日：2012-05-31
申请号：US13126751
申请日：2010-04-07
Applicant: Ping Yuan , Taixiong Guo , Quan Xu , Dan Yu , Yong Zhang , Zhefeng Xu , Yilin Zhou
Inventor： Ping Yuan , Taixiong Guo , Quan Xu , Dan Yu , Yong Zhang , Zhefeng Xu , Yilin Zhou
Abstract: The present invention provides a passivant for hot-dip Al—Zn-coated sheet of which the raw materials include: 2˜6 parts by weight of water soluble molybdate, 4˜12 parts by weight of water soluble manganese salt, 50˜100 parts by weight of basic silica sol and 50˜100 parts by weight of water soluble organic resin. The present invention also provides a method to prepare the passivant for hot-dip Al—Zn-coated sheet including the following steps: adding and dissolving water soluble molybdate and water soluble manganese salt into deionized water; adding basic silica sol into the solution and mixing well; adding water soluble organic resin into the solution and mixing well; regulating the pH value of the solution to 5˜8 by using phosphoric acid. The present invention also provides a hot-dip Al—Zn-coated sheet treated with the present passivant and a method to passivate hot-dip Al—Zn-coated sheet.
Abstract translation: 本发明提供一种热浸镀铝锌板的钝化剂，其原料包括：2〜6重量份水溶性钼酸盐，4〜12重量份水溶性锰盐，50〜100份 的碱性二氧化硅溶胶和50〜100重量份的水溶性有机树脂。 本发明还提供了一种制备用于热浸镀铝锌板的钝化剂的方法，包括以下步骤：将水溶性钼酸盐和水溶性锰盐加入并溶解于去离子水中; 将碱性硅溶胶加入溶液中并充分混合; 将水溶性有机树脂加入溶液中并充分混合; 通过使用磷酸将溶液的pH值调节至5〜8。 本发明还提供了用本发明的钝化剂处理的热浸镀铝锌镀层以及钝化热镀Al-Zn涂层的方法。
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