公开(公告)号：US10138402B2

公开(公告)日：2018-11-27

申请号：US15327666

申请日：2015-06-11

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C08G63/672 ,  C09K3/16

摘要： Provided are: an antistatic agent and an antistatic agent composition which are capable of providing excellent antistatic effect in a small amount and have sufficient persistence and wiping resistance without impairing the intrinsic physical properties of a resin; and an antistatic resin composition and a molded article using the same. The antistatic agent includes a polymer compound (E) having a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and an epoxy compound (D) having two or more epoxy groups are bound via ester bonds: —CH2—CH2—O—  (1).

公开(公告)号：US10100239B2

公开(公告)日：2018-10-16

申请号：US14760570

申请日：2014-01-22

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C09K3/16 ,  C08G81/00 ,  C08G63/91 ,  C08L87/00

摘要： Provided are: an antistatic agent which is capable of imparting excellent antistatic effect in a small amount and has sufficient persistence and wiping resistance; an antistatic agent composition; an antistatic resin composition; and a molded article. The antistatic agent comprises a polymer compound (E) having a structure in which a block polymer (C) and an epoxy compound (D) are bound via an ester bond formed by a carboxyl group of the block polymer (C) and an epoxy group of the epoxy compound (D), the block polymer (C) having a structure comprising carboxyl groups at both ends, in which structure a block constituted by a polyester (A) having carboxyl groups at both ends and a block constituted by a compound (B) having hydroxyl groups at both ends are repeatedly and alternately bound via ester bonds formed by the carboxyl groups and the hydroxyl groups, and the epoxy compound (D) comprising two or more epoxy groups.

公开(公告)号：US10308852B2

公开(公告)日：2019-06-04

申请号：US15563395

申请日：2016-03-07

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Chun Cui ,  Kazukiyo Nomura

IPC分类号： C09K3/16 ,  C08L23/00 ,  D04H1/4291 ,  D04H3/14 ,  D01F6/46 ,  C08L101/00 ,  C08G63/672 ,  C08L23/06 ,  C08G63/66

摘要： Provided are: an antistatic resin composition for containers and pipes of organic solvents, which has long-lasting and sufficient antistaticity and whose antistatic performance is not impaired even when the composition is in contact with an organic solvent for a long period of time; and a container and a pipe for organic solvents, which include the same.The antistatic resin composition for containers and pipes of organic solvents contains 3 to 25 parts by mass of at least one polymer compound (E) with respect to 100 parts by mass of a thermoplastic resin, wherein the polymer compound (E) has a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which includes at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and an epoxy compound (D) having two or more epoxy groups are bound via ester bonds: —CH2—CH2—O—  (1).

公开(公告)号：US10385162B2

公开(公告)日：2019-08-20

申请号：US15537114

申请日：2015-11-19

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C08G63/16 ,  C08L23/00 ,  C08L67/02 ,  C08G59/22 ,  C08G65/08 ,  C08K3/34 ,  C08L23/08 ,  C08L23/10 ,  C08L23/14 ,  C08L77/02

摘要： Provided: polyolefin resin composition excellent in antistatic properties with sufficient persistence and wiping resistance, without impairment of intrinsic mechanical properties; and an automotive interior/exterior material containing the same. The polyolefin resin composition contains: 50 to 90 parts by mass of polyolefin resin; 3 to 40 parts by mass of thermoplastic elastomer; 3 to 30 parts by mass of filler, and an antistatic agent of a polymer compound (E) in an amount of 3 to 20 parts by mass with respect to a total amount of 100 parts by mass of the polyolefin resin, thermoplastic elastomer and filler, wherein the polymer compound (E) has a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) containing at least one group of Formula (1) and having hydroxyl groups at both ends, and an epoxy compound (D) having two or more epoxy groups are bound via ester bonds: —CH2—CH2—O—  (1).

公开(公告)号：US10323166B2

公开(公告)日：2019-06-18

申请号：US15563289

申请日：2016-03-08

申请人： ADEKA CORPORATION

发明人： Chun Cui ,  Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C09K3/16 ,  C08K5/521 ,  C08L23/00 ,  C08L67/02 ,  C07F5/06 ,  C08K5/527 ,  C08K5/56 ,  C08L23/02 ,  C08K5/098 ,  C08K5/00

摘要： Provided are: a resin additive composition capable of imparting excellent antistatic effect in a small amount, and an antistatic thermoplastic resin composition. The resin additive composition contains two or more selected from aromatic metal phosphates (H) represented by the following Formula (3) or (4) in an amount of 0.001 to 50 parts by mass with respect to 100 parts by mass of a polymer compound (E). The polymer compound (E) has a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which contains at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and an epoxy compound (D) having two or more epoxy groups are bound via ester bonds:

公开(公告)号：US10301519B2

公开(公告)日：2019-05-28

申请号：US15505429

申请日：2015-08-05

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C09K3/16 ,  C08G63/668 ,  C08L67/00 ,  C08G63/199 ,  C08G63/672 ,  C08L55/02

摘要： Provided are: an antistatic agent and an antistatic agent composition which are capable of providing excellent antistatic effect in a small amount and have sufficient persistence and wiping resistance; and an antistatic resin composition and a molded article using the same.The antistatic agent includes a polymer compound (E) having a structure in which a diol, a dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and a polycarboxylic acid compound (D) are bound via ester bonds: —CH2—CH2—O—  (1).

公开(公告)号：US10053536B2

公开(公告)日：2018-08-21

申请号：US15540072

申请日：2015-12-08

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C08K3/16 ,  C08G63/672 ,  C08K5/098 ,  C08K5/42 ,  C08L101/00 ,  C08L23/00 ,  C08L25/00 ,  C08L67/02 ,  C09K3/16

CPC分类号： C08G63/672 ,  C08K3/16 ,  C08K5/098 ,  C08K5/42 ,  C08L23/00 ,  C08L25/00 ,  C08L67/02 ,  C08L101/00 ,  C09K3/16

摘要： Provided are: an antistatic resin composition which not only has long-lasting and sufficient antistaticity and shows hardly any ion elution when made into a molded article but also is suitable for containers and packaging materials for storage and transport of electrical/electronic components; and a container and a packaging material which comprise the same. The antistatic resin composition includes, with respect to 100 parts by mass of a synthetic resin, 3 to 20 parts by mass of at least one polymer compound (E) and 0.1 to 5 parts by mass of at least one alkali metal salt (F). The polymer compound (E) has a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and a compound (D) having a reactive functional group are bound via ester bonds, or ester bonds and amide bonds: —CH2—CH2—O—  (1).

公开(公告)号：US10227447B2

公开(公告)日：2019-03-12

申请号：US15511799

申请日：2015-08-05

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C08G63/02 ,  C08G63/672 ,  C09K3/16 ,  C08G63/668 ,  C08L67/00 ,  C08L101/00 ,  C08G81/00 ,  C08L23/12 ,  C08L23/14

摘要： Provided are: an antistatic agent and an antistatic agent composition which are capable of providing excellent antistatic effect in a small amount and have sufficient persistence and wiping resistance without impairing the intrinsic physical properties of a resin; and an antistatic resin composition and a molded article using the same.The antistatic agent includes a polymer compound (E) having a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and a polyhydric alcohol (D) having three or more hydroxyl groups are bound via ester bonds: —CH2—CH2—O—  (1).

公开(公告)号：US09580545B2

公开(公告)日：2017-02-28

申请号：US14778163

申请日：2014-03-18

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C08G63/668 ,  C08G63/672 ,  C08L23/12 ,  C08L25/06

CPC分类号： C08G63/668 ,  C08G63/46 ,  C08G63/672 ,  C08L23/12 ,  C08L25/06 ,  C08L67/025 ,  C08L2201/04 ,  C08L23/00

摘要： Provided are: an antistatic agent which is capable of imparting excellent antistatic effect in a small amount and has sufficient persistence and wiping resistance; an antistatic agent composition; an antistatic resin composition; and a molded article.The antistatic agent comprises a polymer compound (E) having a structure in which a block polymer (C) and a polyhydric alcohol compound (D) are bound via an ester bond formed by a carboxyl group of the block polymer (C) and a hydroxyl group of the polyhydric alcohol compound (D), the block polymer (C) having a structure comprising carboxyl groups at both ends, in which structure a block constituted by a polyester (A) having carboxyl groups at both ends and a block constituted by a compound (B) having hydroxyl groups at both ends are repeatedly and alternately bound via ester bonds formed by the carboxyl and hydroxyl groups, and the polyhydric alcohol compound (D) comprising three or more hydroxyl groups.

摘要翻译： 抗静电剂包括具有嵌段聚合物（C）和多元醇化合物（D）通过嵌段聚合物（C）的羧基形成的酯键与羟基的聚合物（E）结合的高分子化合物 多元醇化合物（D），两末端具有羧基结构的嵌段聚合物（C），由两端具有羧基的聚酯（A）和由两端构成的嵌段构成的嵌段 通过由羧基和羟基形成的酯键和包含三个或更多个羟基的多元醇化合物（D）反复交替地结合在两端具有羟基的化合物（B）。

公开(公告)号：US20160289375A1

公开(公告)日：2016-10-06

申请号：US14778163

申请日：2014-03-18

申请人： ADEKA CORPORATION

发明人： Tatsuhito Nakamura ,  Kazukiyo Nomura

IPC分类号： C08G63/672 ,  C08K3/16 ,  C08L25/12 ,  C08L23/14 ,  C08L23/12 ,  C08G81/00 ,  C08K5/42

CPC分类号： C08G63/668 ,  C08G63/46 ,  C08G63/672 ,  C08L23/12 ,  C08L25/06 ,  C08L67/025 ,  C08L2201/04 ,  C08L23/00

摘要： Provided are: an antistatic agent which is capable of imparting excellent antistatic effect in a small amount and has sufficient persistence and wiping resistance; an antistatic agent composition; an antistatic resin composition; and a molded article.The antistatic agent comprises a polymer compound (E) having a structure in which a block polymer (C) and a polyhydric alcohol compound (D) are bound via an ester bond formed by a carboxyl group of the block polymer (C) and a hydroxyl group of the polyhydric alcohol compound (D), the block polymer (C) having a structure comprising carboxyl groups at both ends, in which structure a block constituted by a polyester (A) having carboxyl groups at both ends and a block constituted by a compound (B) having hydroxyl groups at both ends are repeatedly and alternately bound via ester bonds formed by the carboxyl and hydroxyl groups, and the polyhydric alcohol compound (D) comprising three or more hydroxyl groups.

摘要翻译： 抗静电剂包括具有嵌段聚合物（C）和多元醇化合物（D）通过嵌段聚合物（C）的羧基形成的酯键与羟基的聚合物（E）结合的高分子化合物 多元醇化合物（D），两末端具有羧基结构的嵌段聚合物（C），由两端具有羧基的聚酯（A）和由两端构成的嵌段构成的嵌段 通过由羧基和羟基形成的酯键和包含三个或更多个羟基的多元醇化合物（D）反复交替地结合在两端具有羟基的化合物（B）。