公开(公告)号：US3892526A

公开(公告)日：1975-07-01

申请号：US30238472

申请日：1972-10-30

Applicant: ALLIED CHEM

Inventor： LOFQUIST ROBERT ALDEN ,  SAUNDERS PETER REGINALD

IPC: D06M13/35 ,  D06M13/385 ,  D06P1/52 ,  D06P1/642 ,  D06P3/24 ,  D06P5/02

CPC classification number: D06P3/24 ,  D06M13/35 ,  D06M13/385 ,  D06P1/52 ,  D06P1/642 ,  Y10S8/21 ,  Y10S8/924 ,  Y10T428/31725

Abstract: When from about 0.3 to about 8% of tertiary amines formed by the reaction between I. A. a monoepoxide of greater than four carbons but not styrene oxide and B. a primary amine, a diprimary amine, a secondary amine, a disecondary amine, a primary-secondary diamine, a primarytertiary diamine, a secondary-tertiary diamine, a polyamine, and ammonia; or II. A. an alkyl monoepoxide of four or fewer carbons or styrene oxide, and B. a secondary amine, a disecondary amine, a secondary-tertiary diamine, a primary-tertiary diamine, or a polyamine having greater than two carbons per nitrogen or III. A. styrene oxide and B. ammonia ARE COATED ON NYLON FIBER, OR ARE ADDED TO THE DYEBATH IMPROVED DYEFASTNESS TO OZONE IS OBTAINED COMPARED TO AN UNTREATED DYED NYLON FIBER.

Abstract translation: 当通过I反应形成的叔胺的约0.3至约8％时。

公开(公告)号：US3892525A

公开(公告)日：1975-07-01

申请号：US30238572

申请日：1972-10-30

Applicant: ALLIED CHEM

Inventor： LOFQUIST ROBERT ALDEN

IPC: D06P1/52 ,  D06P1/642 ,  D06P3/24 ,  D06P5/02

CPC classification number: D06P3/24 ,  D06P1/52 ,  D06P1/642 ,  Y10T428/31739

Abstract: When from about 0.3% to about 8% of tertiary amines formed by the reaction between I (A) diepoxides and/or polyepoxides and (B) secondary amines, or between II (A) diepoxides and (B) ammonia, primary amines, and/or primary tertiary diamines ARE COATED ON NYLON FIBER, OR ARE ADDED TO THE DYEBATH OR ARE COATED ON DYED FIBERS, IMPROVED DYEFASTNESS TO OZONE IS OBTAINED COMPARED TO AN UNTREATED DYED NYLON FIBER.

Abstract translation: 当通过I（A）二环氧化物和/或聚环氧化物和（B）仲胺之间或II（A）二环氧化物和（B）氨，伯胺和/或其混合物之间的反应形成的叔胺的约0.3％至约8％ /或初级叔二胺被涂在尼龙纤维上，或被添加到染色体上或涂在染色纤维上，改善对臭氧的去污效果与未经染色的尼龙纤维相比较。

公开(公告)号：US3898200A

公开(公告)日：1975-08-05

申请号：US47847474

申请日：1974-06-12

Applicant: ALLIED CHEM

Inventor： LOFQUIST ROBERT ALDEN

IPC: C08G69/02 ,  C08G20/18

CPC classification number: C08G69/02

Abstract: A cationic-dyeable polyamide, polymerized from omega aminocarboxylic acids or their lactams, of improved physical properties can be made by using from 0.25 to 0.85 mole percent (based on the polyamide) of the sodium salt of a sulfonated dicarboxylic acid such as 5-sulfoisophthalic acid and 0.07 to 0.65 mole percent of an N-sulfoalkyl alkyldiamine such as N-(4sulfobutyl)hexamethylenediamine, or N-(2-sulfoethyl)mxylylenediamine. A polyamide results containing the respectively same number of sulfo groups, but with less diluent and consequently having a higher melting point. The diacid can be a sulfonate derivative of a phthalic acid, or of fluorene, etc. The diamine can be a sulfonate derivative of hexamethylenediamine, metaxylylenediamine, etc. The use of the combination of additives eliminates the necessity of adding a diamine or dicarboxylic acid to achieve full polymerization.

Abstract translation: 由ω-氨基羧酸或其内酰胺聚合的具有改善的物理性能的阳离子可染性聚酰胺可以通过使用0.25至0.85摩尔％（基于聚酰胺）磺化二羧酸的钠盐如5- 磺基间苯二甲酸和0.07〜0.65摩尔％的N-磺基烷基烷基二胺如N-（4-磺丁基）六亚甲基二胺或N-（2-磺基乙基）间苯二甲胺。 聚酰胺结果含有相同数量的磺基，但稀释剂较少，因此具有较高的熔点。 二酸可以是邻苯二甲酸或芴等的磺酸衍生物。二胺可以是六亚甲基二胺，间苯二甲胺等的磺酸酯衍生物。使用这些添加剂的组合不需要将二胺或二羧酸加入到 实现全聚合。

公开(公告)号：US3890286A

公开(公告)日：1975-06-17

申请号：US42677573

申请日：1973-12-20

Applicant: ALLIED CHEM

Inventor： BINGHAM ALEX JOHN ,  HAYLOCK JOHN CHRISTOPHER ,  LOFQUIST ROBERT ALDEN

IPC: C08G67/04 ,  C08G69/16 ,  C08G69/48 ,  D01F6/60 ,  C08G20/14

CPC classification number: C08G69/48 ,  C08G67/04 ,  C08G69/16 ,  D01F6/60

Abstract: It has been suggested that a high strength polycaproamide fiber having excess number of carboxyl end groups over amino end groups can be produced by melt spinning a polymer prepared by polymerizing e-caprolactam and reacting the polymer with a dibasic carboxylic acid containing at least six carbon atoms. However, with incorporation of this dicarboxylic acid reactant in continuous operation, serious problems have been encountered in melt-spinning of the polymer due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the fiber can be greatly reduced by utilizing certain polyanhydrides of dicarboxylic acid and reacting the polyanhydride at the end of the polymerization. Moreover, dyeing properties of the fiber may be more readily controlled.

Abstract translation: 已经提出，在氨基端基上具有过量羧基端基的高强度聚己酰胺纤维可以通过将通过聚合ε-己内酰胺制备的聚合物熔融纺丝并使聚合物与含有至少6个碳原子的二元羧酸反应来制备 。 然而，通过在连续操作中引入这种二羧酸反应物，由于在挤出的聚酰胺长丝中频繁出现“重叠”或扩大的位置，聚合物的熔融纺丝已经遇到严重的问题。 现在已经发现，通过使用某些二羧酸的聚酐并且在聚合结束时使聚酐反应，可以大大降低纤维中所述核子的出现。 此外，可以更容易地控制纤维的染色性。

公开(公告)号：US3917449A

公开(公告)日：1975-11-04

申请号：US44159574

申请日：1974-02-11

Applicant: ALLIED CHEM

Inventor： WELLS RODNEY LEE ,  LOFQUIST ROBERT ALDEN ,  LAZARUS STANLEY DAVID

IPC: D06P1/52 ,  D06P3/24 ,  D06P5/02

CPC classification number: D06P3/24 ,  D06P1/5285 ,  Y10S8/924 ,  Y10S8/929 ,  Y10T442/2557

Abstract: When from about 0.5 percent to about 5 percent of a polythiourea is coated on nylon fiber an improved dye fastness is achieved compared to untreated dyed nylon fiber when this fiber is exposed to ozone.

Abstract translation: 当约0.5％至约5％的聚硫脲涂覆在尼龙纤维上时，与未经处理的染色尼龙纤维相比，当该纤维暴露于臭氧时，获得了改进的染色牢度。

公开(公告)号：US3859045A

公开(公告)日：1975-01-07

申请号：US24081272

申请日：1972-04-03

Applicant: ALLIED CHEM

Inventor： LOFQUIST ROBERT ALDEN ,  SAUNDERS PETER REGINALD ,  MAYER RICHARD EUGENE

IPC: C08L77/00 ,  D01F1/10 ,  D01F6/60 ,  D06M13/372 ,  D06P5/02

CPC classification number: D06P1/645 ,  C08L77/02 ,  C08L77/06 ,  D01F1/10 ,  D01F6/60 ,  D06P5/06 ,  Y10S8/907 ,  Y10S8/924

Abstract: WHERE R is an alkyl or aralkyl radical having seven to 24 carbon atoms, R can contain one or two oxygen atoms as ester or ether linkages, R'' is alkylene, and has from two to ten carbons, and x, y and z are each at least 1 and total 10, or preferably 3, are coated on nylon fiber or added to nylon polymer before spinning, improved dyefastness is achieved when the fiber is exposed to ozone.

WHERE R is an alkyl or aralkyl radical having seven to 24 carbon atoms, R can contain one or two oxygen atoms as ester or ether linkages, and x and y are integers such that x and y are each at least 1, and x + y is not more than 10, preferably 2, or ditertiary amines such as

When from about 0.1 percent to about 8 percent of tertiary amines such as:

Abstract translation: 当约0.1％至约8％的叔胺如：

公开(公告)号：US3701757A

公开(公告)日：1972-10-31

申请号：US3701757D

申请日：1971-02-01

Applicant: ALLIED CHEM

Inventor： LAZARUS STANLEY DAVID ,  LOFQUIST ROBERT ALDEN

IPC: C08G63/87 ,  C08G17/015

CPC classification number: C08G63/87

Abstract: THE PREPARATION OF LINEAR HIGH-MOLECULAR WEIGHT, FILM AND FIBER FORMING POLYALKYLENE TEREPHTHALATES, COMPRISING REACTING EITHER BY DIRECT ESTERIFICATION OR ESTER INTERCHANGE AN ORGANIC DICARBOXYLIC ACID AND/OR THE LOWER ALKYL ESTER THEREOF WITH A POLYOL HAVING 2 TO 10 CARBON ATOMS PER MOLECULE TO OBTAIN THE CORRESPONSING DIGLYCOLESTER INTERMEDIATE AND THEN CONDENSING AND INTERMEDIATE IN THE PRESENCE OF AN EFFECTIVE AMOUNT OF A CONDENSATION ACCELERATOR WHICH IS AN ORTHOESTER OF AN ORGANIC ACID WHICH PRODUCES VOLATILE ALCOHOL AND ACID UPON REACTION WITH WATER.