公开(公告)号：US09822052B2

公开(公告)日：2017-11-21

申请号：US15279837

申请日：2016-09-29

Applicant: AdvanSix Resins & Chemicals LLC ,  University of Southampton

Inventor： Alan B. Levy ,  Scott R. Keenan ,  Robert Raja ,  Arran M. Gill ,  Matthew E. Potter ,  Sivan A. Van Aswegen

IPC: C07C45/35 ,  B01J27/00 ,  B01J37/00 ,  C07C45/39 ,  B01J27/13 ,  B01J27/185 ,  B01J37/04 ,  B01J37/08

CPC classification number: C07C45/39 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J23/8926 ,  B01J27/13 ,  B01J27/1856 ,  B01J35/0013 ,  B01J35/002 ,  B01J37/04 ,  B01J37/08 ,  B01J37/088 ,  B01J37/18 ,  B01J37/343 ,  C07C2601/14 ,  C07C49/403

Abstract: Methods for converting an alcohol, such as cyclohexanol to a ketone, such as cyclohexanone, include reacting the alcohol in the presence of a catalyst and oxygen to produce the ketone. In one exemplary embodiment, the catalyst comprises a microporous copper chloropyrophosphate framework including a plurality of noble metal nanoparticles. In one exemplary embodiment, the noble metal nanoparticles include at least one metal selected from the group consisting of platinum, palladium, and gold.

公开(公告)号：US20180065910A1

公开(公告)日：2018-03-08

申请号：US15790235

申请日：2017-10-23

Applicant: AdvanSixResins & Chemicals LLC ,  University of Southampton

Inventor： Alan B. Levy ,  Scott R. Keenan ,  Robert Raja ,  Arran M. Gill ,  Matthew E. Potter ,  Sivan A. Van Aswegen

IPC: C07C45/39 ,  B01J37/08 ,  B01J37/04 ,  B01J27/13 ,  B01J27/185 ,  C07C49/403

CPC classification number: C07C45/39 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J23/8926 ,  B01J27/13 ,  B01J27/1856 ,  B01J35/0013 ,  B01J35/002 ,  B01J37/04 ,  B01J37/08 ,  B01J37/088 ,  B01J37/18 ,  B01J37/343 ,  C07C2601/14 ,  C07C49/403

Abstract: Methods for converting an alcohol, such as cyclohexanol to a ketone, such as cyclohexanone, include reacting the alcohol in the presence of a catalyst and oxygen to produce the ketone. In one exemplary embodiment, the catalyst comprises a microporous copper chloropyrophosphate framework including a plurality of noble metal nanoparticles. In one exemplary embodiment, the noble metal nanoparticles include at least one metal selected from the group consisting of platinum, palladium, and gold.