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1.发明授权Process for producing polymers or copolymers of olefins containing at least three carbon atoms and catalysts therefor 失效制备含有至少三个碳原子的烯烃的聚合物或共聚物的方法及其催化剂
公开(公告)号：US4490513A
公开(公告)日：1984-12-25
申请号：US836056
申请日：1977-09-23
申请人： Syuji Minami , Akinori Toyota , Norio Kashiwa
发明人： Syuji Minami , Akinori Toyota , Norio Kashiwa
CPC分类号： C08F10/00 , Y10S526/906
摘要： A process for producing a polymer or copolymer of an olefin containing at least 3 carbon atoms which comprises polymerizing or copolymerizing at least one olefin containing at least 3 carbon atoms, or copolymerizing the olefin with to 10 mole % of ethylene and/or a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component and (B) an organometallic compound of a metal of Groups I to III of the periodic table; wherein the solid titanium catalyst component (A) is a composition formed by contacting(i) a reaction product of an organic magnesium compound containing magnesium directly bonded to at least one carbon atom with an organic silicon-containing compound selected from the group consisting of organic silanols containing at least one hydroxyl group directly bonded to silicon and organopolysiloxanes,(ii) an organic acid ester, and(iii) a titanium compound.
摘要翻译： 一种制备包含至少3个碳原子的烯烃的聚合物或共聚物的方法，其包括聚合或共聚至少一种含有至少3个碳原子的烯烃，或将烯烃与10摩尔％的乙烯和/或二烯烃共聚 存在由（A）含镁固体钛催化剂组分和（B）元素周期表第I至III族金属的有机金属化合物组成的催化剂; 其中所述固体钛催化剂组分（A）是通过使（i）含有与至少一个碳原子直接键合的镁的有机镁化合物的反应产物与选自有机基团的有机含硅化合物 含有至少一个与硅和有机聚硅氧烷直接结合的羟基的硅烷醇，（ii）有机酸酯，和（iii）钛化合物。
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2.发明授权Process for polymerizing .alpha.-olefins containing at least 3 carbon atoms and catalyst therefor 失效用于聚合含有至少3个碳原子的α-烯烃和其催化剂的方法
公开(公告)号：US4221894A
公开(公告)日：1980-09-09
申请号：US951973
申请日：1978-10-16
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： A process for polymerizing or copolymerizing .alpha.-olefins having at least 3 carbon atoms or copolymerizing .alpha.-olefins having at least 3 carbon atoms with not more than 50 mole % of ethylene in the presence of a catalyst composed of an organometallic compound of a metal of Groups I to III of the periodic table and a titanium catalyst component supported on a halogen-containing magnesium compound, said titanium catalyst component being a solid reaction product obtained by treating (i) a mechanically copulverized product of a halogen-containing compound and an organic acid ester with (ii) an organo-metallic compound of a metal of Groups I to III of the periodic table, and then reacting the resulting solid product with (iii) a titanium compound in the absence of mechanical pulverization.
摘要翻译： 在具有至少3个碳原子的α-烯烃或具有至少3个碳原子的α-烯烃与不超过50摩尔％的乙烯的聚合或共聚的催化剂的存在下，在由金属的有机金属化合物 元素周期表的I至III族和负载在含卤素的镁化合物上的钛催化剂组分，所述钛催化剂组分是通过处理（i）含卤素化合物和有机物的机械共缩合产物得到的固体反应产物 酸酯与（ⅱ）元素周期表第I至III族金属的有机金属化合物反应，然后在没有机械粉碎的情况下使得到的固体产物与（ⅲ）钛化合物反应。
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3.发明授权Process for preparing highly stereoregular polyolefins and catalyst used therefor 失效制备高立体规则聚烯烃的方法和用于其的催化剂
公开(公告)号：US4157435A
公开(公告)日：1979-06-05
申请号：US710658
申请日：1976-08-02
申请人： Akinori Toyota , Norio Kashiwa , Syuji Minami
发明人： Akinori Toyota , Norio Kashiwa , Syuji Minami
CPC分类号： C08F4/022 , C08F10/00 , Y10S526/904 , Y10S526/906
摘要： A process for preparing highly stereoregular polyolefins in the presence of a catalyst comprising (A) a titanium-containing solid catalyst component composed of an organic complex derived from(i) a magnesium halide(ii) an organopolysiloxane selected from the group consisting of compounds of the formulaQ(Q.sub.2 SiO).sub.n SiQ.sub.3, (Q.sub.2 SiO).sub.n and X(Q.sub.2 SiO).sub.n SiQ.sub.2 X,(iii) an organic carboxylic acid ester, and(iv) a titanium compound of the formulaTi(OR).sub.l X.sub.4-l, and(B) an organoaluminum catalyst component of the formulaR'mAl(OR').sub.3-m,said organic complex being derived by bringing the component (i) into contact with a combination of the components (ii) and (iii) or a combination of the components (ii), (iii) and (iv) under mechanical pulverisation conditions and then treating the resulting pulverized composition with the component (iv) in the absence of mechanical pulverization.
摘要翻译： 一种在催化剂存在下制备高立体规则聚烯烃的方法，包括（A）含钛固体催化剂组分，其由衍生自（I）选自由化合物组成的组中选择的一种有机金属氧化物（II）的有机络合物组成的含钛固体催化剂组分 式（QSiO）nSiQ3，（Q2SiO）n和X（Q2SiO）nSiQ2X，（iii）有机羧酸酯和（Ⅳ）式（Ⅺ）Ⅺ4-Ⅳ的钛化合物和（B） 一种式R'mAl（OR'）3-m的有机铝催化剂组分，通过使组分（I）与组分（II）和（III）的组合接触得到的有机复合物或其组合 组件（II），（III）和（IV）在机械搅拌条件下，然后在组织（IV）的机械搅拌条件下处理结晶粉化组合物。
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公开(公告)号：US4250285A
公开(公告)日：1981-02-10
申请号：US902946
申请日：1978-05-04
申请人： Syuji Minami , Akinori Toyota , Norio Kashiwa
发明人： Syuji Minami , Akinori Toyota , Norio Kashiwa
CPC分类号： C08F10/04 , C08F4/022 , Y10S526/906
摘要： A process for preparing a polymer or copolymer of an olefin having at least 3 carbon atoms which comprises polymerizing or copolymerizing an olefin having at least 3 carbon atoms and containing 0 to 10 mole % of another olefin or diolefin in the presence of a catalyst composed of (i) a solid titanium catalyst component and (ii) an organoaluminum compound; wherein the solid titanium catalyst component is obtained by contacting(1) a magnesium containing copulverization product comprising (A) an aluminum or germanium compound selected from the group consisting of aluminum compounds of the formula AlR.sub.n X.sub.3-n wherein R is a hydrogen atom, or an alkyl, alkenyl, aryl, alkoxy, aryloxy or acyloxy group optionally having a substituent, X is a halogen atom, and O
摘要翻译： 一种制备具有至少3个碳原子的烯烃的聚合物或共聚物的方法，该方法包括使聚合或共聚含有至少3个碳原子的烯烃并含有0-10摩尔％的另一种烯烃或二烯烃，催化剂由 （i）固体钛催化剂组分和（ii）有机铝化合物; 其中所述固体钛催化剂组分是通过使（1）含镁共混物与（A）铝或锗化合物（其中R为氢原子的AlRnX3-n的铝化合物）或 烷基，烯基，芳基，烷氧基，芳氧基或任选具有取代基的酰氧基，X是卤素原子，O
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公开(公告)号：US4143223A
公开(公告)日：1979-03-06
申请号：US773266
申请日：1977-03-01
申请人： Akinori Toyota , Syuji Minami , Norio Kashiwa
发明人： Akinori Toyota , Syuji Minami , Norio Kashiwa
CPC分类号： C08F10/00 , Y10S526/906
摘要： A process for polymerizing or copolymerizing .alpha.-olefins in the presence of a catalyst composed of (A) a mechanically pulverized solid titanium-containing catalyst component and (B) an organometallic compound of a metal of Groups I to III of the periodic table, wherein said titanium-containing component is a solid halogen-containing titanium catalyst component obtained by reacting a mechanically copulverized solid product in the absence of mechanical pulverization with a titanium compound which is liquid under the reaction conditions, said mechanically copulverized product being derived from (1) a magnesium compound, (2) an organic acid ester, and (3) an active hydrogen-containing compound selected from the group of alcohols and phenols; and a catalyst composition used therefor.
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公开(公告)号：US5807801A
公开(公告)日：1998-09-15
申请号：US856290
申请日：1997-05-14
申请人： Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
发明人： Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
CPC分类号： C08F10/00 , C08F210/16 , C08F210/18 , C08F4/65912 , Y10S526/943
摘要： Presence of a catalyst formed from (A) a transition metal compound comprising (A-1) a transition metal atom, (A-2) a hetero atom-containing ligand containing a heteroatom selected from oxygen, sulfur, nitrogen and phosphorus capable of forming a bond with the transition metal atom, and (A-3) a ligand having a conjugated .pi. electron through which the ligand can be bonded to the transition metal atom (A-1), and (B) an aluminoxane. The transition metal compound is pre-treated with (C) an organometallic compound, or (D) a halogen-containing inorganic compound of an element of Group III, IV or V of the periodic table in an organic solvent.
摘要翻译： 存在由（A）过渡金属化合物形成的催化剂，该过渡金属化合物包含（A-1）过渡金属原子，（A-2）含有能够形成的含氧，硫，氮和磷的杂原子的含杂原子的配体 与过渡金属原子的键，和（A-3）具有共轭π电子的配体，配体可以通过其与过渡金属原子（A-1）键合，和（B）铝氧烷。 过渡金属化合物在有机溶剂中用（C）有机金属化合物或（D）元素周期表第III，IV或V族元素的含卤素的无机化合物进行预处理。
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公开(公告)号：US5075396A
公开(公告)日：1991-12-24
申请号：US331221
申请日：1989-03-31
申请人： Norio Kashiwa , Akinori Toyota , Mamoru Kioka
发明人： Norio Kashiwa , Akinori Toyota , Mamoru Kioka
CPC分类号： C08F10/00
摘要： A process for producing a polymer or copolymer of an olefin which comprises polymerizing or copolymerizing at least one olefin with or without a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component containing magnesium, titanium, a halogen and an electron donor as essential ingredients and (B) an organoaluminum compound catalyst component; characterized in that(1) said catalyst further comprises (C) an organic silicon compound catalyst component having an Si--O--C or Si--N--C bond, and(2) said electron donor in the catalyst component (A) is a cyclic mono- or poly-ester such as diethyl furane-3,4-dicarboxylate, di-n-butyl 3,4-dihydro-2H-pyrane-5,6-dicarboxylate, di-isobutyl pyrrole-2,3-dicarboxylic, di-n-butyl thiophene-2,3-dicarboxylate, n-octyl pyrrolidine-2,3-dicarboxylate, and so on.
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公开(公告)号：US5055528A
公开(公告)日：1991-10-08
申请号：US465648
申请日：1990-01-22
申请人： Mamoru Kioka , Akinori Toyota , Norio Kashiwa
发明人： Mamoru Kioka , Akinori Toyota , Norio Kashiwa
IPC分类号： C08F4/64 , C08F4/42 , C08F4/60 , C08F10/06 , C08F210/06 , C08F297/08 , C08L23/10 , C08L23/16
CPC分类号： C08F297/083 , C08L23/10 , C08L2205/02 , C08L23/16
摘要： A process for producing a propylene polymer having good flowability with an MFR of at least 10 g/10 minutes comprises a first polymerization stage consisting of at least two steps and a subsequent second polymerization stage. It is important to control the intrinsic viscositites of a crystalline propylene polymer obtained from the first step of the first polymerization stage and a crystalline propylene polymer obtained from the final step of the first polymerization stage.
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公开(公告)号：US5008356A
公开(公告)日：1991-04-16
申请号：US359131
申请日：1989-05-31
IPC分类号： C08F4/659 , C08F4/6592 , C08F210/00 , C08F210/06 , C08F210/14 , C08F232/00
CPC分类号： C08F232/00 , C08F210/00 , C08F210/06 , C08F210/14 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A cyclo-olefinic random copolymer composed of an alpha-olefin component having 3 to 20 carbon atoms and a cyclo-olefin component,(i) said copolymer containing 5 to 99 mole % of recurring units derived from said alpha-olefin component having 3 to 20 carbon atoms and 1 to 95 mole % of recurring units derived from said cyclo-olefin component, and(ii) said copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.01 to 10 dl/g; and an olefinic random copolymer composed of (A) an olefin component having 3 to 20 carbon atoms and (B) a cyclic polyene component and as required, (C) a cyclo-olefin component,(i) said copolymer containing 5 to 99 mole % of recurring units derived from said alpha-olefin component (A) having 3 to 20 carbon atoms and 1 to 95 mole % of recurring units derived from said cyclic polyene component (B) and 0 to 90 mole % of recurring units derived from said cyclo-olefin component (C), and(ii) said copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.01 to 10 dl/g; and a process for production thereof. Also provided is a process for producing a cyclo-olefinic random copolymer, which comprises copolymerizing an alpha-olefin and a cyclo-olefin in the presence of a catalyst formed from(A) a compound of a transition metal of Group IVB of the periodic table having as a ligand a multidentate coordination compound in which at least two conjugated cycloalkadienyl groups or substituted products thereof are bonded via a lower alkylene group, and(B) an aluminoxane.
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公开(公告)号：US4369306A
公开(公告)日：1983-01-18
申请号：US240404
申请日：1981-03-04
申请人： Akinori Toyota , Norio Kashiwa
发明人： Akinori Toyota , Norio Kashiwa
CPC分类号： C08F6/02
摘要： A method for treating an olefin polymer, which comprises contacting an olefin polymer obtained by polymerizing an olefin in the presence of a catalyst composed of (A) a highly active transition metal compound, (B) an organoaluminum compound and (C) a carbonyl- or Si-containing electron donor, with (D) an organometallic compound of a metal of Groups I to III of the periodic table after the polymerization. This method can markedly reduce the amount of an electron donor remaining in an olefin polymer after polymerization, the electron donor being an ingredient of a catalyst used in the polymerization and constituting the main cause of an offensive odor which the resulting polymer gives off.
摘要翻译： 一种处理烯烃聚合物的方法，其包括在由（A）高活性过渡金属化合物，（B）有机铝化合物和（C）羰基化合物）组成的催化剂存在下使通过聚合烯烃获得的烯烃聚合物接触， 或含Si的电子给体，与（D）聚合后的元素周期表第I至III族金属的有机金属化合物。 该方法可以显着降低聚合后残留在烯烃聚合物中的电子给体的量，电子给体是聚合中使用的催化剂的成分，并且构成所得聚合物发出的恶臭的主要原因。
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