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    Method for producing at least one of α, β-unsaturated aldehyde and α, β-unsaturated carboxylic acid
    2.
    发明授权
    Method for producing at least one of α, β-unsaturated aldehyde and α, β-unsaturated carboxylic acid 有权
    生产α，β-不饱和醛和α，β-不饱和羧酸中的至少一种的方法

    公开(公告)号：US08173838B2

    公开(公告)日：2012-05-08

    申请号：US12443994

    申请日：2006-10-03

    申请人： Akio Takeda ,  Yuji Fujimori ,  Seiichi Kawato

    发明人： Akio Takeda ,  Yuji Fujimori ,  Seiichi Kawato

    IPC分类号： C07C51/16 ,  C07C45/00

    CPC分类号： C07C45/38 ,  C07C51/235 ,  C07C47/22 ,  C07C57/04

    摘要： Disclosed is a method for producing at least one of an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid from an alcohol in a liquid phase through a simple process. Namely, at least one of an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid is produced by dehydrating and oxidizing an alcohol in a liquid phase at 110 to 250° C. in the presence of molecular oxygen and a noble metal-containing catalyst. Alternatively, at least one of an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid is produced by dehydrating and oxidizing an alcohol in a liquid phase in the presence of molecular oxygen, a noble metal-containing catalyst, and an acidic substance.

    摘要翻译： 公开了通过简单的方法从液相中生产α，β-不饱和醛和α，β-不饱和羧酸中的至少一种的方法。 即，α-和β-不饱和醛和α，β-不饱和羧酸中的至少一种是通过在分子氧存在下在110-250℃下在液相中脱水和氧化来制备的， 含贵金属的催化剂。 或者，α，β-不饱和醛和α，β-不饱和羧酸中的至少一种是通过在分子氧，含贵金属的催化剂存在下在液相中脱水和氧化来制备的， 和酸性物质。

    METHOD FOR PRODUCING AT LEAST ONE OF ALPHA, BETA-UNSATURATED ALDEHYDE AND ALPHA, BETA-UNSATURATED CARBOXYLIC ACID
    3.
    发明申请
    METHOD FOR PRODUCING AT LEAST ONE OF ALPHA, BETA-UNSATURATED ALDEHYDE AND ALPHA, BETA-UNSATURATED CARBOXYLIC ACID 有权
    用于生产至少一种ALPHA，不饱和二硫代氨基甲酸酯和ALPHA，β-不饱和羧酸的方法

    公开(公告)号：US20100094045A1

    公开(公告)日：2010-04-15

    申请号：US12443994

    申请日：2006-10-03

    申请人： Akio Takeda ,  Yuji Fujimori ,  Seiichi Kawato

    发明人： Akio Takeda ,  Yuji Fujimori ,  Seiichi Kawato

    IPC分类号： C07C51/235 ,  C07C45/38

    CPC分类号： C07C45/38 ,  C07C51/235 ,  C07C47/22 ,  C07C57/04

    摘要： Disclosed is a method for producing at least one of an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid from an alcohol in a liquid phase through a simple process. Namely, at least one of an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid is produced by dehydrating and oxidizing an alcohol in a liquid phase at 110 to 250° C. in the presence of molecular oxygen and a noble metal-containing catalyst. Alternatively, at least one of an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid is produced by dehydrating and oxidizing an alcohol in a liquid phase in the presence of molecular oxygen, a noble metal-containing catalyst, and an acidic substance.

    摘要翻译： 公开了通过简单的方法从液相中生产α，β-不饱和醛和α，β-不饱和羧酸中的至少一种的方法。 即，α-和β-不饱和醛和α，β-不饱和羧酸中的至少一种是通过在分子氧存在下在110-250℃下在液相中脱水和氧化来制备的， 含贵金属的催化剂。 或者，α，β-不饱和醛和α，β-不饱和羧酸中的至少一种是通过在分子氧，含贵金属的催化剂存在下在液相中脱水和氧化来制备的， 和酸性物质。

    Method For Producing Alpha, Beta-Unsaturated Carboxylic Acid
    6.
    发明申请
    Method For Producing Alpha, Beta-Unsaturated Carboxylic Acid 审中-公开
    生产α，β-不饱和羧酸的方法

    公开(公告)号：US20080064899A1

    公开(公告)日：2008-03-13

    申请号：US11628215

    申请日：2005-05-30

    申请人： Seiichi Kawato ,  Akio Takeda ,  Yoshiyuki Himeno

    发明人： Seiichi Kawato ,  Akio Takeda ,  Yoshiyuki Himeno

    IPC分类号： C07C51/25

    CPC分类号： C07C45/35 ,  C07C51/235 ,  C07C51/252 ,  C07C51/50 ,  C07C47/22 ,  C07C57/04

    摘要： The present invention provides a method for producing an α,β-unsaturated carboxylic acid in high yield. In particular, the present invention resides in a method for producing an α,β-unsaturated carboxylic acid by oxidation of an olefin or an α,β-unsaturated aldehyde with molecular oxygen in liquid phase in the presence of a catalyst containing at least palladium, wherein at least one compound selected from the group consisting of p-methoxyphenol, 4,4′-dihydroxytetraphenylmethane, 1,1,1-tris(p-hydroxyphenyl)ethane, compounds having an N-oxyl group in the molecule and compounds having an N-nitrosyl group in the molecule is caused to be coexistent.

    摘要翻译： 本发明提供以高产率生产α，β-不饱和羧酸的方法。 特别地，本发明在于一种通过在含有至少钯的催化剂存在下在液相中用分子氧氧化烯键或α，β-不饱和醛来生产α，β-不饱和羧酸的方法， 其中选自对甲氧基苯酚，4,4'-二羟基四苯基甲烷，1,1,1-三（对羟基苯基）乙烷中的至少一种化合物，分子中具有N-氧基的化合物和具有 分子中的N-亚硝酰基被共同存在。