Permanent magnet material and method for making
    1.
    发明授权
    Permanent magnet material and method for making 失效
    永磁材料及其制造方法

    公开(公告)号:US5209789A

    公开(公告)日:1993-05-11

    申请号:US755188

    申请日:1991-09-05

    摘要: A melt of Nd-Fe-B alloy is injected in an inert gas atmosphere through a nozzle against a chill roll or a pair of chill rolls rotating relative to the nozzle for contacting the melt with the circumference of the chill roll or rolls, thereby quenching the melt. The chill roll has a low heat conductivity surface layer around a base or has a predetermined surface roughness on its circumference. The contact time of the melt with the chill roll can be increased by blowing an inert gas flow. Further the melt is quenched in an inert gas atmosphere of up to 1 Torr. A wind shield is disposed in proximity to the chill roll circumference for preventing a wind of the ambient gas induced by rotation of the chill roll from reaching a paddle of the melt. With these means, there is obtained a permanent magnet material having a grain diameter with a reduced variation.

    摘要翻译: Nd-Fe-B合金的熔体通过喷嘴在惰性气体气氛中通过冷却辊或相对于喷嘴旋转的一对冷却辊注入,用于使熔体与冷却辊或辊的周边接触,从而淬火 熔化。 冷却辊在基部周围具有低导热性表面层或在其圆周上具有预定的表面粗糙度。 可以通过吹入惰性气流来增加熔体与冷却辊的接触时间。 此外,熔体在高达1托的惰性气体气氛中淬火。 挡风玻璃设置在冷却辊周边附近,用于防止由冷却辊的旋转引起的环境气体的风到达熔体的桨叶。 通过这些方法,获得具有减小的变化的粒径的永久磁铁材料。

    Method for preparing permanent magnet material, chill roll, permanent
magnet material, and permanent magnet material powder
    2.
    发明授权
    Method for preparing permanent magnet material, chill roll, permanent magnet material, and permanent magnet material powder 失效
    制备永磁材料,冷却辊,永磁材料和永磁材料粉末的方法

    公开(公告)号:US5665177A

    公开(公告)日:1997-09-09

    申请号:US878523

    申请日:1992-05-05

    摘要: A permanent magnet material is prepared by cooling with a chill roll a molten alloy containing R wherein R is at least one rare earth element inclusive of Y, Fe or Fe and Co, and B. The chill roll has a plurality of circumferentially extending grooves in a circumferential surface, the distance between two adjacent ones of the grooves at least in a region with which the molten alloy comes in contact being 100 to 300 .mu.m average in an arbitrary cross section containing a roll axis. Permanent magnet material of stable performance is obtained since the variation of cooling rate caused by a change in the circumferential speed of the chill roll is small. The variation of cooling rate is small even when it is desired to change the thickness of the magnet by altering the circumferential speed. The equalized groove pitch results in a minimized variation in crystal grain diameter.

    摘要翻译: 通过用冷却辊冷却含有R的熔融合金来制备永久磁铁材料,其中R是至少一种包括Y,Fe或Fe和Co以及B的稀土元素。冷却辊具有多个周向延伸的凹槽 至少在熔融合金接触的区域中,两个相邻的槽之间的距离在包含辊轴的任意横截面中平均为100〜300μm。 由于冷却辊的圆周速度的变化引起的冷却速度的变化小,所以获得了稳定性能的永久磁铁材料。 即使希望通过改变圆周速度来改变磁体的厚度,冷却速度的变化也很小。 均匀的沟槽间距导致晶粒直径的最小化。

    Method for preparing permanent magnet material, chill roll, permanent
magnet material, and permanent magnet material powder
    3.
    发明授权
    Method for preparing permanent magnet material, chill roll, permanent magnet material, and permanent magnet material powder 失效
    制备永磁材料,冷却辊,永磁材料和永磁材料粉末的方法

    公开(公告)号:US5993939A

    公开(公告)日:1999-11-30

    申请号:US835814

    申请日:1997-04-16

    摘要: A permanent magnet material is prepared by cooling with a chill roll a molten alloy containing R wherein R is at least one rare earth element inclusive of Y, Fe or Fe and Co, and B. The chill roll has a plurality of circumferentially extending grooves in a circumferential surface, the distance between two adjacent ones of the grooves at least in a region with which the molten alloy comes in contact being 100 to 300 .mu.m on average in an arbitrary cross section containing a roll axis. Permanent magnet material of stable performance is obtained since the variation of cooling rate caused by a change in the circumferential speed of the chill roll is small. The variation of cooling rate is small even when it is desired to change the thickness of the magnet by altering the circumferential speed. The equalized groove pitch results in a minimized variation in crystal grain diameter.

    摘要翻译: 通过用冷却辊冷却含有R的熔融合金来制备永久磁铁材料,其中R是至少一种包括Y,Fe或Fe和Co以及B的稀土元素。冷却辊具有多个周向延伸的凹槽 至少在熔融合金接触的区域中,在包含辊轴的任意横截面中,平均两个相邻槽之间的距离为100-300μm。 由于冷却辊的圆周速度的变化引起的冷却速度的变化小,所以获得了稳定性能的永久磁铁材料。 即使希望通过改变圆周速度来改变磁体的厚度,冷却速度的变化也很小。 均匀的沟槽间距导致晶粒直径的最小化。

    Permanent magnet material and method for making
    4.
    发明授权
    Permanent magnet material and method for making 失效
    永磁材料及其制造方法

    公开(公告)号:US5309977A

    公开(公告)日:1994-05-10

    申请号:US9948

    申请日:1993-01-27

    摘要: A melt of Nd-Fe-B alloy is injected in an inert gas atmosphere through a nozzle against a chill roll or a pair of chill rolls rotating relative to the nozzle for contacting the melt with the circumference of the chill roll or rolls, thereby quenching the melt. The chill roll has a low heat conductivity surface layer around a base or has a predetermined surface roughness on its circumference. The contact time of the melt with the chill roll can be increased by blowing an inert gas flow. Further the melt is quenched in an inert gas atmosphere of up to 1 Torr. A wind shield is disposed in proximity to the chill roll circumference for preventing a wind of the ambient gas induced by rotation of the chill roll from reaching a paddle of the melt. With these means, there is obtained a permanent magnet material having a grain diameter with a reduced variation.

    摘要翻译: Nd-Fe-B合金的熔体通过喷嘴在惰性气体气氛中通过冷却辊或相对于喷嘴旋转的一对冷却辊注入,用于使熔体与冷却辊或辊的周边接触,从而淬火 熔化。 冷却辊在基部周围具有低导热性表面层或在其圆周上具有预定的表面粗糙度。 可以通过吹入惰性气流来增加熔体与冷却辊的接触时间。 此外,熔体在高达1托的惰性气体气氛中淬火。 挡风玻璃设置在冷却辊周边附近,用于防止由冷却辊的旋转引起的环境气体的风到达熔体的桨叶。 通过这些方法,获得具有减小的变化的粒径的永久磁铁材料。

    Magnet and bonded magnet
    5.
    发明授权
    Magnet and bonded magnet 失效
    磁铁和粘结磁铁

    公开(公告)号:US5750044A

    公开(公告)日:1998-05-12

    申请号:US500578

    申请日:1995-07-11

    IPC分类号: H01F1/059 C04B35/04

    CPC分类号: H01F1/0596

    摘要: A magnet consists essentially of 4-8 at % of R, 10-20 at % of N, 2-10 at % of M, and the balance of T wherein R is at least one rare earth element, Sm being present in R in a proportion of at least 50 at %, T is Fe or Fe and Co, M is Zr with or without partial replacement by at least one element of Ti, V, Cr, Nb, Hf, Ta, Mo, W, Al, C, and P. Contained in the magnet are a hard magnetic phase based on R, T, and N and containing at least one crystalline phase selected from TbCu.sub.7, Th.sub.2 Zn.sub.17, and Th.sub.2 Ni.sub.17 types and a soft magnetic phase consisting of a T phase having a bcc structure, the soft magnetic phase having a mean grain size of 5-60 nm and being present in a proportion of 10-60% by volume. This construction ensures high coercivity, high squareness ratio, and high maximum energy product.

    摘要翻译: 磁体基本上由R的4-8原子%组成,N为10-20原子%,M为2-10原子%,余量为T,其中R为至少一种稀土元素,Sm存在于R中 至少50原子%的比例,T是Fe或Fe和Co,M是具有或不被Ti,V,Cr,Nb,Hf,Ta,Mo,W,Al,C的至少一种元素部分置换的Zr的Zr 和P.包含在磁体中的是基于R,T和N的硬磁相,并且含有至少一种选自TbCu7,Th2Zn17和Th2Ni17类型的结晶相和由具有bcc的T相组成的软磁相 结构,软磁性相的平均粒径为5-60nm,以10〜60体积%的比例存在。 这种结构确保了高矫顽力,高矩形比和高最大能量产品。

    Preparation of magnet
    6.
    发明授权
    Preparation of magnet 失效
    制备磁铁

    公开(公告)号:US5916376A

    公开(公告)日:1999-06-29

    申请号:US984945

    申请日:1997-12-04

    CPC分类号: H01F1/059

    摘要: An object of the invention is to provide an inexpensive magnet having a high coercivity, high squareness ratio and high maximum energy product. According to the invention, a magnet containing R, T, N, and M wherein R is at least one rare earth element with essential samarium, T is iron or iron and cobalt, and M is at least one element of Ti, V, Cr, Nb, Hf, Ta, Mo, W, Al, C, and P, with essential zirconium, in amounts of 4-8 at % of R, 10-20 at % of N, 2-10 at % of M, and having a hard magnetic phase (TbCu.sub.7 type crystalline phase) and a soft magnetic phase (which is a bcc structured T phase, has an average grain diameter of 5-60 nm, and accounts for 10 to 60% by volume of the entirety), the atomic ratio (R+M)/(R+T+M) in the hard magnetic phase being in excess of 12.5%, is prepared utilizing a single roll technique. In the single roll technique, the peripheral speed of a chill roll is at least 50 m/s, and the discharge pressure of the molten alloy is 0.3-2 kgf/cm.sup.2. Following quenching, the quenched alloy is subjected to heat treatment at 600-800.degree. C. and then to nitriding treatment.

    摘要翻译: 本发明的目的是提供一种具有高矫顽力,高矩形比和高最大能量积的廉价磁铁。 根据本发明,含有R,T,N和M的磁体,其中R是至少一种具有必需钐的稀土元素,T是铁或铁和钴,M是Ti,V,Cr中的至少一种元素 ,Nb,Hf,Ta,Mo,W,Al,C和P与必需的锆,其量为R的4-8原子%,N为10-20at%,M为2-10at%,以及 具有硬磁相(TbCu7型结晶相)和软磁相(其为bcc结构的T相,平均粒径为5-60nm,占全体的10〜60体积%), 使用单辊技术制备硬磁相中的原子比(R + M)/(R + T + M)超过12.5%。 在单辊技术中,冷却辊的圆周速度为至少50m / s,熔融合金的排出压力为0.3-2kgf / cm 2。 淬火后淬火合金在600-800℃进行热处理,然后进行氮化处理。

    Permanent magnet material and process for producing the same
    7.
    发明授权
    Permanent magnet material and process for producing the same 失效
    永磁材料及其制造方法

    公开(公告)号:US4210471A

    公开(公告)日:1980-07-01

    申请号:US766686

    申请日:1977-02-08

    IPC分类号: C22C19/07 H01F1/055 H01F1/08

    CPC分类号: H01F1/055 C22C19/07

    摘要: Disclosed is the addition of Nb, V, Ta or Zr to the ternary alloy of R (rare earth)-Co-Cu for permanent magnet materials, to thereby provide the permanent magnets with increased coercive force, residual magnetization and energy product. The additional elements enables employment of such Cu and Fe contents of the alloy as less than 10% and more than 6%, respectively. These percentages were avoided in the prior art to prevent the reduction of Br and Hc, respectively.

    摘要翻译: 公开了将Nb,V,Ta或Zr添加到用于永磁材料的R(稀土)-Co-Cu的三元合金中,从而为永磁体提供增加的矫顽力,剩余磁化强度和能量积。 这些附加元素使得合金中这种Cu和Fe的含量分别小于10%且大于6%。 在现有技术中避免了这些百分比,以防止分别降低Br和Hc。

    Magnetic recording medium comprising a magnetic layer containing a
specified magnetic ferrite powder and having a curie temperature up to
180.degree. C.
    8.
    发明授权
    Magnetic recording medium comprising a magnetic layer containing a specified magnetic ferrite powder and having a curie temperature up to 180.degree. C. 失效
    包含指定磁铁粉末的磁性层并具有高达180度C的温度的磁记录介质。

    公开(公告)号:US5229219A

    公开(公告)日:1993-07-20

    申请号:US536661

    申请日:1990-07-09

    IPC分类号: C01G49/00 G11B5/706 H01F1/11

    摘要: According to the invention, a magnetic recording medium is formed by using magnetic powder having a composition of the following formula:MeO.multidot.n[Fe.sub.2-x-y-z Ga.sub.x Cr.sub.y Al.sub.z O.sub.3 ]wherein Me is at least on element selected from the group consisting of Ba, Sr, Pb, and Ca,4.5.ltoreq.n.ltoreq.6, x.gtoreq.0, y.gtoreq.0, z.gtoreq.0,x/3+y/4+z/6.gtoreq.1/6, andx/6+y/10+z/11.ltoreq.1/6,preferably the number of those particles having a particle size of from 0.5d to 1.5d being at least 65% of the entire particles wherein is an average particle size, and the Fe content on the particle surface being substantially equal to the Fe content in the particle interior, and blending the powder with a binder. Thermomagnetic recording and thermomagnetic duplication are carried out using the medium. There results a magnetic layer which has high Hc, is not easily erased once recorded, has high squareness ratio, and enables thermomagnetic recording and thermomagnetic duplication at 100.degree. to 180.degree. C. with outputs having an excellent frequency response and minimized variation and noise.

    摘要翻译: PCT No.PCT / JP89 / 01133 Sec。 371 1990年7月9日第 102(e)日1990年7月9日PCT 1989年11月2日PCT PCT。 WO90 / 05367 PCT出版物 日本1990年5月17日。根据本发明,通过使用具有下式的组成的磁粉形成磁记录介质:MeOxn [Fe2-xy-zGaxCryAlzO3]其中Me至少在选自 Ba,Sr,Pb和Ca,4.5≤n≤6,x> = 0,y> / = 0,z> / = 0,x / 3 + y / 4 + z / 6> = 1/6,x / 6 + y / 10 + z / 11 = 1/6,优选粒径为0.5< bar>至1.5& 整个颗粒,其中平均颗粒大小,并且颗粒表面上的Fe含量基本上等于颗粒内部的Fe含量,并将粉末与粘合剂混合。 使用介质进行热磁记录和热磁复制。 产生高Hc的磁性层,记录后不容易擦除,具有高矩形比,并且能够在100〜180℃下进行热磁记录和热磁复制,具有出色的频率响应和最小化的变化和噪声。