摘要:
An exhaust gas purifying catalyst with an excellent effect of suppressing deterioration due to aggregation of a noble metal catalyst during endurance at high temperature, and a production method therefor. The method for producing the exhaust gas purifying catalyst that has a porous carrier and a noble metal catalyst supported thereon includes: preparing the porous carrier that contains alumina-ceria-zirconia composite oxide particles and has physical property values, after subjected to baking at 900° C. for 5 hours, of a pore diameter of the particles in the range of 2 to 20 nm, a specific surface area of the particles in the range of 75 to 115 m2/g, a crystallite size of a ceria-zirconia composite oxide contained in the particles in the range of 4 to 6 nm, and a bulk density of the particles in the range of 0.5 to 0.9 cm3/g, and bringing a noble metal chemical solution having an aggregate of platinum or the like with a grain size adjusted to less than or equal to 1 nm with the use of a platinum nitric acid solution or the like, into contact with the porous carrier, so that the noble metal catalyst is supported on the porous carrier.
摘要:
An exhaust gas purifying apparatus provides a reflux pipe for connecting an intake pipe to an exhaust pipe and an EGR valve disposed in the reflux pipe for adjusting a flow rate of the exhaust gas flowing through the reflux pipe. A nitrogen oxide purifying catalyst section is formed by a brown miralite type composite oxide. A pair of electrodes are provided on the vicinity of the opposite ends of the purifying catalyst section. A conductivity measuring section measures conductivity of a nitrogen oxide catalyst of the nitrogen oxide purifying catalyst section through the electrodes. A control section controls an opening degree of the EGR valve on the basis of engine rpm, engine load and the conductivity measured in the conductivity measuring section.
摘要:
A refrigerator having a main body; a refrigerating compartment arranged at an upper position in the main body to refrigerate foods; and at least three lower compartments vertically arranged under the refrigerating compartment; wherein at least one of the lower compartments is a freezer compartment for freezing foods, and one of the remaining lower compartments is a vegetable compartment to store vegetables or a switchable compartment to make a temperature zone therein switchable between a freezing temperature zone and a temperature zone for refrigerated foods, vegetables or chilled foods.
摘要:
The present disclosure provides an exhaust gas purification catalyst having an improved Rh activation, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the upstream portion contains Rh fine particles and Pt, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation σ of the particle size of 0.8 nm or less, and wherein the downstream portion contains Rh.
摘要:
The present disclosure provides an exhaust gas purification catalyst having improved durability, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the downstream portion contains Rh fine particles, and wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation σ of the particle size of 0.8 nm or less.
摘要:
The present disclosure provides an exhaust gas purification catalyst having improved durability, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the downstream portion contains Rh fine particles, and wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation a of the particle size of 0.8 nm or less.
摘要:
An exhaust gas purifying catalyst for use in an oxygen surplus atmosphere, includes a brown millerite composite oxide for directly decomposing and absorbing nitrogen oxide (NOx), and a noble metal-series reducing catalyst disposed on the surface of said brown millerite composite oxide. The brown millerite composite oxide is represented by one of the following formulae: A3-aBaC4-bDbO9, A2-aBaC2-bDbO5, and A1-aBaC2-bDbO4 where A and B are elements selected from the group consisting of Ba, Ca, Sr, Mg and Ce, C and D are elements selected from the group consisting of Y, Dy, Zn, Ti, Mn, Fe, Co, Ni, Cu, Sn, Zr and Nd, a is within the range 0≦a
摘要翻译:一种用于富氧气氛的废气净化催化剂包括用于直接分解和吸收氮氧化物(NOx)的褐色石榴石复合氧化物,以及设置在所述棕色石榴石复合氧化物表面上的贵金属系还原催化剂。 褐铁矿复合氧化物由下式表示:其中A和B是选自Ba,Ca,Sr,Mg和Ce的元素,C和D是选自Y,Dy ,Zn,Ti,Mn,Fe,Co,Ni,Cu,Sn,Zr和Nd,a在0 <= a <1的范围内,b在0 <= b <2的范围内。