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公开(公告)号：US4229282A
公开(公告)日：1980-10-21
申请号：US33775
申请日：1979-04-27
申请人： Alan W. Peters , Emmerson Bowes , Thomas R. Stein
发明人： Alan W. Peters , Emmerson Bowes , Thomas R. Stein
摘要： An improved process for catalytically dewaxing a hydrocarbon oil is disclosed. In this process the waxy oil is contacted in the presence of hydrogen with a dense zeolitic dewaxing catalyst associated with a nickel-tungsten hydrogenation component. The dewaxed oil has unexpectedly good stability and a low bromine number compared with prior-art processed oils. The process may be used to dewax crude oils, fuel oil fractions and lubricating oils.
摘要翻译： 公开了一种用于催化脱蜡烃油的改进方法。 在该方法中，蜡状油在氢的存在下与与镍 - 钨氢化组分相关的致密的沸石脱蜡催化剂接触。 与现有技术的加工油相比，脱蜡的油具有出乎意料的良好的稳定性和低的溴数。 该方法可用于脱蜡原油，燃料油馏分和润滑油。
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2.发明授权Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index 失效改性结晶硅铝酸盐沸石催化剂及其在生产高黏度指数的润滑剂中的应用
公开(公告)号：US5157191A
公开(公告)日：1992-10-20
申请号：US756668
申请日：1991-09-09
申请人： Emmerson Bowes , David S. Shihabi
发明人： Emmerson Bowes , David S. Shihabi
CPC分类号： B01J29/40 , C10G50/02 , B01J2229/16 , B01J2229/36 , B01J2229/37 , B01J29/65 , B01J29/70
摘要： The catalytic activity of a crystalline aluminosilicate zeolite having a Constraint Index of from about 1 to about 12 for a variety of hydrocarbon conversions including the oligomerization of olefins to provide high viscosity index lubes is significantly enhanced by modifying the catalyst to reduce surface acid sites. This is accomplished by contacting the zeolite with a fluorosilicate salt to extract surface zeolitic aluminum which is replaced by silicon.
摘要翻译： 通过改性催化剂以减少表面酸性位点，显着提高了具有约1至约12约束指数约1至约12的结晶硅铝酸盐沸石的催化活性，用于各种烃转化，包括烯烃低聚提供高粘度指数的润滑剂。 这通过使沸石与氟硅酸盐接触以提取由硅代替的表面沸石铝来实现。
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公开(公告)号：US4486298A
公开(公告)日：1984-12-04
申请号：US267307
申请日：1981-05-28
CPC分类号： C10G25/003 , C10G25/00
摘要： A process for the demetalation of heavy petroleum residua is provided wherein said residua dispersed in a suitable solvent is contacted with a large pore solid sorbent whereby organomettalic compounds or complexes contained in said residua are selectively adsorbed by the large pore solid sorbent.
摘要翻译： 提供了一种用于脱模余辉石油残渣的方法，其中分散在合适溶剂中的所述残余物与大孔固体吸附剂接触，由此所述残留物中所含的有机化合物或络合物被大孔固体吸附剂选择性吸附。
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4.发明授权Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index 失效改性结晶硅铝酸盐沸石催化剂及其在生产高黏度指数的润滑剂中的应用
公开(公告)号：US5043307A
公开(公告)日：1991-08-27
申请号：US402716
申请日：1989-09-05
申请人： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
发明人： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
IPC分类号： C10G50/02
CPC分类号： C10G50/02
摘要： The present invention provides a process for modifying a crystalline aluminosilicate zeolite having a Constraint Index of from about to about 12 which comprises:a) steaming the as synthesized crystalline aluminosilicate zeolite containing organic template material to decompose at least a portion of said template material and to extract zeolitic aluminum; and,b) contacting the zeolite resulting from step (a) in the ammonium, alkali metal or hydrogen form with a dealuminizing agent which forms a water-soluble complex with aluminum to remove a further quantity of zeolitic aluminum therefrom.
摘要翻译： 本发明提供了一种修饰约约至约12约束指数的结晶硅铝酸盐沸石的方法，该方法包括：a）蒸煮含有有机模板材料的合成的结晶硅铝酸盐沸石以分解所述模板材料的至少一部分，以及 提取沸石铝; 和b）将由步骤（a）得到的沸石以铵，碱金属或氢的形式与脱铝剂接触，脱铝剂与铝形成水溶性络合物以从其中除去另外量的沸石铝。
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公开(公告)号：US4908120A
公开(公告)日：1990-03-13
申请号：US87199
申请日：1987-08-20
申请人： Emmerson Bowes , Fritz A. Smith
发明人： Emmerson Bowes , Fritz A. Smith
IPC分类号： C10G65/04
CPC分类号： C10G65/043
摘要： A lubricant dewaxing process which is useful with difficult feeds, especially highly waxy feeds having paraffin contents in excess of 25 weight percent or feeds with high nitrogen levels, employs two-step dewaxing in which the first stage is carried out under relatively mild conditions using a binder-free zeolite dewaxing catalyst to obtain extended catalyst cycle life between successive reactivations with a constant temperature for the duration of each dewaxing cycle. The second stage dewaxing is also carried out with a binder-free catalyst under conditions which maintain the target pour point for the product with a progressively increasing temperature during each dewaxing cycle. More than one preliminary dewaxing stage may be provided in order to reduce severity in each stage with mild conditions and constant temperature being maintained in the preliminary steps. Using this process, extended catalyst cycle lives may be obtained with difficult feeds.
摘要翻译： 用于难加工的润滑剂脱蜡方法，特别是具有超过25重量％的石蜡含量或高氮水平进料的高度蜡质进料采用两步脱蜡，其中第一阶段在相对温和的条件下进行，使用 无粘结剂的沸石脱蜡催化剂，以在每个脱蜡循环的持续时间内在恒定温度下连续反应之间获得延长的催化剂循环寿命。 在每个脱蜡循环期间，对于具有逐渐升高的温度的产品的目标倾点的条件下，还可以用无粘合剂的催化剂进行第二阶段脱蜡。 可以提供多于一个初步脱蜡阶段，以便在初步步骤中保持温和条件和恒定温度的各个阶段中减轻严重性。 使用该方法，可以通过困难的进料获得延长的催化剂循环寿命。
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公开(公告)号：US4780444A
公开(公告)日：1988-10-25
申请号：US606497
申请日：1984-05-03
申请人： Eric G. Derouane , Emmerson Bowes
发明人： Eric G. Derouane , Emmerson Bowes
IPC分类号： B01J29/84 , C10G11/04 , B01J27/182 , B01J27/14
摘要： There is provided a method for activating preformed, crystalline aluminum phosphates by combining these aluminum phosphates with an activating metal oxide, such as silica, and water under conditions, such as mulling, sufficient to increase the acid catalytic activity of the material.
摘要翻译： 提供了一种通过将这些磷酸铝与活化金属氧化物如二氧化硅和水在诸如研磨的条件下组合而足以增加材料的酸催化活性来激活预形成的结晶磷酸铝的方法。
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7.发明授权Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index 失效改性结晶硅铝酸盐沸石催化剂及其在生产高黏度指数的润滑剂中的应用
公开(公告)号：US5080878A
公开(公告)日：1992-01-14
申请号：US522485
申请日：1990-05-14
申请人： Emmerson Bowes , David S. Shihabi
发明人： Emmerson Bowes , David S. Shihabi
CPC分类号： C10G50/02 , B01J29/40 , B01J2229/16 , B01J2229/36 , B01J2229/37 , B01J29/65 , B01J29/70 , Y10S423/22 , Y10S423/23 , Y10S423/29 , Y10S423/33 , Y10S423/35 , Y10S423/36
摘要： The catalytic activity of a crystalline aluminosilicate zeolite having a Constraint Index of from about 1 to about 12 for a variety of hydrocarbon conversions including the oligomerization of olefins to provide high viscosity index lubes is significantly enhanced by modifying the catalyst to reduce surface acid sites. This is accomplished by contacting the zeolite with a fluorosilicate salt to extract surface zeolite aluminum which is replaced by silicon.
摘要翻译： 通过改性催化剂以减少表面酸性位点，显着提高了具有约1至约12约束指数约1至约12的结晶硅铝酸盐沸石的催化活性，用于各种烃转化，包括烯烃低聚提供高粘度指数的润滑剂。 这通过使沸石与氟硅酸盐接触以提取由硅代替的表面沸石铝来实现。
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8.发明授权Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index 失效改性结晶硅铝酸盐沸石催化剂及其在生产高黏度指数的润滑剂中的应用
公开(公告)号：US4876411A
公开(公告)日：1989-10-24
申请号：US27034
申请日：1987-03-19
申请人： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
发明人： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
IPC分类号： C10G50/02
CPC分类号： C10G50/02
摘要： The present invention provides a process for modifying a crystalline aluminosilicate zeolite having a Constraint Index of from about to about 12 which comprises:(a) steaming the as synthesized crytalline aluminosilicate zeolite containing organic template material to decompose at least a portion of said template material and to extract zeolitic aluminum; and,(b) contacting the zeolite resulting from step (a) in the ammonium, alkali metal or hydrogen form with a dealuminizing agent which forms a water-soluble complex with aluminum to remove a further quantity of zeolitic aluminum therefrom wherein said treated catalyst is employed in the making of lube oil from olefins.
摘要翻译： 本发明提供了一种修饰约约至约12的约束指数的结晶硅铝酸盐沸石的方法，该方法包括：（a）蒸煮含有有机模板材料的合成的胆固醇铝硅酸盐沸石，以分解所述模板材料的至少一部分，以及 提取沸石铝; 和（b）将由步骤（a）得到的沸石以铵，碱金属或氢的形式与脱铝剂接触，脱铝剂与铝形成水溶性络合物，以从中除去另外量的沸石铝，其中所述处理过的催化剂为 用于从烯烃制备润滑油。
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9.发明授权Preparation of natural ferrierite hydrocracking catalyst and hydrocarbon conversion with catalyst 失效天然镁碱沸石加氢裂化催化剂的制备和催化剂烃转化
公开(公告)号：US4335019A
公开(公告)日：1982-06-15
申请号：US225079
申请日：1981-01-13
申请人： Emmerson Bowes , Bruce P. Pelrine
发明人： Emmerson Bowes , Bruce P. Pelrine
CPC分类号： C10G45/64 , B01J29/67 , B01J29/68 , B01J29/69 , B01J2229/26 , B01J2229/37 , B01J2229/42 , C10G2300/70
摘要： A shape-selective hydrocracking catalyst prepared by making a composite of a hydrogenation component and a natural ferrierite that has been treated with oxalic acid to impart thereto catalytic activity for converting slightly branched as well as straight chain hydrocarbons. The catalyst is useful for hydrodewaxing and for upgrading naphtha.
摘要翻译： 通过制备已经用草酸处理的氢化组分和天然镁碱沸石的复合物赋予形式选择性加氢裂化催化剂以赋予其稍微转化和直链烃转化的催化活性。 该催化剂可用于加氢脱蜡和升级石脑油。
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公开(公告)号：US4018831A
公开(公告)日：1977-04-19
申请号：US612679
申请日：1975-09-11
申请人： Emmerson Bowes , Robert E. Chute
发明人： Emmerson Bowes , Robert E. Chute
CPC分类号： C07C45/62
摘要： 2-Ethyl hexanal is produced by hydrogenation of 2-ethyl hexene-2-al-1 without substantial formation of by-product 2-ethyl hexanol by liquid phase upflow through a catalyst bed with controlled hydrogen concentration at 90.degree.-180.degree. C and a pressure of 5-40 Kgm/cm.sup.2.
摘要翻译： 2-乙基己醛通过2-乙基己烯-2-al-1的氢化而产生，而通过液相上流通过催化剂床在90-180℃下控制氢浓度基本形成副产物2-乙基己醇， 压力为5-40Kgm / cm2。
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