Process for the manufacture of (iodoorganyl)alkoxysilanes
    3.
    发明授权
    Process for the manufacture of (iodoorganyl)alkoxysilanes 失效
    (碘代有机基)烷氧基硅烷的制备方法

    公开(公告)号:US4362885A

    公开(公告)日:1982-12-07

    申请号:US330355

    申请日:1981-12-14

    IPC分类号: C07F7/18 C07F7/08

    CPC分类号: C07F7/1888

    摘要: The subject of the invention is a process for the manufacture of (iodoorganyl)alkoxysilanes of the general formula: ##STR1## in which R.sup.1 is an alkylene group, R.sup.2 is an alkoxy group and R.sup.3 and R.sup.4 an alkoxy group and/or an alkyl or aryl group, whereby the chlorine or bromine compound corresponding to that of formula (1) is caused to react with stoichiometric to double molar quantities of an inorganic iodine donor in the presence of 0.01-5 mol % of an organic substituted onium salt of nitrogen, phosphorus, arsenic or antimony or an organic substituted sulfonium salt or a crown ether as catalyst, in certain solubilizing agents.

    摘要翻译: 本发明的主题是制备通式如下的(碘代有机基)烷氧基硅烷的方法:其中R1是亚烷基,R2是烷氧基,R3和R4是烷氧基和/或 烷基或芳基,其中使与对应于式(1)的氯或溴化合物在0.01-5mol%的有机取代鎓盐的存在下与化学计量比与双摩尔量的无机碘供体反应 的氮,磷,砷或锑或有机取代的锍盐或冠醚作为催化剂,在某些增溶剂中。

    Aqueous solution of cationic organosilicon compounds and process for the
production of the solutions
    4.
    发明授权
    Aqueous solution of cationic organosilicon compounds and process for the production of the solutions 失效
    阳离子有机硅化合物的水溶液及其制备方法

    公开(公告)号:US4390712A

    公开(公告)日:1983-06-28

    申请号:US298251

    申请日:1981-08-31

    IPC分类号: B03D1/01 C07F7/18 C07F7/10

    摘要: There are prepared aqueous solutions of cationic organosilicon compounds which are produced by reacting an alkoxysilylalkyl halide of the formula (RO).sub.3-n R.sub.n.sup.1 --Si--R.sup.2 --X (I) where R is C.sub.1 to C.sub.5 alkyl, methoxy, ethoxy, phenyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.1 is C.sub.1 to C.sub.5 alkyl, phenyl, tolyl, benzyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.2 is a divalent ethylenic double bond free hydrocarbon group having 3 to 8 carbon atoms, n is zero, 1 or 2 and X is chlorine, bromine, or iodine with a tertiary amine of the formula R.sup.3 NR.sup.4 R.sup.5 (II) where R.sup.3, R.sup.4, and R.sup.5 are the same or different and each is an alkyl group or benzyl in which the number of carbon atoms of the alkyl group or the alkyl groups together is up to 30 or R.sup.4 and .sup.5 together with the nitrogen atom, as well as in a given case a further hetero atom selected from the group consisting of oxygen, nitrogen, and sulfur is a univalent five to eight membered heterocyclic ring having three to seven --CH.sub.2 -- groups in the heterocyclic ring, or R.sup.5 is a C.sub.3 to C.sub.12 cycloalkyl group in aqueous medium at a temperature from room temperature (e.g. about 20.degree. C.) to 300.degree. C. at a mole ratio of (I) to (II) between 1:0.8 to 1:1,2 and in a given case under pressure.

    摘要翻译: 制备阳离子有机硅化合物的水溶液,其通过使式(RO)3-nRn1-Si-R2-X(I)的烷氧基​​甲硅烷基烷基卤化物反应制备,其中R是C1至C5烷基,甲氧基,乙氧基,苯基或 C5至C8环烷基; R 1是C 1至C 5烷基,苯基,甲苯基,苄基或C 5至C 8环烷基; R2是具有3-8个碳原子的二价烯键式双键无键烃基,n为0,1或2,X为氯,溴或碘,与式R3NR4R5(Ⅱ)的叔胺反应,其中R3,R4和 R5相同或不同,并且各自为烷基或苄基,其中烷基或烷基的碳原子数一起为至多30或R4和5以及氮原子以及在给定的 在另一个选自氧,氮和硫的杂原子的情况下,杂环中具有三至七个-CH 2 - 基的一价五元至八元杂环,或者R5是水性中的C3至C12环烷基 介质在室温(例如约20℃)至300℃的温度下以(I)至(II)的摩尔比为1:0.8至1:1.2,在给定情况下在压力下。

    Shaped articles for heat insulation
    8.
    发明授权
    Shaped articles for heat insulation 失效
    异形物品用于隔热

    公开(公告)号:US5362541A

    公开(公告)日:1994-11-08

    申请号:US147095

    申请日:1993-11-03

    IPC分类号: C04B30/00 B32B1/02 B32B9/00

    摘要: A preferably platelike form body for use as heat insulation, consisting of:a) a finely divided, powdery or fibrous material,b) a microporous casing andc) a gas and watertight casing.The form body is produced by optionally drying the powdery or fibrous material, optionally placing it into a microporous casing, optionally pressing it and then optionally drying it. Then, the powdery material is placed with the microporous casing into a gas and watertight casing. This gas and watertight casing is optionally evacuated and sealed.

    摘要翻译: 用作隔热材料的优选板状体,由以下部分组成:a)细碎的粉状或纤维状材料,b)微孔套管,c)气体和水密套管。 通过任选地干燥粉末或纤维材料,任选地将其置于微孔壳体中,任选地将其压制,然后任选地将其干燥来制造成形体。 然后,将粉状材料与微孔套管一起放入气体和水密套管中。 该气体和水密外壳可选择地抽真空并密封。

    Inclusion pigments of zirconium silicate with included chromic oxide, a
process for the preparation and use thereof
    9.
    发明授权
    Inclusion pigments of zirconium silicate with included chromic oxide, a process for the preparation and use thereof 失效
    含有氧化铬的硅酸锆的包含颜料,其制备方法和用途

    公开(公告)号:US5330571A

    公开(公告)日:1994-07-19

    申请号:US847498

    申请日:1992-03-12

    CPC分类号: C09C1/0081 C01P2002/08

    摘要: Inclusion pigments are discolored having zirconium silicate as a casing component and chromium (III) oxide (Cr.sub.2 O.sub.3) as a discrete, included color compound. The included Cr.sub.2 O.sub.3 has a D.sub.50 value in the range of 0.1 to 3.0 .mu.m and a brilliant light green color. Contrary to non-included Cr.sub.2 O.sub.3 of identical value, the pigments of the present invention may be used for the preparation of decorations without problems and difficulties in their application and maintaining sharp lines and contours. The pigments are suitable for direct pressing and high temperature firing processes. They are prepared by fusing a mixture of zirconium dioxide, silicon dioxide, mineralizators and chromium oxide.

    摘要翻译: 包含颜料变色,其具有硅酸锆作为外壳组分和作为分散的包括彩色化合物的氧化铬(III)(Cr 2 O 3)。 所含的Cr 2 O 3的D 50值为0.1〜3.0μm,亮绿色。 与不含相同值的Cr 2 O 3相反,本发明的颜料可用于制备装饰品而不会出现问题,并且难以应用并保持尖锐的线条和轮廓。 颜料适用于直接压制和高温烧制工艺。 它们通过熔融二氧化锆,二氧化硅,矿化剂和氧化铬的混合物来制备。