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    Nitrogen containing alkoxysilane and process for its production
    3.
    发明授权
    Nitrogen containing alkoxysilane and process for its production 失效
    含氮烷氧基硅烷及其生产方法

    公开(公告)号：US4337205A

    公开(公告)日：1982-06-29

    申请号：US182313

    申请日：1980-08-28

    申请人： Wolfgang Buder ,  Siegfried Wolff ,  Peter Kleinschmit

    发明人： Wolfgang Buder ,  Siegfried Wolff ,  Peter Kleinschmit

    IPC分类号： C07F7/18 ,  C07C117/04 ,  C07C118/04

    CPC分类号： C07F7/182

    摘要： There are prepared nitrogen containing alkoxysilanes of the formula (RO).sub.3-n (CH.sub.3).sub.n Si(CH.sub.2).sub.m NHCON.sub.3 in which R is an alkyl group having 1 to 3 carbon atoms, n is 0, 1 or 2 and m is 1, 2 or 3 by a process comprising dissolving in an inert solvent an isocyanate group containing silane of the formula (RO).sub.3-n (CH.sub.3).sub.n Si(CH.sub.2).sub.m N.dbd.C.dbd.O in which R, n and m are as defined above and reacting the silane with a water free hydrogen nitride or with hydrogen halide and an alkali metal-alkaline earth metal-, or ammonium azide at a temperature between 0.degree. C. and the boiling point of the inert solvent. The compounds are useful in making phosphinimines.

    摘要翻译： 制备式（RO）3-n（CH3）nSi（CH2）mNHCON3的含氮烷氧基硅烷，其中R是具有1至3个碳原子的烷基，n是0,1或2，m是1,2 或通过包括在惰性溶剂中溶解含有式（RO）3-n（CH 3）n Si（CH 2）m N = C = O的硅烷的异氰酸酯基团的方法，其中R，n和m如上所定义，并使 该硅烷与无水氮化氢或与卤化氢和碱金属 - 碱土金属或叠氮化铵在0℃至惰性溶剂的沸点之间的温度下进行。 该化合物可用于制备次膦酰亚胺。

    Process for the vacuum distillation of crude cyanohydrins containing 3 to 6 carbon atoms using liquid jet pump
    5.
    发明授权
    Process for the vacuum distillation of crude cyanohydrins containing 3 to 6 carbon atoms using liquid jet pump 失效
    使用液体喷枪将含有3至6个碳原子的原料氰化物真空蒸馏的方法

    公开(公告)号：US5091555A

    公开(公告)日：1992-02-25

    申请号：US592485

    申请日：1990-10-05

    申请人： Wolfgang Buder ,  Udo Rudolph

    发明人： Wolfgang Buder ,  Udo Rudolph

    IPC分类号： C07C253/34 ,  C07C255/16 ,  C07C255/34

    CPC分类号： C07C255/16 ,  Y02P20/582

    摘要： A process for the purification of crude cyanohydrins which contain 3 to 6 carbon atoms, especially of crude acetone cyanohydrin, by distilling off the unreacted reactants namely hydrogen cyanide and the carbonyl compound. The purification becomes very simple, and the unreacted reactants can be fed directly into the cyanohydrin synthesis, when the vacuum is generated with a liquid jet pump. The exhaust vapors arising in the distillation or desorption are led into the driving jet of the pump, the liquid jet pump is driven with crude cyanohydrin which contains basic catalyst, and the exhaust vapors absorbed in the crude cyanohydrin are reacted to completion in a cooled reaction circuit in which the liquid jet pump is incorporated.

    摘要翻译： 通过蒸馏未反应的反应物，即氰化氢和羰基化合物，纯化含有3至6个碳原子的粗氰醇的方法，特别是粗丙酮氰醇。 纯化变得非常简单，并且当用液体喷射泵产生真空时，未反应的反应物可以直接进料到氰醇合成中。 在蒸馏或脱附中产生的排气蒸气被引入泵的驱动喷射器中，液体喷射泵由含有碱性催化剂的粗氰醇驱动，并且在粗氰醇中吸收的排气蒸气在冷却反应中反应完成 引入液体喷射泵的电路。

    Method for preparation of 3-chloropropyl-trichlorosilane
    6.
    发明授权
    Method for preparation of 3-chloropropyl-trichlorosilane 失效
    3-氯丙基三氯硅烷的制备方法

    公开(公告)号：US4584395A

    公开(公告)日：1986-04-22

    申请号：US699696

    申请日：1985-02-08

    申请人： Peter Panster ,  Rudolf Michel ,  Wolfgang Buder ,  Peter Kleinschmit

    发明人： Peter Panster ,  Rudolf Michel ,  Wolfgang Buder ,  Peter Kleinschmit

    IPC分类号： C07F7/12 ,  B01J31/00 ,  C07B61/00 ,  C07F7/14 ,  C07F7/08

    CPC分类号： C07F7/14

    摘要： A method for the preparation of 3-chloropropyltrichlorosilane is carried out by conversion of trichlorosilane with allylchloride in the presence of a platinum containing polymeric organosiloxane-ammonium compound containing units represented by the structural formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 represent a group of the formula:R.sup.5 --SiO.sub.3/2 (2)wherein R.sup.5 denotes an alkylene group and the free valences of the oxygen atoms are saturated by silicon atoms of further groups of the formula (2), optionally with incorporation of crosslinking agents, R.sup.4 has the same meaning as R.sup.1, R.sup.2 and R.sup.3 or hydrogen, alkyl, cycloalkyl or benzyl, Y.sup.x- represents PtX.sub.4.sup.2- or PtX.sub.6.sup.2- (X is Cl or Br) and can also be an inorganic 1 to 3 functional anion of a protonic acid which yields stable salts with amine bases or the hydroxy group, and x is a number from 1 to 3.

    摘要翻译： 制备3-氯丙基三氯硅烷的方法是通过在含有由下列结构式表示的含有单元的含铂聚合物有机硅氧烷 - 铵化合物存在下，将三氯硅烷与烯丙基氯反应进行的：其中R1，R2和R3 代表式为R5-SiO3 / 2（2）的基团，其中R5表示亚烷基并且氧原子的游离价被另外的式（2）的基团的硅原子饱和，任选地加入交联剂 ，R4与R1，R2和R3或氢，烷基，环烷基或苄基具有相同的含义，Yx-表示PtX42-或PtX62-（X是Cl或Br），也可以是质子的无机1至3官能阴离子 其与胺碱或羟基产生稳定的盐，x为1至3的数。

    Production of organosilicon compounds having azido groups
    8.
    发明授权
    Production of organosilicon compounds having azido groups 失效
    生产具有叠氮基的有机硅化合物

    公开(公告)号：US4401598A

    公开(公告)日：1983-08-30

    申请号：US312979

    申请日：1981-10-20

    申请人： Alfons Karl ,  Wolfgang Buder

    发明人： Alfons Karl ,  Wolfgang Buder

    IPC分类号： G01F23/00 ,  G01F23/24 ,  C07C117/00

    CPC分类号： G01F23/245 ,  G01F23/0023

    摘要： There are prepared azido groups containing organosilicon compounds of the formula ##EQU1## where R is a divalent hydrocarbon group having 1 to 8 carbon atoms which is free from ethylenically unsaturated bonds and whose carbon chain in a given case, is interrupted once by --O--, --S--, or --NR.sup.3 where R.sup.3 is hydrogen, methyl, ethyl, or phenyl,R.sup.1 is a univalent alkyl group having 1 to 3 carbon atoms, phenyl, benzyl, or tolyl,R.sup.2 is an alkyl group having 1 to 4 carbon atoms, phenyl, benzyl, or an alkoxyalkyl group having a total of up to four carbon atoms,m is zero, 1, 2, or 3, andn is zero, 1 or 2 whereby m

    摘要翻译： 制备含有式（I）的有机硅化合物的叠氮基，其中R是不含烯属不饱和键的碳原子数为1至8的二价烃基，并且在给定情况下碳链被中断一次-O - ， - S-或-NR 3，其中R 3是氢，甲基，乙基或苯基，R 1是具有1至3个碳原子的一价烷基，苯基，苄基或甲苯基，R 2是具有1至4个 碳原子，苯基，苄基或总数最多为4个碳原子的烷氧基烷基，m为0,1,2或3，n为0,1或2，由此m <3-n，通过使 式XR-SiRn1（OR2）3-n，II的卤代硅烷，其中X是氯或溴，其他符号如上所定义，其中M是锂，钠，钾或铵的式MN3 III的叠氮化物 由此，在给出的情况下，使用相转移催化剂，由此进行水解或部分水解。 或者，可以首先进行水解或部分水解，其中首先进行一个或多个烷氧基甲硅烷基-OR 2的水解，随后进行与叠氮化物的反应。 有机硅化合物是有价值的中间体，也可用作制备二氧化硅增强橡胶的偶联剂。

    Aqueous solution of cationic organosilicon compounds and process for the production of the solutions
    9.
    发明授权
    Aqueous solution of cationic organosilicon compounds and process for the production of the solutions 失效
    阳离子有机硅化合物的水溶液及其制备方法

    公开(公告)号：US4390712A

    公开(公告)日：1983-06-28

    申请号：US298251

    申请日：1981-08-31

    申请人： Alfons Karl ,  Wolfgang Buder ,  Peter Kleinschmit

    发明人： Alfons Karl ,  Wolfgang Buder ,  Peter Kleinschmit

    IPC分类号： B03D1/01 ,  C07F7/18 ,  C07F7/10

    CPC分类号： C07F7/1892 ,  B03D1/0046 ,  B03D1/01

    摘要： There are prepared aqueous solutions of cationic organosilicon compounds which are produced by reacting an alkoxysilylalkyl halide of the formula (RO).sub.3-n R.sub.n.sup.1 --Si--R.sup.2 --X (I) where R is C.sub.1 to C.sub.5 alkyl, methoxy, ethoxy, phenyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.1 is C.sub.1 to C.sub.5 alkyl, phenyl, tolyl, benzyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.2 is a divalent ethylenic double bond free hydrocarbon group having 3 to 8 carbon atoms, n is zero, 1 or 2 and X is chlorine, bromine, or iodine with a tertiary amine of the formula R.sup.3 NR.sup.4 R.sup.5 (II) where R.sup.3, R.sup.4, and R.sup.5 are the same or different and each is an alkyl group or benzyl in which the number of carbon atoms of the alkyl group or the alkyl groups together is up to 30 or R.sup.4 and .sup.5 together with the nitrogen atom, as well as in a given case a further hetero atom selected from the group consisting of oxygen, nitrogen, and sulfur is a univalent five to eight membered heterocyclic ring having three to seven --CH.sub.2 -- groups in the heterocyclic ring, or R.sup.5 is a C.sub.3 to C.sub.12 cycloalkyl group in aqueous medium at a temperature from room temperature (e.g. about 20.degree. C.) to 300.degree. C. at a mole ratio of (I) to (II) between 1:0.8 to 1:1,2 and in a given case under pressure.

    摘要翻译： 制备阳离子有机硅化合物的水溶液，其通过使式（RO）3-nRn1-Si-R2-X（I）的烷氧基​​甲硅烷基烷基卤化物反应制备，其中R是C1至C5烷基，甲氧基，乙氧基，苯基或 C5至C8环烷基; R 1是C 1至C 5烷基，苯基，甲苯基，苄基或C 5至C 8环烷基; R2是具有3-8个碳原子的二价烯键式双键无键烃基，n为0,1或2，X为氯，溴或碘，与式R3NR4R5（Ⅱ）的叔胺反应，其中R3，R4和 R5相同或不同，并且各自为烷基或苄基，其中烷基或烷基的碳原子数一起为至多30或R4和5以及氮原子以及在给定的 在另一个选自氧，氮和硫的杂原子的情况下，杂环中具有三至七个-CH 2 - 基的一价五元至八元杂环，或者R5是水性中的C3至C12环烷基 介质在室温（例如约20℃）至300℃的温度下以（I）至（II）的摩尔比为1:0.8至1:1.2，在给定情况下在压力下。

    Process for the manufacture of (iodoorganyl)alkoxysilanes
    10.
    发明授权
    Process for the manufacture of (iodoorganyl)alkoxysilanes 失效
    （碘代有机基）烷氧基硅烷的制备方法

    公开(公告)号：US4362885A

    公开(公告)日：1982-12-07

    申请号：US330355

    申请日：1981-12-14

    申请人： Peter Panster ,  Alfons Karl ,  Wolfgang Buder ,  Peter Kleinschmit

    发明人： Peter Panster ,  Alfons Karl ,  Wolfgang Buder ,  Peter Kleinschmit

    IPC分类号： C07F7/18 ,  C07F7/08

    CPC分类号： C07F7/1888

    摘要： The subject of the invention is a process for the manufacture of (iodoorganyl)alkoxysilanes of the general formula: ##STR1## in which R.sup.1 is an alkylene group, R.sup.2 is an alkoxy group and R.sup.3 and R.sup.4 an alkoxy group and/or an alkyl or aryl group, whereby the chlorine or bromine compound corresponding to that of formula (1) is caused to react with stoichiometric to double molar quantities of an inorganic iodine donor in the presence of 0.01-5 mol % of an organic substituted onium salt of nitrogen, phosphorus, arsenic or antimony or an organic substituted sulfonium salt or a crown ether as catalyst, in certain solubilizing agents.

    摘要翻译： 本发明的主题是制备通式如下的（碘代有机基）烷氧基硅烷的方法：其中R1是亚烷基，R2是烷氧基，R3和R4是烷氧基和/或 烷基或芳基，其中使与对应于式（1）的氯或溴化合物在0.01-5mol％的有机取代鎓盐的存在下与化学计量比与双摩尔量的无机碘供体反应 的氮，磷，砷或锑或有机取代的锍盐或冠醚作为催化剂，在某些增溶剂中。