公开(公告)号：US06849243B1

公开(公告)日：2005-02-01

申请号：US09937524

申请日：2000-03-21

申请人： Alfred Hagemeyer ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Günter Dambeck ,  Gerhardt Geiss ,  Andrea Rutsch ,  Stephan Weidlich

发明人： Alfred Hagemeyer ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Günter Dambeck ,  Gerhardt Geiss ,  Andrea Rutsch ,  Stephan Weidlich

IPC分类号： B01J23/52 ,  B01J23/58 ,  B01J23/66 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C67/05 ,  C07C67/055 ,  C07C69/15 ,  C01B21/068 ,  C01B33/06

CPC分类号： B01J23/66 ,  B01J23/52 ,  B01J23/58 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： The invention relates to a supported catalyst and the production and use thereof in the synthesis of vinyl acetate in the gaseous phase from ethylene, acetic acid and oxygen, or from gases containing oxygen, whereby the activity and selectivity are simultaneously improved. The catalyst contains palladium, at least one alkali metal compound and optionally one or more catalyst accelerators, in particular, gold, barium and/or cadmium on a porous support. Said support contains at least one reducible metal oxide, in particular oxides of the elements of groups IIIb, IVb, Vb, VIb from the periodic table of elements. Once the support has been loaded with at least one palladium compound, a reduction is carried out at a temperature of >200° C.

摘要翻译： 本发明涉及负载催化剂及其在乙烯，乙酸和氧气或含氧气体合成乙酸乙烯酯的生产和应用，从而同时改善活性和选择性。 催化剂包含钯，至少一种碱金属化合物和任选的一种或多种催化剂促进剂，特别是多孔载体上的金，钡和/或镉。 所述载体包含至少一种可还原金属氧化物，特别是元素周期表中IIIb，IVb，Vb，VIb族元素的氧化物。 一旦载体上载有至少一种钯化合物，在> 200℃的温度下进行还原

公开(公告)号：US06372687B1

公开(公告)日：2002-04-16

申请号：US09173123

申请日：1998-10-15

申请人： Alfred Hagemeyer ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  John Meurig Thomas ,  Brian F. G. Johnson ,  D. S. Shephard ,  T. Maschmeyer

发明人： Alfred Hagemeyer ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  John Meurig Thomas ,  Brian F. G. Johnson ,  D. S. Shephard ,  T. Maschmeyer

IPC分类号： B01J2340

CPC分类号： B01J31/1616 ,  B01J21/08 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/0271 ,  B01J31/20 ,  B01J2231/641 ,  B01J2231/70 ,  B01J2231/76 ,  B01J2531/0211 ,  B01J2531/821

摘要： Supported catalysts having a high sintering stability and comprising one or more noble metal cluster carbonyl compounds of the formula (1) [HaMbNcLd(CO)x]n−An+ and their use for the dehydrogenation, hydrogenation and oxidation of organic compounds where M and N are, independently of one another, one or more metals selected from the group consisting of Pt, Rh, Ir, Os, Ru, Ag, Pd, Au, Ni, Fe, Co, Cu, Re, Mn; L is one or more neutral or anionic ligands which may be identical or different; (A)n+ is one or more cations which balance the charge of the complex; a is an integer from 0 to 10, preferably from 0 to 6; b is an integer from 2 to 60; c is an integer from 0 to 30; d is an integer from 0 to 60; x is an integer from 1 to 120; n is the total charge of the complex which results from the individual charges of the constituents and is greater than 0, wherein the compounds of the formula (1) are located in the pores of a mesoporous support material.

摘要翻译： 具有高烧结稳定性并且包含一种或多种式（1）的贵金属簇羰基化合物的负载型催化剂及其用于有机化合物的脱氢，氢化和氧化的用途，其中式（1）的化合物位于孔中 的介孔载体材料。

公开(公告)号：US06191312B1

公开(公告)日：2001-02-20

申请号：US09368081

申请日：1999-08-03

申请人： Alfred Hagemeyer ,  Rolf Peter Schulz ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Heinz Alexander

发明人： Alfred Hagemeyer ,  Rolf Peter Schulz ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Heinz Alexander

IPC分类号： C07C49105

CPC分类号： C07C49/443 ,  B01J29/70 ,  B01J2229/16 ,  C07C45/39

摘要： A process for preparing a bicyclooctanone, in particular 1,5-dialkylbicyclo[3.2.1]octan-8-one, by reacting a bicyclooctanol, in particular dialkylbicyclo[3.2.1]octan-8-ol, with a. a catalyst applied to an active-carbon support and comprising heteropolyoxometallate anions of vanadium, molybdenum and phosphorus, and also a corresponding alkali-metal, alkaline-earth-metal and/or ammonium counter ion, and b. a gaseous, oxygen-containing oxidizing agent.

摘要翻译： 一种通过使双环辛醇，特别是二烷基双环[3.2.1]辛烷-8-醇与二环辛烷酮，特别是1,1-二烷基双环[3.2.1]辛-8-酮的制备方法。 用于活性碳载体并包含钒，钼和磷的杂多金属氧酸盐阴离子的催化剂，以及相应的碱金属，碱土金属和/或铵的离子，和b。 一种气态的含氧氧化剂。

公开(公告)号：US06268522B1

公开(公告)日：2001-07-31

申请号：US09089627

申请日：1998-06-03

申请人： Alfred Hagemeyer ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Johannes Heitz ,  Dieter Bäuerle

发明人： Alfred Hagemeyer ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Johannes Heitz ,  Dieter Bäuerle

IPC分类号： C07C6705

CPC分类号： B01J37/345 ,  B01J23/44 ,  B01J23/52 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： The invention relates to a process for producing supported shell catalysts comprising noble metals by UV photoreduction of noble metal salt precursors fixed to a support. For this purpose, the shaped supported body is impregnated with suitable noble metal salts which are then reduced to the metals in a zone close to the surface by means of UV radiation, preferably in the absence of a chemical reducing agent. The metal salts in the interior of the pellets which have not been irradiated and therefore have not been reduced are extracted using a solvent. The noble metal shell catalysts produced in this way can be used for many heterogeneously catalyzed reactions such as hydrogenations and oxidations. According to the invention, Pd/Au shell catalysts on porous ceramic supports, e.g. SiO2 shaped bodies, produced by this process can be used in the synthesis of vinyl acetate.

摘要翻译： 本发明涉及通过紫外光还原固定在载体上的贵金属盐前体制备包含贵金属的负载型壳催化剂的方法。 为此，成形的支撑体浸渍有合适的贵金属盐，然后通过UV辐射将其还原成靠近表面的区域中的金属，优选在不存在化学还原剂的情况下。 使用溶剂提取未被照射并因此未被还原的颗粒内部的金属盐。以这种方式制备的贵金属壳催化剂可用于许多非均相催化反应如氢化和氧化。根据 对于本发明，Pd / Au壳催化剂在多孔陶瓷载体上，例如 通过该方法生产的SiO 2形体可用于乙酸乙烯酯的合成。