-
公开(公告)号:US20140163228A1
公开(公告)日:2014-06-12
申请号:US14077426
申请日:2013-11-12
CPC分类号: B01J20/226 , B01D53/02 , B01D2253/116 , B01D2256/245 , B01D2257/504 , B01J20/186 , B01J29/70 , B01J29/76 , B01J29/78 , B01J31/22 , B01J35/002 , B01J35/1014 , B01J35/1038 , C01B39/48 , Y02C10/08 , Y02P20/152
摘要: The present invention relates to molecular sieves having the structure of ITQ-32 is synthesized from a reaction mixture substantially free of fluoride ions and comprising 4,4-dimethyl, 1-cyclohexyl-piperazinium cations in its pore structure, as well as methods of making such molecular sieves and methods of using them.
摘要翻译: 本发明涉及具有ITQ-32结构的分子筛,其基本上不含氟离子的反应混合物,其孔结构中包含4,4-二甲基,1-环己基 - 哌嗪鎓阳离子,以及制备方法 这种分子筛和使用它们的方法。
-
公开(公告)号:US09266087B2
公开(公告)日:2016-02-23
申请号:US14077426
申请日:2013-11-12
IPC分类号: B01J20/18 , B01J20/22 , B01J31/22 , C01B39/48 , B01D53/02 , B01J29/70 , B01J29/76 , B01J29/78 , B01J35/00 , B01J35/10
CPC分类号: B01J20/226 , B01D53/02 , B01D2253/116 , B01D2256/245 , B01D2257/504 , B01J20/186 , B01J29/70 , B01J29/76 , B01J29/78 , B01J31/22 , B01J35/002 , B01J35/1014 , B01J35/1038 , C01B39/48 , Y02C10/08 , Y02P20/152
摘要: The present invention relates to molecular sieves having the structure of ITQ-32 is synthesized from a reaction mixture substantially free of fluoride ions and comprising 4,4-dimethyl, 1-cyclohexyl-piperazinium cations in its pore structure, as well as methods of making such molecular sieves and methods of using them.
摘要翻译: 本发明涉及具有ITQ-32结构的分子筛,其基本上不含氟离子的反应混合物,其孔结构中包含4,4-二甲基,1-环己基 - 哌嗪鎓阳离子,以及制备方法 这种分子筛和使用它们的方法。
-
公开(公告)号:US20150087841A1
公开(公告)日:2015-03-26
申请号:US14541777
申请日:2014-11-14
IPC分类号: C07D453/02 , C07D211/12
CPC分类号: C07D453/02 , B01J29/70 , C01B39/04 , C01B39/48 , C07D211/12 , C07D295/037
摘要: A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1-yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1′-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1′-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).
摘要翻译: 合成具有MSE骨架类型的结晶分子筛的方法包括使包含水源,四价元素的氧化物源Y的反应混合物结晶,Y选自硅,锡,钛,钒, 和锗,任选的三价元素的源,X,碱金属或碱土金属的源,M和有机二价元素的Q,例如3-羟基-1-(4-(1-甲基哌啶-4-基) (1-(1-甲基哌啶-1-基)戊基)奎宁环ium,1,1'ium基-1- yl基)丁基)奎宁环ium,3-羟基-1- - (丁烷-1,4-二基)双(1-甲基哌啶-1-基),1,1' - (戊烷-1,5-二基)双(1-甲基哌啶-1-基),1,1' - (己烷-1,6-二基)双(1-甲基哌啶-1-基)和1,1' - ((3as,6as) - 八氢二烯-2,5-二基)双(1-甲基哌啶-1-基) ium)。
-
公开(公告)号:US09035058B2
公开(公告)日:2015-05-19
申请号:US14541777
申请日:2014-11-14
IPC分类号: C07D453/02 , C07D211/12
CPC分类号: C07D453/02 , B01J29/70 , C01B39/04 , C01B39/48 , C07D211/12 , C07D295/037
摘要: A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1-yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1′-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1′-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).
摘要翻译: 合成具有MSE骨架类型的结晶分子筛的方法包括使包含水源,四价元素的氧化物源Y的反应混合物结晶,Y选自硅,锡,钛,钒, 和锗,任选的三价元素的源,X,碱金属或碱土金属的源,M和有机二价元素的Q,例如3-羟基-1-(4-(1-甲基哌啶-4-基) (1-(1-甲基哌啶-1-基)戊基)奎宁环ium,1,1'ium基-1- yl基)丁基)奎宁环ium,3-羟基-1- - (丁烷-1,4-二基)双(1-甲基哌啶-1-基),1,1' - (戊烷-1,5-二基)双(1-甲基哌啶-1-基),1,1' - (己烷-1,6-二基)双(1-甲基哌啶-1-基)和1,1' - ((3as,6as) - 八氢二烯-2,5-二基)双(1-甲基哌啶-1-基) ium)。
-
公开(公告)号:US09205416B2
公开(公告)日:2015-12-08
申请号:US14235419
申请日:2012-07-24
IPC分类号: C01B39/48 , B01J29/70 , B01J29/86 , B01J29/87 , B01J29/89 , C01B37/00 , C01B37/02 , C07D295/037
CPC分类号: C07D295/037 , B01J29/70 , B01J29/7007 , B01J29/86 , B01J29/87 , B01J29/89 , B01J35/002 , C01B37/00 , C01B37/02 , C01B39/48
摘要: A new molecular sieve material is designated as EMM-23 and has, in its as-calcined form, an X-ray diffraction pattern including the following peaks in Table 1: TABLE 1 d-spacing (Å)Relative Intensity [100 × I/I(o)] 17.5-16.360-100 10.6-10.15-50 9.99-9.5620-70 6.23-6.061-10 5.84-5.691-10 5.54-5.401-10 4.29-4.211-10 3.932-3.8641-10 3.766-3.7045-40 3.735-3.6741-10 3.657-3.5981-10 3.595-3.5391-20
摘要翻译: 一种新的分子筛材料被命名为EMM-23,并以其煅烧形式具有包括表1中以下峰的X射线衍射图:表1 d-间距(Å)相对强度[100×I / I(o)] 17.5-16.3 60-100 10.6-10.1 5-50 9.99-9.56 20-70 6.23-6.06 1-10 5.84-5.69 1-10 5.54-5.40 1-10 4.29-4.21 1-10 3.932-3.864 1-10 3.766-3.704 5-40 3.735-3.674 1-10 3.657-3.598 1-10 3.595-3.539 1-20
-
公开(公告)号:US20140336394A1
公开(公告)日:2014-11-13
申请号:US14235419
申请日:2012-07-24
IPC分类号: B01J29/70 , C07D295/037
CPC分类号: C07D295/037 , B01J29/70 , B01J29/7007 , B01J29/86 , B01J29/87 , B01J29/89 , B01J35/002 , C01B37/00 , C01B37/02 , C01B39/48
摘要: A new molecular sieve material is designated as EMM-23 and has, in its as-calcined form, an X-ray diffraction pattern including the following peaks in Table 1: TABLE 1 d-spacing (Å)Relative Intensity [100 × I/I(o)] 17.5-16.360-100 10.6-10.15-50 9.99-9.5620-70 6.23-6.061-10 5.84-5.691-10 5.54-5.401-10 4.29-4.211-10 3.932-3.8641-10 3.766-3.7045-40 3.735-3.6741-10 3.657-3.5981-10 3.595-3.5391-20
摘要翻译: 一种新的分子筛材料被命名为EMM-23,并以其煅烧形式具有包括表1中以下峰的X射线衍射图:表1 d-间距(Å)相对强度[100×I / I(o)] 17.5-16.3 60-100 10.6-10.1 5-50 9.99-9.56 20-70 6.23-6.06 1-10 5.84-5.69 1-10 5.54-5.40 1-10 4.29-4.21 1-10 3.932-3.864 1-10 3.766-3.704 5-40 3.735-3.674 1-10 3.657-3.598 1-10 3.595-3.539 1-20
-
公开(公告)号:US09636666B2
公开(公告)日:2017-05-02
申请号:US14188954
申请日:2014-02-25
申请人: Allen Wayne Burton , Karl G. Strohmaier , Hilda B. Vroman , Yifeng Yun , Xiaodong Zou , Wei Wan , Tom J. Willhammar
发明人: Allen Wayne Burton , Karl G. Strohmaier , Hilda B. Vroman , Yifeng Yun , Xiaodong Zou , Wei Wan , Tom J. Willhammar
CPC分类号: B01J29/70 , C01B37/007 , C01B39/12 , C01B39/48 , C07C7/13 , C07C2531/02 , C07C2601/16
摘要: A molecular sieve material, EMM-25, having in its calcined form an X-ray diffraction pattern including the following peaks: d-spacing (Å)Relative Intensity [100 × I/I(o)] % 11.74-11.34 60-100 9.50-9.1030-80 8.68-8.2810-40 5.64-5.4420-60 4.52-4.4210-50 4.28-4.1810-40 3.96-3.8640-80 3.69-3.5930-70.
-
公开(公告)号:US20160207032A9
公开(公告)日:2016-07-21
申请号:US14188954
申请日:2014-02-25
申请人: Allen Wayne Burton , Karl G. Strohmaier , Hilda B. Vroman , Yifeng Yun , Xiaodong Zou , Wei Wan , Tom J. Willhammar
发明人: Allen Wayne Burton , Karl G. Strohmaier , Hilda B. Vroman , Yifeng Yun , Xiaodong Zou , Wei Wan , Tom J. Willhammar
CPC分类号: B01J29/70 , C01B37/007 , C01B39/12 , C01B39/48 , C07C7/13 , C07C2531/02 , C07C2601/16
摘要: A molecular sieve material, EMM-25, having in its calcined form an X-ray diffraction pattern including the following peaks: d-spacing (Å)Relative Intensity [100 × I/I(o)] % 11.74-11.34 60-100 9.50-9.1030-80 8.68-8.2810-40 5.64-5.4420-60 4.52-4.4210-50 4.28-4.1810-40 3.96-3.8640-80 3.69-3.5930-70
-
公开(公告)号:US20150238945A1
公开(公告)日:2015-08-27
申请号:US14188954
申请日:2014-02-25
申请人: Allen Wayne Burton , Karl G. Strohmaier , Hilda B. Vroman , Yifeng Yun , Xiaodong Zou , Wei Wan , Tom J. Willhammar
发明人: Allen Wayne Burton , Karl G. Strohmaier , Hilda B. Vroman , Yifeng Yun , Xiaodong Zou , Wei Wan , Tom J. Willhammar
CPC分类号: B01J29/70 , C01B37/007 , C01B39/12 , C01B39/48 , C07C7/13 , C07C2531/02 , C07C2601/16
摘要: A molecular sieve material, EMM-25, having in its calcined form an X-ray diffraction pattern including the following peaks: d-spacing (Å)Relative Intensity [100 × I/I(o)] % 11.74-11.34 60-100 9.50-9.1030-80 8.68-8.2810-40 5.64-5.4420-60 4.52-4.4210-50 4.28-4.1810-40 3.96-3.8640-80 3.69-3.5930-70
摘要翻译: 分子筛材料EMM-25,其煅烧形式为包含以下峰的X射线衍射图:d-间距(Å)相对强度[100×I / I(o)]%11.74-11.34 60-100 9.50-9.10 30-80 8.68-8.28 10-40 5.64-5.44 20-60 4.52-4.42 10-50 4.28-4.18 10-40 3.96-3.86 40-80 3.69-3.59 30-70
-
公开(公告)号:US08562941B2
公开(公告)日:2013-10-22
申请号:US11637347
申请日:2006-12-12
CPC分类号: C01B39/02 , C01B37/00 , C01B39/026 , C01B39/04 , C01B39/265 , C01B39/42 , C01B39/44 , C01B39/48 , C01B39/54
摘要: The present invention is a method that perturbs the initial crystallization of a material from a less desired phase into a more desired phase. More specifically, the present invention is a method to form a different crystallization of a zeolite, mesoporous material, SAPO4, AlPO4 or porous inorganic oxide after the hydrothermal synthesis has started and a precursor crystalline phase has formed.
摘要翻译: 本发明是一种将材料从不太期望的阶段初始结晶化到更期望的阶段的方法。 更具体地,本发明是在水热合成开始并形成前体结晶相之后形成沸石,介孔材料,SAPO 4,AlPO 4或多孔无机氧化物的不同结晶的方法。
-
-
-
-
-
-
-
-
-