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    Process for hydroformylation using a catalyst based on cobalt and/or rhodium employed in a two-phase medium
    2.
    发明授权
    Process for hydroformylation using a catalyst based on cobalt and/or rhodium employed in a two-phase medium 有权
    使用在两相介质中使用的基于钴和/或铑的催化剂进行加氢甲酰化的方法

    公开(公告)号：US06469216B2

    公开(公告)日：2002-10-22

    申请号：US09730795

    申请日：2000-12-07

    申请人： Gerhard Hillebrand ,  André Hirschauer ,  Dominique Commereuc ,  Hélène Olivier-Bourbigou ,  Lucien Saussine

    发明人： Gerhard Hillebrand ,  André Hirschauer ,  Dominique Commereuc ,  Hélène Olivier-Bourbigou ,  Lucien Saussine

    IPC分类号： C07C4550

    CPC分类号： C07C45/50 ,  C07C47/02

    摘要： In an improved process for hydroformylation of olefinically unsaturated compounds using a catalyst based on cobalt and/or rhodium employed in a two-phase medium, a catalyst based on cobalt and/or rhodium is used dissolved in a non-aqueous ionic solvent which is liquid at a temperature of less than 90° C., in which the aldehydes formed are slightly soluble or insoluble. More particularly, the catalyst comprises at least one complex of cobalt and/or rhodium co-ordinated with at least one nitrogen-containing ligand and the non-aqueous ionic solvent comprises at least one quaternary ammonium and/or phosphonium cation and at least one inorganic anion. At the end of the reaction, the organic phase is generally separated and the ionic non-aqueous solvent phase containing the catalyst can be re-used.

    摘要翻译： 在使用基于在两相介质中使用的钴和/或铑的催化剂的烯属不饱和化合物的加氢甲酰基化的改进方法中，使用基于钴和/或铑的催化剂溶解在非水离子溶剂中，其为液体 在低于90℃的温度下，形成的醛是微溶或不溶的。 更具体地，催化剂包含与至少一种含氮配体配位的至少一种钴和/或铑配合物，非水离子溶剂包含至少一种季铵和/或鏻阳离子和至少一种无机 阴离子 在反应结束时，通常分离有机相，并且可以重新使用含有催化剂的离子非水溶剂相。

    Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling
    5.
    发明授权
    Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling 有权
    在具有改进的催化剂再循环的非水液体中使用钴基催化剂的羰基化方法

    公开(公告)号：US07060860B2

    公开(公告)日：2006-06-13

    申请号：US10411389

    申请日：2003-04-11

    申请人： Lionel Magna ,  Hélène Olivier-Bourbigou ,  Lucien Saussine ,  Virginie Kruger-Tissot

    发明人： Lionel Magna ,  Hélène Olivier-Bourbigou ,  Lucien Saussine ,  Virginie Kruger-Tissot

    IPC分类号： C07C45/50

    CPC分类号： C07B41/06 ,  C07C45/50 ,  Y02P20/584 ,  C07C47/02

    摘要： A process for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst is carried out in a non-aqueous ionic liquid which is a liquid at a temperature below 90° C. and comprises at least one ammonium and/or phosphonium and/or sulfonium cation Q+ and at least one anion A−; catalyst recycling is improved by using a ligand selected from the group consisting of Lewis bases and employing a depressurization step between the pressurized reaction step and the step for separating the phases by decanting. At the end of said depressurization step, the organic phase is separated in the decanting step and the non-aqueous ionic liquid containing the catalyst can be re-used.

    摘要翻译： 通过钴基催化剂加氢甲酰化烯属不饱和化合物的方法是在低于90℃的温度下为液体的非水性离子液体中进行的，并且包含至少一种铵和/或鏻和/或 锍阳离子Q + +和至少一种阴离子A - 通过使用选自路易斯碱的配体和在加压反应步骤和通过倾析分离相的步骤之间的减压步骤来改善催化剂再循环。 在所述减压步骤结束时，在倾析步骤中分离有机相，并且可以重新使用含有催化剂的非水性离子液体。

    Process for co-producing olefins and diesters or diacids starting from unsaturated fats
    8.
    发明授权
    Process for co-producing olefins and diesters or diacids starting from unsaturated fats 有权
    从不饱和脂肪开始共聚产生烯烃和二酯或二酸的方法

    公开(公告)号：US07906663B2

    公开(公告)日：2011-03-15

    申请号：US11626077

    申请日：2007-01-23

    申请人： Hélène Olivier-Bourbigou ,  Christophe Vallee ,  Gérard Hillion

    发明人： Hélène Olivier-Bourbigou ,  Christophe Vallee ,  Gérard Hillion

    IPC分类号： C07C51/00

    CPC分类号： C07C51/347 ,  C07C1/213 ,  C07C6/04 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/24 ,  C07C11/04 ,  C07C11/02 ,  C07C57/13 ,  C07C69/533 ,  C07C69/593

    摘要： In order to produce both an olefinic fraction and a composition of diacids or diesters of fats, a process is carried out which comprises, in succession: a) metathesis of an unsaturated fat with ethylene in the presence of at least one non-aqueous ionic liquid; b) separating and recycling the ionic liquid used in the first step; c) separating, by distillation, the olefinic fraction (fraction A) from the unsaturated fat mono-ester or mono-basic acid fraction (fraction B) formed in step a); d) homometathesis of the mono-unsaturated fat ester or acid cut (fraction B) which allows the co-production of unsaturated fat diesters or diacids (fraction C) and ethylene which is recycled to the first methathesis step of the process; and e) optionally, recycling the ionic liquid containing the catalyst used in step d). Of particular application to an oleic sunflower oil, an oleic rapeseed oil or to a mixture of mono-alcohol esters of said oils, whereupon the process can produce both an olefinic fraction (mainly composed of 1-decene) and a composition of diesters or diacids wherein, in general, over half of the chains is constituted by unsaturated C18 chains (mainly composed of octadecene-9 1,18-iacid or diester) and to recycle the ethylene employed.

    摘要翻译： 为了产生烯烃级分和脂肪二酸或二酯的组合物，进行了以下过程：a）在至少一种非水离子液体的存在下，不饱和脂肪与乙烯的复分解 ; b）分离和再循环第一步中使用的离子液体; c）通过蒸馏从步骤a）中形成的不饱和脂肪单酯或单碱性酸部分（级分B）分离出烯烃级分（级分A）; d）单不饱和脂肪酯或酸切割（B馏分）的同位素，其允许共生产不饱和脂肪二酯或二酸（馏分C）和乙烯，其被再循环到该方法的第一个复分解步骤; 和e）任选地，循环含步骤d）中使用的催化剂的离子液体。 特别适用于油酸向日葵油，油菜菜籽油或所述油的单醇酯的混合物，于是该方法可以产生烯​​烃级分（主要由1-癸烯组成）和二酯或二酸的组合物 其中通常一半以上的链由不饱和C18链（主要由十八碳烯-9,18-酸或二酯组成）构成，并循环使用乙烯。

    Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling
    9.
    发明授权
    Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling 有权
    在具有改进的催化剂再循环的非水液体中使用钴基催化剂的羰基化方法

    公开(公告)号：US07223374B2

    公开(公告)日：2007-05-29

    申请号：US11350881

    申请日：2006-02-10

    申请人： Lionel Magna ,  Hélène Olivier-Bourbigou ,  Lucien Saussine ,  Virginie Kruger-Tissot

    发明人： Lionel Magna ,  Hélène Olivier-Bourbigou ,  Lucien Saussine ,  Virginie Kruger-Tissot

    IPC分类号： B01J19/00 ,  B01J8/08

    CPC分类号： C07B41/06 ,  C07C45/50 ,  Y02P20/584 ,  C07C47/02

    摘要： A process for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst is carried out in a non-aqueous ionic liquid which is a liquid at a temperature below 90° C. and comprises at least one ammonium and/or phosphonium and/or sulfonium cation Q+ and at least one anion A−; catalyst recycling is improved by using a ligand selected from the group consisting of Lewis bases and employing a depressurization step between the pressurized reaction step and the step for separating the phases by decanting. At the end of said depressurization step, the organic phase is separated in the decanting step and the non-aqueous ionic liquid containing the catalyst can be re-used.

    摘要翻译： 通过钴基催化剂加氢甲酰化烯属不饱和化合物的方法是在低于90℃的温度下为液体的非水性离子液体中进行的，并且包含至少一种铵和/或鏻和/或 锍阳离子Q + +和至少一种阴离子A - 通过使用选自路易斯碱的配体和在加压反应步骤和通过倾析分离相的步骤之间的减压步骤来改善催化剂再循环。 在所述减压步骤结束时，在倾析步骤中分离有机相，并且可以重新使用含有催化剂的非水性离子液体。