公开(公告)号：US20090118392A1

公开(公告)日：2009-05-07

申请号：US12349900

申请日：2009-01-07

申请人： Andrew R. Barron ,  Dennis J. Flood ,  Andrew A. Guzelian

发明人： Andrew R. Barron ,  Dennis J. Flood ,  Andrew A. Guzelian

IPC分类号： C08K9/10 ,  C09K3/00

CPC分类号： C07F7/1804 ,  C07B2200/11 ,  Y10S423/39 ,  Y10S423/40 ,  Y10S977/734 ,  Y10S977/735 ,  Y10S977/742 ,  Y10T428/2993

摘要： This invention is directed to a new composition of matter in the form of chemically derivatized silica coated fullerenes, including silica coated C60 molecules and silica coated carbon nanotubes, processes for making the same and to uses for the derivatized silica coated fullerenes. Included among many uses in chemical, physical or biological fields of use, but not limited thereto, are high speed, low loss electrical interconnects for nanoscale electronic devices, components and circuits. In one embodiment, this invention also provides a method for preparing silica coated fullerenes having substituents attached to the surface of silica coated fullerenes by reacting silica coated fullerenes with a wide range of organic or inorganic chemical species in a gaseous or liquid state. Preferred substituents include but are not limited to organic groups and organic groups containing heteroatoms such as oxygen, nitrogen, sulfur, and halogens. The identity of the surface functional group is chosen to provide desirable properties to the silica coated fullerenes including but not limited to solubility, miscibility, stickiness, and melting point. The present invention also describes the application of surface functionalized silica coated fullerenes as components of polymer blends and composites.

摘要翻译： 本发明涉及以化学衍生的二氧化硅涂覆的富勒烯形式的物质的新组合物，包括二氧化硅涂覆的C60分子和二氧化硅涂覆的碳纳米管，其制备方法和用于衍生的二氧化硅涂覆的富勒烯的用途。 在化学，物理或生物领域的许多用途中包括用于纳米级电子器件，部件和电路的高速度，低损耗电互连，但不限于此。 在一个实施方案中，本发明还提供了一种制备二氧化硅涂覆的富勒烯的方法，其具有通过使二氧化硅涂覆的富勒烯与宽范围的气态或液态的有机或无机化学物质反应而附着到二氧化硅涂覆的富勒烯的表面上的取代基。 优选的取代基包括但不限于有机基团和含有杂原子如氧，氮，硫和卤素的有机基团。 选择表面官能团的身份来为二氧化硅涂覆的富勒烯提供所需的性质，包括但不限于溶解度，混溶性，粘性和熔点。 本发明还描述了表面官能化二氧化硅涂覆的富勒烯作为聚合物共混物和复合材料的组分的应用。

公开(公告)号：US20080233040A1

公开(公告)日：2008-09-25

申请号：US11451110

申请日：2006-06-12

申请人： Andrew R. Barron ,  Dennis J. Flood ,  Andrew A. Guzelian

发明人： Andrew R. Barron ,  Dennis J. Flood ,  Andrew A. Guzelian

IPC分类号： B32B1/00 ,  B32B9/00 ,  B32B15/02

CPC分类号： C07F7/1804 ,  C07B2200/11 ,  Y10S423/39 ,  Y10S423/40 ,  Y10S977/734 ,  Y10S977/735 ,  Y10S977/742 ,  Y10T428/2993

摘要： This invention is directed to a new composition of matter in the form of chemically derivatized silica coated fullerenes, including silica coated C60 molecules and silica coated carbon nanotubes, processes for making the same and to uses for the derivatized silica coated fullerenes. Included among many uses in chemical, physical or biological fields of use, but not limited thereto, are high speed, low loss electrical interconnects for nanoscale electronic devices, components and circuits. In one embodiment, this invention also provides a method for preparing silica coated fullerenes having substituents attached to the surface of silica coated fullerenes by reacting silica coated fullerenes with a wide range of organic or inorganic chemical species in a gaseous or liquid state. Preferred substituents include but are not limited to organic groups and organic groups containing heteroatoms such as oxygen, nitrogen, sulfur, and halogens. The identity of the surface functional group is chosen to provide desirable properties to the silica coated fullerenes including but not limited to solubility, miscibility, stickiness, and melting point. The present invention also describes the application of surface functionalized silica coated fullerenes as components of polymer blends and composites.

摘要翻译： 本发明涉及一种以化学衍生的二氧化硅涂覆的富勒烯形式的物质的新组合物，包括二氧化硅涂覆的C 60 C 60分子和二氧化硅涂覆的碳纳米管，其制备方法和用于衍生化的 二氧化硅涂覆的富勒烯。 在化学，物理或生物领域的许多用途中包括用于纳米级电子器件，部件和电路的高速度，低损耗电互连，但不限于此。 在一个实施方案中，本发明还提供了一种制备二氧化硅涂覆的富勒烯的方法，其具有通过使二氧化硅涂覆的富勒烯与宽范围的气态或液态的有机或无机化学物质反应而附着到二氧化硅涂覆的富勒烯的表面上的取代基。 优选的取代基包括但不限于有机基团和含有杂原子如氧，氮，硫和卤素的有机基团。 选择表面官能团的身份来为二氧化硅涂覆的富勒烯提供所需的性质，包括但不限于溶解度，混溶性，粘性和熔点。 本发明还描述了表面官能化二氧化硅涂覆的富勒烯作为聚合物共混物和复合材料的组分的应用。

公开(公告)号：US07491376B2

公开(公告)日：2009-02-17

申请号：US11451110

申请日：2006-06-12

申请人： Andrew R. Barron ,  Dennis J. Flood ,  Andrew A. Guzelian

发明人： Andrew R. Barron ,  Dennis J. Flood ,  Andrew A. Guzelian

IPC分类号： C01B31/00

CPC分类号： C07F7/1804 ,  C07B2200/11 ,  Y10S423/39 ,  Y10S423/40 ,  Y10S977/734 ,  Y10S977/735 ,  Y10S977/742 ,  Y10T428/2993

摘要： This invention is directed to a new composition of matter in the form of chemically derivatized silica coated fullerenes, including silica coated C60 molecules and silica coated carbon nanotubes, processes for making the same and to uses for the derivatized silica coated fullerenes. Included among many uses in chemical, physical or biological fields of use, but not limited thereto, are high speed, low loss electrical interconnects for nanoscale electronic devices, components and circuits. In one embodiment, this invention also provides a method for preparing silica coated fullerenes having substituents attached to the surface of silica coated fullerenes by reacting silica coated fullerenes with a wide range of organic or inorganic chemical species in a gaseous or liquid state. Preferred substituents include but are not limited to organic groups and organic groups containing heteroatoms such as oxygen, nitrogen, sulfur, and halogens. The identity of the surface functional group is chosen to provide desirable properties to the silica coated fullerenes including but not limited to solubility, miscibility, stickiness, and melting point. The present invention also describes the application of surface functionalized silica coated fullerenes as components of polymer blends and composites.

摘要翻译： 本发明涉及以化学衍生的二氧化硅涂覆的富勒烯形式的物质的新组合物，包括二氧化硅涂覆的C60分子和二氧化硅涂覆的碳纳米管，其制备方法和用于衍生的二氧化硅涂覆的富勒烯的用途。 在化学，物理或生物领域的许多用途中包括用于纳米级电子器件，部件和电路的高速度，低损耗电互连，但不限于此。 在一个实施方案中，本发明还提供了一种制备二氧化硅涂覆的富勒烯的方法，其具有通过使二氧化硅涂覆的富勒烯与宽范围的气态或液态的有机或无机化学物质反应而附着到二氧化硅涂覆的富勒烯的表面上的取代基。 优选的取代基包括但不限于有机基团和含有杂原子如氧，氮，硫和卤素的有机基团。 选择表面官能团的身份来为二氧化硅涂覆的富勒烯提供所需的性质，包括但不限于溶解度，混溶性，粘性和熔点。 本发明还描述了表面官能化二氧化硅涂覆的富勒烯作为聚合物共混物和复合材料的组分的应用。

公开(公告)号：US07692218B2

公开(公告)日：2010-04-06

申请号：US10534431

申请日：2003-11-19

申请人： Andrew R. Barron ,  Dennis J. Flood ,  Elizabeth A. Whitsitt ,  Robin E. Anderson ,  Graham B. I. Scott

发明人： Andrew R. Barron ,  Dennis J. Flood ,  Elizabeth A. Whitsitt ,  Robin E. Anderson ,  Graham B. I. Scott

IPC分类号： H01L31/00

CPC分类号： H01L29/80 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152 ,  G01N27/4146 ,  G01N33/551 ,  H01L29/0665 ,  H01L29/0673 ,  H01L29/0676 ,  H01L51/0049 ,  H01L51/0508 ,  Y10S977/936

摘要： A field effect transistor and a method for making the same. In one embodiment, the field effect transistor comprises a source; a drain; a gate; at least one carbon nanotube on the gate; and a dielectric layer that coats the gate and a portion of the at least one carbon nanotube, wherein the at least one carbon nanotube has an exposed portion that is not coated with the dielectric layer, and wherein the exposed portion is functionalized with at least one indicator molecule. In other embodiments, the field effect transistor is a biochem-FET.

摘要翻译： 场效应晶体管及其制造方法。 在一个实施例中，场效应晶体管包括源极; 排水 一个门 栅极上的至少一个碳纳米管; 以及覆盖所述栅极和所述至少一个碳纳米管的一部分的电介质层，其中所述至少一个碳纳米管具有未涂覆有所述电介质层的暴露部分，并且其中所述暴露部分用至少一个 指标分子。 在其他实施例中，场效应晶体管是生物化学FET。

公开(公告)号：US20080171204A1

公开(公告)日：2008-07-17

申请号：US11834471

申请日：2007-08-06

申请人： Andrew R. Barron ,  Dennis J. Flood ,  John R. Loscutova

发明人： Andrew R. Barron ,  Dennis J. Flood ,  John R. Loscutova

IPC分类号： B32B9/00 ,  H01L21/36

CPC分类号： G02B6/32 ,  B82Y15/00 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152 ,  C30B7/14 ,  C30B19/12 ,  C30B29/48 ,  C30B29/605 ,  H01L21/02376 ,  H01L21/02521 ,  H01L21/02601 ,  H01L21/02628 ,  Y10S977/70 ,  Y10S977/734 ,  Y10S977/737 ,  Y10S977/742 ,  Y10T428/2991 ,  Y10T428/30

摘要： A nanoparticle coated with a semiconducting material and a method for making the same. In one embodiment, the method comprises making a semiconductor coated nanoparticle comprising a layer of at least one semiconducting material covering at least a portion of at least one surface of a nanoparticle, comprising: (A) dispersing the nanoparticle under suitable conditions to provide a dispersed nanoparticle; and (B) depositing at least one semiconducting material under suitable conditions onto at least one surface of the dispersed nanoparticle to produce the semiconductor coated nanoparticle. In other embodiments, the nanoparticle comprises a fullerene. Further embodiments include the semiconducting material comprising CdS or CdSe.

摘要翻译： 涂覆有半导体材料的纳米颗粒及其制备方法。 在一个实施方案中，该方法包括制备半导体涂覆的纳米颗粒，其包含覆盖纳米颗粒的至少一个表面的至少一部分的至少一种半导体材料的层，包括：（A）在合适的条件下分散纳米颗粒以提供分散的 纳米颗粒 和（B）在合适的条件下将至少一种半导体材料沉积在分散的纳米颗粒的至少一个表面上以产生半导体涂覆的纳米颗粒。 在其它实施方案中，纳米颗粒包含富勒烯。 其它实施方案包括包含CdS或CdSe的半导体材料。

公开(公告)号：US20120119162A1

公开(公告)日：2012-05-17

申请号：US13270985

申请日：2011-10-11

申请人： Andrew R. Barron ,  Dennis J. Flood ,  Elizabeth Whitsitt

发明人： Andrew R. Barron ,  Dennis J. Flood ,  Elizabeth Whitsitt

IPC分类号： H01L23/48 ,  H01B1/24 ,  B05D5/00 ,  B05D3/10 ,  H01B1/18 ,  H01L21/56 ,  B82Y30/00

CPC分类号： H01L23/53276 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/152 ,  C01B32/168 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/28 ,  C01P2002/54 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/12 ,  C01P2004/13 ,  C01P2004/32 ,  C01P2004/84 ,  C01P2006/40 ,  C04B35/62807 ,  C04B2235/5288 ,  C08K9/02 ,  C09C1/3045 ,  C09C1/44 ,  H01L21/76838 ,  H01L51/0046 ,  H01L51/0048 ,  H01L51/0052 ,  H01L2924/0002 ,  Y10T428/30 ,  H01L2924/00

摘要： The present invention relates to coated fullerenes comprising a layer of at least one inorganic material covering at least a portion of at least one surface of a fullerene and methods for making. The present invention further relates to composites comprising the coated fullerenes of the present invention and further comprising polymers, ceramics, and/or inorganic oxides. A coated fullerene interconnect device where at least two fullerenes are contacting each other to form a spontaneous interconnect is also disclosed as well as methods of making. In addition, dielectric films comprising the coated fullerenes of the present invention and methods of making are further disclosed.

摘要翻译： 本发明涉及包含覆盖富勒烯的至少一个表面的至少一部分的至少一种无机材料的层的涂层富勒烯的制备方法。 本发明还涉及包含本发明的涂覆的富勒烯并且还包含聚合物，陶瓷和/或无机氧化物的复合材料。 还公开了其中至少两个富勒烯彼此接触以形成自发互连的涂覆的富勒烯互连装置以及制备方法。 此外，还公开了包含本发明的被覆富勒烯和制造方法的介电膜。

公开(公告)号：US07253014B2

公开(公告)日：2007-08-07

申请号：US10534452

申请日：2003-11-19

申请人： Andrew R. Barron ,  Dennis J. Flood ,  John Ryan Loscutova

发明人： Andrew R. Barron ,  Dennis J. Flood ,  John Ryan Loscutova

IPC分类号： H01L21/00

CPC分类号： G02B6/32 ,  B82Y15/00 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152 ,  C30B7/14 ,  C30B19/12 ,  C30B29/48 ,  C30B29/605 ,  H01L21/02376 ,  H01L21/02521 ,  H01L21/02601 ,  H01L21/02628 ,  Y10S977/70 ,  Y10S977/734 ,  Y10S977/737 ,  Y10S977/742 ,  Y10T428/2991 ,  Y10T428/30

摘要： A nanoparticle coated with a semiconducting material and a method for making the same. In one embodiment, the method comprises making a semiconductor coated nanoparticle comprising a layer of at least one semiconducting material covering at least a portion of at least one surface of a nanoparticle, comprising: (A) dispersing the nanoparticle under suitable conditions to provide a dispersed nanoparticle; and (B) depositing at least one semiconducting material under suitable conditions onto at least one surface of the dispersed nanoparticle to produce the semiconductor coated nanoparticle. In other embodiments, the nanoparticle comprises a fullerene. Further embodiments include the semiconducting material comprising CdS or CdSe.

摘要翻译： 涂覆有半导体材料的纳米颗粒及其制备方法。 在一个实施方案中，该方法包括制备半导体涂覆的纳米颗粒，其包含覆盖纳米颗粒的至少一个表面的至少一部分的至少一种半导体材料的层，包括：（A）在合适的条件下分散纳米颗粒以提供分散的 纳米颗粒 和（B）在合适的条件下将至少一种半导体材料沉积在分散的纳米颗粒的至少一个表面上以产生半导体涂覆的纳米颗粒。 在其它实施方案中，纳米颗粒包含富勒烯。 其它实施方案包括包含CdS或CdSe的半导体材料。

公开(公告)号：US09290665B2

公开(公告)日：2016-03-22

申请号：US13270985

申请日：2011-10-11

申请人： Andrew R. Barron ,  Dennis J. Flood ,  Elizabeth Whitsitt

发明人： Andrew R. Barron ,  Dennis J. Flood ,  Elizabeth Whitsitt

IPC分类号： C09C1/00 ,  C09C1/30 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/02 ,  C04B35/628 ,  C08K9/02 ,  C09C1/44 ,  H01L51/00

CPC分类号： H01L23/53276 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/152 ,  C01B32/168 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/28 ,  C01P2002/54 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/12 ,  C01P2004/13 ,  C01P2004/32 ,  C01P2004/84 ,  C01P2006/40 ,  C04B35/62807 ,  C04B2235/5288 ,  C08K9/02 ,  C09C1/3045 ,  C09C1/44 ,  H01L21/76838 ,  H01L51/0046 ,  H01L51/0048 ,  H01L51/0052 ,  H01L2924/0002 ,  Y10T428/30 ,  H01L2924/00

摘要： The present invention relates to coated fullerenes comprising a layer of at least one inorganic material covering at least a portion of at least one surface of a fullerene and methods for making. The present invention further relates to composites comprising the coated fullerenes of the present invention and further comprising polymers, ceramics, and/or inorganic oxides. A coated fullerene interconnect device where at least two fullerenes are contacting each other to form a spontaneous interconnect is also disclosed as well as methods of making. In addition, dielectric films comprising the coated fullerenes of the present invention and methods of making are further disclosed.

摘要翻译： 本发明涉及包含覆盖富勒烯的至少一个表面的至少一部分的至少一种无机材料的层的涂层富勒烯的制备方法。 本发明还涉及包含本发明的涂覆的富勒烯并且还包含聚合物，陶瓷和/或无机氧化物的复合材料。 还公开了其中至少两个富勒烯彼此接触以形成自发互连的涂覆的富勒烯互连装置以及制备方法。 此外，还公开了包含本发明的被覆富勒烯和制造方法的介电膜。

公开(公告)号：US08361349B2

公开(公告)日：2013-01-29

申请号：US12708225

申请日：2010-02-18

申请人： Andrew R. Barron ,  Dennis J. Flood ,  John Ryan Loscutova

发明人： Andrew R. Barron ,  Dennis J. Flood ,  John Ryan Loscutova

IPC分类号： H01B1/00 ,  B05D7/00

CPC分类号： G02B6/32 ,  B82Y15/00 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152 ,  C30B7/14 ,  C30B19/12 ,  C30B29/48 ,  C30B29/605 ,  H01L21/02376 ,  H01L21/02521 ,  H01L21/02601 ,  H01L21/02628 ,  Y10S977/70 ,  Y10S977/734 ,  Y10S977/737 ,  Y10S977/742 ,  Y10T428/2991 ,  Y10T428/30

摘要： A nanoparticle coated with a semiconducting material and a method for making the same. In one embodiment, the method comprises making a semiconductor coated nanoparticle comprising a layer of at least one semiconducting material covering at least a portion of at least one surface of a nanoparticle, comprising: (A) dispersing the nanoparticle under suitable conditions to provide a dispersed nanoparticle; and (B) depositing at least one semiconducting material under suitable conditions onto at least one surface of the dispersed nanoparticle to produce the semiconductor coated nanoparticle. In other embodiments, the nanoparticle comprises a fullerene. Further embodiments include the semiconducting material comprising CdS or CdSe.

摘要翻译： 涂覆有半导体材料的纳米颗粒及其制备方法。 在一个实施方案中，该方法包括制备半导体涂覆的纳米颗粒，其包含覆盖纳米颗粒的至少一个表面的至少一部分的至少一种半导体材料的层，包括：（A）在合适的条件下分散纳米颗粒以提供分散的 纳米颗粒 和（B）在合适的条件下将至少一种半导体材料沉积在分散的纳米颗粒的至少一个表面上以产生半导体涂覆的纳米颗粒。 在其它实施方案中，纳米颗粒包含富勒烯。 其它实施方案包括包含CdS或CdSe的半导体材料。

公开(公告)号：US07682527B2

公开(公告)日：2010-03-23

申请号：US11834471

申请日：2007-08-06

申请人： Andrew R. Barron ,  Dennis J. Flood ,  John Ryan Loscutova

发明人： Andrew R. Barron ,  Dennis J. Flood ,  John Ryan Loscutova

IPC分类号： H01B1/00 ,  H01B1/04

CPC分类号： G02B6/32 ,  B82Y15/00 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152 ,  C30B7/14 ,  C30B19/12 ,  C30B29/48 ,  C30B29/605 ,  H01L21/02376 ,  H01L21/02521 ,  H01L21/02601 ,  H01L21/02628 ,  Y10S977/70 ,  Y10S977/734 ,  Y10S977/737 ,  Y10S977/742 ,  Y10T428/2991 ,  Y10T428/30

摘要： A nanoparticle coated with a semiconducting material and a method for making the same. In one embodiment, the method comprises making a semiconductor coated nanoparticle comprising a layer of at least one semiconducting material covering at least a portion of at least one surface of a nanoparticle, comprising: (A) dispersing the nanoparticle under suitable conditions to provide a dispersed nanoparticle; and (B) depositing at least one semiconducting material under suitable conditions onto at least one surface of the dispersed nanoparticle to produce the semiconductor coated nanoparticle. In other embodiments, the nanoparticle comprises a fullerene. Further embodiments include the semiconducting material comprising CdS or CdSe.

摘要翻译： 涂覆有半导体材料的纳米颗粒及其制备方法。 在一个实施方案中，该方法包括制备半导体涂覆的纳米颗粒，其包含覆盖纳米颗粒的至少一个表面的至少一部分的至少一种半导体材料的层，包括：（A）在合适的条件下分散纳米颗粒以提供分散的 纳米颗粒 和（B）在合适的条件下将至少一种半导体材料沉积在分散的纳米颗粒的至少一个表面上以产生半导体涂覆的纳米颗粒。 在其它实施方案中，纳米颗粒包含富勒烯。 其它实施方案包括包含CdS或CdSe的半导体材料。