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公开(公告)号：US07361619B2
公开(公告)日：2008-04-22
申请号：US10819379
申请日：2004-04-06
CPC分类号： C10G2/33 , B01J23/75 , B01J23/8896 , B01J37/12 , B01J37/18
摘要： Dispersed Active Metal catalyst for hydrogenation reactions is produced by treating a substantially catalytically inactive metal particulate with a solution capable of oxidizing the metal particulate and comprising of at least one compound of a hydrogenation catalyst metal thereby forming a layer of at least one of hydroxides and oxides thereon. The metal particulate is activated by treatment with a hydrogen-containing gas at elevated temperatures to form a porous layer of Dispersed Active Metal catalyst. Preferably, the treated metal particulate is dried prior to activation, and also preferably calcined in an oxidant-containing atmosphere prior to activation. The treatment solution may advantageously contain a compound of at least one promoter metal for the added catalyst metal. The porosity of the layer provides enhanced catalyst activity as well as improved methane selectivity in the Fischer-Tropsch process.
摘要翻译： 用于氢化反应的分散活性金属催化剂通过用能够氧化金属颗粒并且包含至少一种氢化催化剂金属的化合物的溶液处理基本上催化惰性的金属颗粒而产生，从而形成氢氧化物和氧化物中的至少一种的层 上。 通过在高温下用含氢气体处理来活化金属颗粒以形成分散活性金属催化剂的多孔层。 优选地，处理的金属颗粒在活化之前被干燥，并且还优选在活化之前在含氧化剂的气氛中煅烧。 处理溶液可以有利地含有用于加入的催化剂金属的至少一种助催化剂金属的化合物。 该层的孔隙率提高了催化剂活性以及在费 - 托工艺中提高的甲烷选择性。
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公开(公告)号：US07419928B2
公开(公告)日：2008-09-02
申请号：US10819378
申请日：2004-04-06
CPC分类号： C10G2/332 , B01J23/75 , B01J23/8896 , B01J25/00 , B01J37/12 , B01J37/14 , B01J37/18 , C10G2/333
摘要： A process for enhancing the activity of a catalyst metal particulate for hydrogenation reactions comprising calcining the particulate in an oxidant-containing atmosphere to partially oxidize it thereby forming a porous layer of oxides thereon, treating with an solution capable of oxidizing the calcined metal particulate and comprising a compound of a hydrogenation catalyst metal to where said metal particulate has absorbed a volume of solution equal to at least about 10% of its calculated pore volume and activating it by treatment with a hydrogen-containing gas at elevated temperatures thereby forming a dispersed active metal catalyst. Preferably, the treated particulate is calcined a second time under the same conditions as the first before final activation with a hydrogen-containing gas. The metal particulate is preferably sized after each calcination and any agglomerates larger than 250 microns are comminuted to a desired size.
摘要翻译： 一种用于增强用于氢化反应的催化剂金属颗粒的活性的方法，包括在含氧化剂的气氛中煅烧颗粒以部分氧化，从而在其上形成多孔氧化物层，用能够氧化煅烧金属颗粒的溶液进行处理并包含 氢化催化剂金属的化合物，其中所述金属颗粒吸收了等于其计算孔体积的至少约10％的溶液体积，并通过在高温下用含氢气体处理使其活化，由此形成分散的活性金属 催化剂。 优选地，处理的颗粒在与含氢气体最终活化之前的第一次相同的条件下煅烧第二次。 优选在每次煅烧之后将金属颗粒定形，并将大于250微米的任何附聚物粉碎至所需尺寸。
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公开(公告)号：US4962239A
公开(公告)日：1990-10-09
申请号：US456702
申请日：1989-12-26
申请人： Weldon K. Bell , Werner O. Haag , David O. Marler
发明人： Weldon K. Bell , Werner O. Haag , David O. Marler
IPC分类号： B01J29/86 , B01J20060101 , B01J29/04 , B01J29/06 , B01J29/70 , C07B61/00 , C07C20060101 , C07C2/12 , C07C41/06 , C07C43/02 , C07C43/04 , C10G20060101
CPC分类号： B01J29/04 , C07C2/12 , C07C41/06 , C07C2529/70
摘要： Olefin is etherified with alcohol to provide an ether or mixture of ethers employing catalyst comprising zeolite characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36+0.4, 11.03+0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译： 烯烃与醇醚化以提供醚或醚的混合物，其使用包含沸石的催化剂，其特征在于X射线衍射图包括在12.36±0.4,11.03±0.2,8.83±0.14,6.13±0.128°的面间d-间距 ，6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。
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公开(公告)号：US5225609A
公开(公告)日：1993-07-06
申请号：US808496
申请日：1991-12-17
申请人： Weldon K. Bell , Werner O. Haag
发明人： Weldon K. Bell , Werner O. Haag
IPC分类号： C07C41/06
CPC分类号： C07C41/06
摘要： A process is disclosed for the production of alkyl tertiary alkyl ether from alkanol and iso-olefin employing zeolite catalyst, particularly zeolite Beta, that results is a high ether selectivity and a significant reduction in the formation of olefin oligomer by-product. The improvement is realized by incorporating a catalyst pretreatment step in the overall etherification process. The zeolite catalyst pretreatment comprises either steaming or a hydrothermal treatment using liquid water at elevated temperature. The process is particularly effective in reducing the formation of dimer by-product in the zeolite Beta catalyzed process for the formation of MTBE with high selectivity.
摘要翻译： 公开了一种使用沸石催化剂，特别是β沸石从链烷醇和异烯烃制备烷基叔烷基醚的方法，其结果是高的醚选择性和烯烃低聚物副产物的形成显着降低。 通过在整体醚化过程中引入催化剂预处理步骤来实现改进。 沸石催化剂预处理包括在高温下使用液态水蒸汽或水热处理。 该方法特别有效地减少用于形成MTBE的沸石β催化过程中二聚体副产物的形成，具有高选择性。
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公开(公告)号：US5144086A
公开(公告)日：1992-09-01
申请号：US695843
申请日：1991-05-06
CPC分类号： C07C41/09 , C07C1/24 , C07C2529/70
摘要： A process for synthesizing di-isopropyl ether (DIPE) by etherification of isopropanol. A multi-stage process can employ propene in mixture with other feedstock materials, such as propane from refinery gas, in a primary hydration stage to produce isopropanol. The isopropanol is enriched between stages to remove water. In the second reaction stage the isopropanol is converted catalytically with large pore acidic zeolite to yield DIPE, which can be separated to recover pure propene.
摘要翻译： 通过异丙醇醚化合成二异丙醚（DIPE）的方法。 多级方法可以在初级水合阶段中使用丙烯与其它原料物质混合，例如来自精炼厂气体的丙烷，以产生异丙醇。 阶段之间富含异丙醇以除去水分。 在第二反应阶段，异丙醇用大孔酸性沸石催化转化，得到DIPE，可以分离回收纯丙烯。
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公开(公告)号：US5013329A
公开(公告)日：1991-05-07
申请号：US331201
申请日：1989-03-31
摘要： A process is disclosed for converting a light hydrocarbon feedstock that contains a mixture of linear and branched olefins to ether-rich high octane gasoline streams that include tertiary alkyl and isoalkyl ethers such as MTBE, TAME, methyl isopropyl ether (MIPE), and methyl sec-butylether (MSBE). The conversion is achieved by utilizing the differing reactivity of tertiary olefins under selected conditions compared to linear olefins in the catalyzed etherification processes. The discovery has been made that unreacted olefins from the etherification reactions can be converted to gasoline boiling range hydrocarbons by contacting them with zeolite catalyst at elevated temperature. Further, it has been discovered that unreacted paraffins in the integrated process can be dehydrogenated to produce C.sub.3 -C.sub.4 olefins which can be recycled to the etherification process.
摘要翻译： 公开了一种将包含直链和支链烯烃的混合物的轻质烃原料转化成富含高级辛烷值汽油的方法，其中包括叔烷基和异烷基醚如MTBE，TAME，甲基异丙醚（MIPE）和甲基sec 丁基醚（MSBE）。 通过在催化醚化过程中与线性烯烃相比，在选择的条件下利用三级烯烃的不同反应性来实现转化。 已经发现，来自醚化反应的未反应的烯烃可以通过在升高的温度下与沸石催化剂接触而转化为汽油沸程烃。 此外，已经发现，一体化方法中的未反应的链烷烃可以脱氢生产可以再循环到醚化过程的C 3 -C 4烯烃。
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7.发明授权Method for preparing a promoted iron catalyst and catalyst prepared by the method for conversion of synthesis gas to liquid hydrocarbons 失效通过将合成气转化为液态烃的方法制备促进的铁催化剂和催化剂的方法
公开(公告)号：US4994428A
公开(公告)日：1991-02-19
申请号：US324796
申请日：1989-03-17
申请人： Weldon K. Bell , Werner O. Haag
发明人： Weldon K. Bell , Werner O. Haag
CPC分类号： B01J37/10 , B01J23/78 , B01J37/16 , C07C1/0445 , C07C2523/745 , C07C2527/232
摘要： A novel Fischer Tropsch iron catalyst that has unusually high selectivity for liquid hydrocarbons (low selectivity for methane) is provided. The catalyst is prepared by treatment of the usual inactive catalyst precursor with water vapor at elevated temperature either after conventional activation by syngas or concurrently therewith. Surprisingly, the "selectivation" with water vapor does not affect catalytic activity. The novel "selectivated" catalyst may be used to advantage either to increase temperature and throughput, or to increase liquid hydrocarbon selectivity, compared with conventional catalyst that has not been "selectivated".
摘要翻译： 提供了一种具有非常高的液体烃选择性（甲烷选择性低）的新型费 - 托铁催化剂。 催化剂是通过在常规的合成气活化或与其同时的高温下用水蒸气处理常规的惰性催化剂前体来制备的。 令人惊讶的是，水蒸汽的“选择”不影响催化活性。 与未进行“选择”的常规催化剂相比，新型“选择性”催化剂可以用于增加温度和通量，或者增加液体烃选择性。
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公开(公告)号：US5714640A
公开(公告)日：1998-02-03
申请号：US184537
申请日：1994-01-21
申请人： Weldon K. Bell , Stephen H. Brown , Frederick E. Daugherty , Mohsen N. Harandi , Jeffrey C. Trewella
发明人： Weldon K. Bell , Stephen H. Brown , Frederick E. Daugherty , Mohsen N. Harandi , Jeffrey C. Trewella
CPC分类号： C07C41/06 , C07B61/00 , C07C2/12 , C07C2521/08 , C07C2529/70 , Y02P20/127 , Y02P20/582
摘要： A condensation reaction process and reactor for converting a plurality of reactants to at least one reaction product having a vapor pressure less than the vapor pressure of the reactants. The process includes heating a liquid phase of the reactants to at least partial vaporization thus forming a vapor phase of the reactants. The vapor phase reactants are passed in a vapor and or condensed state through at least one catalyst bed spaced from the liquid state to form reaction product(s). The reaction product(s) is returned to the liquid phase without additional contact with catalyst.
摘要翻译： 一种缩合反应过程和反应器，用于将多种反应物转化成至少一种具有低于反应物的蒸气压的蒸气压的反应产物。 该方法包括将反应物的液相加热至少部分汽化，从而形成反应物的气相。 气相反应物以蒸气和/或冷凝状态通过与液态间隔开的至少一个催化剂床，以形成反应产物。 反应产物返回到液相，而不与催化剂另外接触。
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公开(公告)号：US5414146A
公开(公告)日：1995-05-09
申请号：US109971
申请日：1993-08-23
IPC分类号： C07C41/06
CPC分类号： C07C41/06 , C07C41/42 , Y10S203/06
摘要： Porous metallosilicate catalyst (e.g. Zeolite Beta) is active at low temperature for converting lower alkanol (e.g. methanol) and C.sub.4 -C.sub.7 tertiary alkenes to high octane ether product. Such catalytic reaction is especially useful in multizone catalytic reactor systems employing catstill rectification.
摘要翻译： 多孔金属硅酸盐催化剂（例如沸石β）在低温下是有活性的，用于将低级烷醇（例如甲醇）和C 4 -C 7叔烯烃转化成高辛烷值的产物。 这种催化反应在使用密度整流的多区域催化反应器系统中特别有用。
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10.发明授权
公开(公告)号：US5569789A
公开(公告)日：1996-10-29
申请号：US510371
申请日：1995-08-02
摘要： A multistaged fixed catalyst bed process for the production of diisopropyl ether and isopropanol is disclosed comprising a fixed bed of serially connected stages containing zeolite Beta catalyst. A feedstream of propylene and water equivalents selected from the group consisting of water, isopropanol and diisopropyl ether is introduced into each stage at a rate sufficient to provide a mole ratio of water equivalents to propylene equivalents that increases in increments by stage from at least 0.1 in a first stage to at most 1.2 in a final stage. The feedstream is introduced at a temperature between 50.degree. and 450.degree. C., pressure between 700 and 24000 kPa, and weight hourly space velocity between 0.10 and 30, based on catalyst, whereby a single non-aqueous liquid phase is maintained in the fixed bed. An effluent product stream is recovered comprising diisopropyl ether, isopropanol and water from the final stage. Isopropanol is recycled to the first stage when the preferred product is diisopropyl ether. When the preferred product is isopropanol, diisopropyl ether and water are recycled to the first stage.
摘要翻译： 公开了一种用于生产二异丙醚和异丙醇的多阶段固定催化剂床方法，其包括含有沸石β催化剂的连续连续步骤的固定床。 将丙烯和水当量的进料流选自水，异丙醇和二异丙基醚以足以提供水当量与丙烯当量的摩尔比的速率被引入每个阶段，其增量逐步增加至少0.1 在最后阶段达到最多1.2的第一阶段。 基于催化剂，在50〜450℃的温度，700〜24000kPa的压力和0.10〜30的重时空速下引入原料流，由此将单一的非水性液相保持在固定 床。 从最后阶段回收包含二异丙基醚，异丙醇和水的流出物产物流。 当优选的产物是二异丙醚时，异丙醇被再循环到第一阶段。 当优选的产物是异丙醇时，二异丙醚和水再循环到第一阶段。
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