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1.发明授权Oriented polymeric sheets exhibiting dichroism and articles containing the same 有权具有二色性的定向聚合物片和含有它们的物品公开(公告)号：US09096014B2
公开(公告)日：2015-08-04
申请号：US11779386
申请日：2007-07-18
申请人： Anil Kumar , Peter C. Foller , David Park , Declan Devine , Cornelis Wilhelmus Maria Bastiaansen , Jean-Pierre Teunissen , Martin Cloonan , Clement L. Higginbotham
发明人： Anil Kumar , Peter C. Foller , David Park , Declan Devine , Cornelis Wilhelmus Maria Bastiaansen , Jean-Pierre Teunissen , Martin Cloonan , Clement L. Higginbotham
CPC分类号： C08J5/18 , B29C55/12 , B29K2995/0034 , C08J2323/20 , C08J2375/04 , C08J2377/00 , G01N21/19 , G02B5/23 , G02B5/305 , G02F1/133533 , G02F2202/14 , G03C1/733
摘要： Provided is an oriented polymeric sheet comprising a photochromic-dichroic material, wherein the sheet exhibits dichroism in an activated state. Also provided is a multilayer composite comprising at least a support layer; and an oriented thermoplastic polymeric sheet having two opposing surfaces and comprising a photochromic-dichroic material. The sheet exhibits dichroism in an activated state. At least one surface of the sheet is connected to at least a portion of the support layer. The present invention also relates to an optical element comprising the multilayer composite. Related methods also are disclosed.
摘要翻译： 提供了包含光致变色二色性材料的定向聚合物片材，其中片材呈活性状态的二色性。 还提供了至少包含支撑层的多层复合材料; 以及具有两个相对表面并且包含光致变色二色性材料的取向热塑性聚合物片材。 该片材呈活性状态的二色性。 片材的至少一个表面连接到支撑层的至少一部分。 本发明还涉及包含多层复合材料的光学元件。 还公开了相关方法。
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公开(公告)号：US20120033173A1
公开(公告)日：2012-02-09
申请号：US13145845
申请日：2010-01-22
申请人： Dirk J. Broer , Y. Han , Casper Laurens Van Oosten , Daniel Adalbert Nowak , Rintje Pieter Sijbensma , Jean-Pierre Teunissen , Cornelis Wilhelmus Maria Bastiaansen , Katherine Pacheco
发明人： Dirk J. Broer , Y. Han , Casper Laurens Van Oosten , Daniel Adalbert Nowak , Rintje Pieter Sijbensma , Jean-Pierre Teunissen , Cornelis Wilhelmus Maria Bastiaansen , Katherine Pacheco
CPC分类号： G01K11/06 , G01K11/165 , G01N31/22
摘要： The invention relates to a multifunctional optical sensor, having at least 2 areas which independently react to different input parameters, the sensor comprising a substrate and a polymeric layer comprising polymerized liquid crystal monomers having an ordered morphology, wherein the color, the reflectivity or the birefringence of the sensor changes due to a change of the morphology, wherein said change of the morphology is caused by physical contact with a chemical agent such as a gas or liquid a change of temperature, or passage of time. The invention also relates to a process for the preparation of the sensor and for the use of a film comprising a single substrate, a layer having a cholesteric liquid crystalline structure for application in labels for packaging of perishable goods, food, fine chemicals, bio-medical materials.
摘要翻译： 本发明涉及一种多功能光学传感器，其具有独立地响应于不同输入参数的至少2个区域，所述传感器包括基底和聚合物层，聚合物层包含具有有序形态的聚合液晶单体，其中颜色，反射率或双折射 传感器由于形态的变化而变化，其中所述形态的变化是由与化学试剂例如气体或液体的温度变化或时间的物理接触引起的。 本发明还涉及一种用于制备传感器和使用包含单个基底的薄膜的方法，具有胆甾醇型液晶结构的层以用于易腐食品包装的食品，食品，精细化学品， 医疗材料。
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公开(公告)号：US20100279074A1
公开(公告)日：2010-11-04
申请号：US12663916
申请日：2008-05-23
CPC分类号： G03F7/36 , G03F7/38 , Y10T428/24612
摘要： The invention relates to a process for the preparation of a polymeric relief structure comprising the steps of coating a substrate with a coating composition comprising one or more radiation-sensitive ingredients, locally treating the coated substrate with electromagnetic radiation having a periodic or random radiation-intensity pattern, forming a latent image, and polymerizing and/or crosslinking the resulting coated substrate, wherein the coating composition comprises one or more RAFT agents.
摘要翻译： 本发明涉及一种制备聚合物浮雕结构的方法，包括以下步骤：用包含一种或多种辐射敏感成分的涂料组合物涂覆基材，用具有周期性或随机辐射强度的电磁辐射局部处理涂覆的基材 形成潜像，并聚合和/或交联所得涂覆的基材，其中涂料组合物包含一种或多种RAFT试剂。
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4.发明授权Method for producing an optical rod-shaped graded-index polymer preform, preform obtained in accordance with this method and optical lens and optical fibre obtained by using same 失效用于制造光棒状渐变折射率聚合物预成型体的方法，根据该方法获得的预成型体和使用其获得的光学透镜和光纤
公开(公告)号：US6166107A
公开(公告)日：2000-12-26
申请号：US125155
申请日：1999-03-01
IPC分类号： G02B6/00 , B29C41/00 , B29C41/04 , B29D11/00 , C08F2/00 , C08F20/22 , D01F6/36 , G02B1/04 , G02B3/00 , G02B6/028 , C08L83/00 , C08F18/20
CPC分类号： B29C41/003 , B29C41/04 , B29D11/00355 , B29D11/00682 , B29D11/00721
摘要： A method for producing optical rod-shaped graded-index polymer preform by making the composition of the preform near the core differ from the composition of the shell of the preform by polymerization with rotation of a mixture containing the starting substances, whereby a mixture comprising various monomers is rotated and that after achieving a distribution of the monomers, the polymerization is carried out with rotation of the mixture, or that a monomer and thermoplastic polymer-containing mixture, whereby said monomer is different from the monomer from which said polymer has been prepared, is rotated and that, after achieving a distribution of said monomer and polymer, the monomer present in said mixture is subsequently polymerized with rotation, in which both cases the rotation is carried out with a diameter dependent rotation velocity, represented by the following general equation: rpm>10,000 d.sup.-0.5 wherein: rpm=rotation velocity, revolutions per minute d=diameter of the preform (cm). The invention furthermore relates to optical lenses and fibres formed of the polymer preform thus produced.
摘要翻译： PCT No.PCT / NL97 / 00055 Sec。 371日期1999年3月1日 102（e）1999年3月1日PCT 1997年2月12日PCT PCT。 第WO97 / 29903号公报 日期1997年8月21日制造光学棒状渐变折射率聚合物预成型体的方法通过使预成型体的组合物通过使包含起始物质的混合物的旋转聚合而与核预成型体的壳的组成不同， 由此使包含各种单体的混合物旋转，并且在实现单体的分布之后，聚合是通过混合物的旋转，或单体和含热塑性聚合物的混合物进行的，由此所述单体不同于其中单体 所述聚合物已被制备，旋转，并且在实现所述单体和聚合物的分布之后，存在于所述混合物中的单体随后以旋转聚合，其中两种情况都以直径依赖的旋转速度进行旋转 通过以下通用方程式：rpm> 10,000d-0.5其中：rpm =旋转速度，每分钟转数d =直径 的预制件（cm）。 本发明还涉及由如此制备的聚合物预制件形成的光学透镜和纤维。
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公开(公告)号：US20120234079A1
公开(公告)日：2012-09-20
申请号：US13419489
申请日：2012-03-14
CPC分类号： G01N27/414 , G01N27/227
摘要： Disclosed is a sensor for detecting a component (20) of an atmosphere, the sensor comprising a sensing surface (14, 16) covered by a barrier layer (18) of a material switchable between respective layer orientations that have permeability to the component. A NFC device comprising such a sensor, a package incorporating the NFC device and a method of manufacturing the sensor are also disclosed.
摘要翻译： 公开了一种用于检测大气成分（20）的传感器，该传感器包括被阻挡层（18）覆盖的感测表面（14,16），所述阻挡层可以在对该部件具有渗透性的各层取向之间切换。 还公开了一种包括这种传感器的NFC设备，包含NFC设备的封装以及制造传感器的方法。
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公开(公告)号：US20100028816A1
公开(公告)日：2010-02-04
申请号：US12438209
申请日：2007-08-28
IPC分类号： G03F7/00
摘要： The invention relates to a process for the preparation of a polymeric relief structure comprising the steps of coating a substrate with a coating composition comprising one or more radiation-sensitive ingredients, locally treating the coated substrate with electromagnetic radiation having a periodic or random radiation-intensity pattern, forming a latent image, and polymerizing and/or crosslinking the resulting coated substrate, wherein the coating composition comprises one or more radical scavengers in an amount sufficient to inhibit/retard substantial polymerization in the non-treated areas of the coated substrate, and low enough to allow polymerization and/or crosslinking in the treated areas in step c, with the proviso that the amount of oxygen present in the coating composition is not equal to the equilibrium amount of oxygen present when the coating composition is in contact with air.
摘要翻译： 本发明涉及一种制备聚合物浮雕结构的方法，包括以下步骤：用包含一种或多种辐射敏感成分的涂料组合物涂覆基材，用具有周期性或随机辐射强度的电磁辐射局部处理涂覆的基材 形成潜像，并且聚合和/或交联所得涂覆的基底，其中涂层组合物包含足以抑制/延迟涂覆的基底的未处理区域中的基本聚合的量的一种或多种自由基清除剂，以及 足够低以允许在步骤c中处理的区域中的聚合和/或交联，条件是涂料组合物中存在的氧的量不等于当涂料组合物与空气接触时存在的氧的平衡量。
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公开(公告)号：US20090233181A1
公开(公告)日：2009-09-17
申请号：US11721059
申请日：2005-12-09
申请人： Christianus Martinus Van Heesch , Carlos Sanchez , Michael James Escuti , Cornelis Wilhelmus Maria Bastiaansen , Dirk Jan Broer
发明人： Christianus Martinus Van Heesch , Carlos Sanchez , Michael James Escuti , Cornelis Wilhelmus Maria Bastiaansen , Dirk Jan Broer
IPC分类号： G03F7/00
摘要： The present invention relates to a method for the manufacture of a holographic film. The method includes a polymerizable composition that comprises monomers with high reactivity, monomers with low reactivity and a non-reactive material. The method comprises a patterned exposure to obtain a patterned polymerization of the monomers with high reactivity and a subsequent polymerization to polymerize also monomers with low reactivity to form a solid film. The method gives a holographic film with a high refractive index modulation and a modulated porosity.
摘要翻译： 本发明涉及一种制造全息膜的方法。 该方法包括可聚合组合物，其包含具有高反应性的单体，具有低反应性的单体和非反应性材料。 该方法包括图案曝光以获得具有高反应性的单体的图案聚合，并且随后聚合以聚合具有低反应性的单体以形成固体膜。 该方法给出了具有高折射率调制和调制孔隙率的全息膜。
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公开(公告)号：US08927856B2
公开(公告)日：2015-01-06
申请号：US12991135
申请日：2009-05-18
CPC分类号： C09K19/588 , C09K19/60 , C09K19/606 , F24S50/80 , G02F1/13762 , G02F2001/13324 , G02F2203/023 , H01L31/055 , Y02E10/40 , Y02E10/50 , Y02E10/52
摘要： An optical device (1) is provided. The optical device comprising a switchable layer (2) at least one alignment layer (6) a light guiding system (5), whereas the switchable layer (2) comprises a luminescent material (3) for absorbing and emitting light, whereby the alignment of the luminescent material (3) is changeable and the light guiding system (5) guides the emitted light, whereby the switchable layer (2) is in contact with the at least one alignment layer (6) and the luminescent material (3) exhibits anisotropic properties, whereby the optical device (1) comprises a light energy-converting means (7), wherein the light guiding system (5) is in physical contact with the energy converting means (7).
摘要翻译： 提供了一种光学装置（1）。 光学装置包括可切换层（2）至少一个对准层（6），光导系统（5），而可切换层（2）包括用于吸收和发射光的发光材料（3），由此 发光材料（3）是可变的并且导光系统（5）引导发射的光，由此可切换层（2）与至少一个取向层（6）接触，发光材料（3）呈现各向异性 属性，由此光学装置（1）包括光能转换装置（7），其中光导系统（5）与能量转换装置（7）物理接触。
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公开(公告)号：US20110104445A1
公开(公告)日：2011-05-05
申请号：US12936896
申请日：2009-04-07
申请人： Ko Hermans , Itsuro Tomatsu , Rintje Pieter Sijbesma , Cornelis Wilhelmus Maria Bastiaansen , Jan Dirk Broer
发明人： Ko Hermans , Itsuro Tomatsu , Rintje Pieter Sijbesma , Cornelis Wilhelmus Maria Bastiaansen , Jan Dirk Broer
摘要： The invention relates to a photo-embossing process for the preparation of a polymeric relief structure comprising the steps of: a) coating a substrate with a coating composition comprising one or more radiation-sensitive ingredients and less than 30 wt % polymeric binder material; b) locally treating the coated substrate with electromagnetic radiation having a periodic, non-periodic or random radiation-intensity pattern, forming a latent image, at a temperature below a transition temperature of the coating composition; and c) polymerizing and/or crosslinking the resulting coated substrate, at a temperature above said transition temperature, wherein the transition temperature is a temperature that defines a transition of the coating composition between a state of high viscosity and low viscosity and wherein the coating composition comprises a compound A comprising at least one radiation curable group and a photoinitiator, the coating composition having a transition temperature between 30° C. and 120° C.
摘要翻译： 本发明涉及一种用于制备聚合物浮雕结构的光压印方法，包括以下步骤：a）用包含一种或多种辐射敏感成分和小于30wt％聚合物粘合剂材料的涂料组合物涂覆基材; b）在低于涂层组合物的转变温度的温度下，用具有周期性，非周期性或随机辐射强度图案的电磁辐射局部处理涂覆的基底，形成潜像; 和c）在高于所述转变温度的温度下聚合和/或交联所得涂覆的基材，其中所述转变温度是限定所述涂料组合物在高粘度和低粘度状态之间的转变的温度，并且其中所述涂料组合物 包含包含至少一种可辐射固化基团和光引发剂的化合物A，该涂料组合物的转变温度在30℃至120℃之间。
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10.发明申请WATER-RESPONSIVE MECHANICAL ELEMENT AND A METHOD FOR MANUFACTURING SUCH AN ELEMENT 审中-公开水力机械元件和制造这些元件的方法公开(公告)号：US20090233043A1
公开(公告)日：2009-09-17
申请号：US11721056
申请日：2005-12-08
CPC分类号： C09K19/2007 , C09K19/3852 , C09K2019/0448 , Y10T428/24058
摘要： This invention relates to flexible structures (401) that respond to the application of an agent. Upon application of the agent, the flexible structure bends (402) in a predetermined fashion. The flexible structure is formed from a polymer liquid crystal that is orientated to define an upper surface layer and a lower surface layer having an essentially different molecule orientation, and the polymer liquid crystal is such that a length/width ration is changed upon application of the agent. Thereby, the upper and lower surface layers respond differently to the application of the agent, resulting in bending or un-bending of the flexible structure (401).
摘要翻译： 本发明涉及响应于代理商的应用的灵活结构（401）。 在应用该试剂时，柔性结构以预定的方式弯曲（402）。 柔性结构由定向为限定上表面层和具有基本不同分子取向的下表面层的聚合物液晶形成，并且聚合物液晶使得长度/宽度比例在施加时 代理商 因此，上表面层和下表面层对于涂料的应用不同，导致柔性结构（401）的弯曲或不弯曲。
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