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公开(公告)号：US5364554A
公开(公告)日：1994-11-15
申请号：US954438
申请日：1992-09-30
CPC分类号： C11D3/391 , C11D3/2093 , C11D3/386 , C11D3/38627 , C11D3/39
摘要： A perhydrolysis system or activated oxidant system for in situ generation of peracid in aqueous solutions is disclosed including a protease enzyme, a source of hydrogen peroxide and an ester substrate having the general structure ##STR1## where R and R' are alkyl groups unsubstituted or substituted with at least one functional group. Preferred substrates are defined which are preferably chemically non-perhydrolyzable. Processes for bleaching and peracid production are also disclosed.
摘要翻译： 公开了一种用于在水溶液中原位产生过酸的过水解系统或活化氧化剂体系，其包括蛋白酶，过氧化氢源和具有通用结构“IMAGE”的酯底物，其中R和R'为未取代或取代的烷基 与至少一个官能团。 定义优选的基材是优选化学上不可水解的。 还公开了漂白和过酸生产的方法。
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公开(公告)号：US5030240A
公开(公告)日：1991-07-09
申请号：US932717
申请日：1986-11-19
申请人： Richard J. Wiersema , Anna G. Stanislowski , Gregory L. Gray , Ayrookaram J. Poulose , Scott D. Power
发明人： Richard J. Wiersema , Anna G. Stanislowski , Gregory L. Gray , Ayrookaram J. Poulose , Scott D. Power
IPC分类号： C12P7/00 , C11D3/20 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/60 , C11D7/42 , C11D7/54 , C12N9/20 , C12N15/00 , C12P7/40 , C12P7/62 , C12R1/40 , D06L4/40
CPC分类号： D06L3/11 , C11D3/2093 , C11D3/38627 , C11D3/39 , C11D3/391 , C11D3/3945 , C12N9/20
摘要： An enzymatic perhydrolysis system, useful for bleaching, has a novel enzyme, a substrate, and a source of hydrogen peroxide, and provides in situ formation of peracid in aqueous solution. The substrate is selected for enzyme catalyzed reaction, and preferably is an acylglycerol with two or three fatty acid chains. The enzyme is hydrolytically and perhydrolytically active even in the presence of anionic surfactants, has lipase activity, and is isolatable from Pseudomonas putida ATCC 53552.
摘要翻译： 可用于漂白的酶促过水解系统具有新型酶，底物和过氧化氢源，并且在水溶液中原位形成过酸。 选择底物用于酶催化反应，并且优选是具有两个或三个脂肪酸链的酰基甘油。 该酶即使在阴离子表面活性剂存在下也具有水解和全水解活性，具有脂肪酶活性，并且可从恶臭假单胞菌ATCC 53552中分离。
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3.发明授权Cooperative enzymes comprising alkaline or mixtures of alkaline and neutral proteases without stabilizers 失效包含碱性的合成酶或不含稳定剂的碱性和中性蛋白酶的混合物
公开(公告)号：US4511490A
公开(公告)日：1985-04-16
申请号：US508449
申请日：1983-06-27
摘要： A stable, cooperative enzyme system which is stable under use conditions is disclosed which comprises at least two enzymes having activity towards a relatively complex substrate with at least partial activity over the same pH range, wherein their combined activities are greater than the sum of their individual activities as determined by the formula: ##EQU1## wherein E.sub.1 and E.sub.2 are said enzymes. No additional chemical stabilizers, modifiers or activators are added to the enzymes of this invention.Particularly preferred enzymes in this invention are proteases having optimal activity in acidic, neutral or alkaline media, and mixtures of the same.A method of making this cooperative enzyme system is also disclosed.The enzyme systems of this invention have a wide variety of uses in cleaning and other applications.
摘要翻译： 公开了一种在使用条件下稳定的稳定的合作酶系统，其包含至少两种酶，其对相对复杂的底物具有活性，在相同的pH范围内具有至少部分活性，其中它们的组合活性大于其个体的总和 由下式确定的活性：其中E1和E2是所述酶。 本发明的酶不添加额外的化学稳定剂，改性剂或活化剂。 本发明中特别优选的酶是在酸性，中性或碱性介质中具有最佳活性的蛋白酶及其混合物。 还公开了制备该合作酶系统的方法。 本发明的酶系统在清洁和其它应用中具有广泛的用途。
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公开(公告)号：US5296161A
公开(公告)日：1994-03-22
申请号：US964565
申请日：1992-10-21
CPC分类号： C11D3/2093 , C11D3/38627 , C11D3/39 , C11D3/391
摘要： A perhydrolysis system or activated oxidant system for in situ generation of peracid in aqueous solutions is disclosed including an esterase or lipase enzyme, a source of hydrogen peroxide, and a functionalized ester substrate having the structure ##STR1## wherein R is a substituent having at least one carbon atom and X is a functional moiety or group. Preferred substrates include glycerides, ethylene glycol derivatives and propylene glycol derivatives. The system is adapted for use in both high and low temperature wash conditions. In one embodiment, a lipase enzyme is employed with an insoluble substrate and an emulsifying agent. In another embodiment, an esterase and/or lipase enzyme, a glyceride substrate and hydrogen peroxide produce a peracid with active oxygen from a peracid of at least about 0.5 ppm. Bleaching processes and stain removal capabilities are also disclosed.
摘要翻译： 公开了用于在水溶液中原位产生过酸的过水解系统或活化氧化剂体系，其包括酯酶或脂肪酶，过氧化氢源和具有结构（*化学结构*）的官能化酯底物，其中R是取代基 具有至少一个碳原子，X是官能部分或基团。 优选的底物包括甘油酯，乙二醇衍生物和丙二醇衍生物。 该系统适用于高温和低温洗涤条件。 在一个实施方案中，脂肪酶与不溶性底物和乳化剂一起使用。 在另一个实施方案中，酯酶和/或脂肪酶，甘油酯底物和过氧化氢产生具有至少约0.5ppm的过酸的活性氧的过酸。 还公开了漂白工艺和去污能力。
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公开(公告)号：US4708816A
公开(公告)日：1987-11-24
申请号：US825959
申请日：1986-02-04
CPC分类号： B82Y30/00 , C09C1/00 , C09C1/32 , C11D17/0039 , C11D3/3956 , C11D3/40 , C11D3/42 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2004/80 , C01P2006/10 , Y10T428/2989
摘要： Microcapsules having density controlled to be close to that of an aqueous solution are provided which may be dispersed in liquid bleaching solutions and which are useful as coloring or whitening agents.
摘要翻译： 提供具有接近于水溶液密度的微胶囊，其可以分散在液体漂白溶液中，并且其可用作着色剂或增白剂。
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公开(公告)号：US5545748A
公开(公告)日：1996-08-13
申请号：US325050
申请日：1994-10-18
IPC分类号： C01B15/00 , C07C409/24 , C11D3/39 , C11D7/54 , D06L3/02 , D06L3/06 , C07C409/02 , C01B15/10
CPC分类号： C11D3/3907
摘要： Polyglycolate compounds are provided having the general structure: ##STR1## wherein n is an integer from 2 to about 10; R is C.sub.1-20 linear or branched alkyl, alkoxylated alkyl, cycloalkyl, aryl, alkylaryl, substituted aryl; R' and R" are independently H, C.sub.1-20 alkyl, aryl, C.sub.1-20 alkylaryl, substituted aryl, and NR.sub.3.sup..alpha.+, wherein R.sup..alpha. is C.sub.1-30 alkyl; and L is a leaving group displaceable in a peroxygen bleaching solution by perhydroxide anion. When this compound is combined with a source of peroxgen in aqueous solution, then a plurality of stain removing peracids are formed. Such peracids are formed substantially sequentially beginning with the carbonyl adjacent to the leaving group L. Thus, a first stain removing peracid having the structure ##STR2## will be formed in amounts approaching quantitative yield.
摘要翻译： 提供了具有以下通用结构的聚乙醇酸酯化合物：其中n为2至约10的整数; R为C 1-20直链或支链烷基，烷氧基化烷基，环烷基，芳基，烷基芳基，取代芳基; R'和R“独立地为H，C 1-20烷基，芳基，C 1-20烷基芳基，取代的芳基和NR 3α+，其中Rα为C 1-30烷基; L是在过氧漂白溶液中通过全氢氧化物阴离子置换的离去基团。 当该化合物与水溶液中的过氧化物源组合时，形成多个去污过酸。 这样的过酸基本上是从与离去基团L相邻的羰基开始形成的。因此，具有接近定量收率的量的第一个去除污垢的过酸的结构将被形成。
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公开(公告)号：US5545667A
公开(公告)日：1996-08-13
申请号：US228912
申请日：1994-04-18
IPC分类号： A61K31/205
CPC分类号： A61K31/205
摘要： The present invention provides a new therapeutic use of the zwitterionic surfactants, specifically betaines and sulfobetaines, to treat cellular, neoplastic disorders.
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公开(公告)号：US06265191B1
公开(公告)日：2001-07-24
申请号：US08110341
申请日：1993-08-20
申请人： Eugene A. Mizusawa , Susan A. Anderson , Maha Y. El-Sayed , Daniel R. Leiske , Richard J. Wiersema , Chihae Yang
发明人： Eugene A. Mizusawa , Susan A. Anderson , Maha Y. El-Sayed , Daniel R. Leiske , Richard J. Wiersema , Chihae Yang
IPC分类号： C12N1102
CPC分类号： C11D3/38627 , D06M16/003 , Y10S435/877
摘要： Lipase is immobilized on surfaces to facilitate oil removal from the surfaces and to alter wettability of the surfaces. The lipase is isolatable from a Pseudomonas organism such as Pseudomonas putida ATCC 53552 or from an organism expressing a coding region found in or cloned from the Pseudomonas. A particularly preferred lipase has a molecular weight of about 30 to 35 kd and is resolvable as a single band by SDS gel electrophoresis. Lipase sorbed on fabric forms a fabric-lipase complex for oil stain removal. The lipase may be sorbed on fabric before or after an oil stain, and the lipase is active to hydrolyze an oil stain on dry fabric or fabric in laundering solutions. The sorbed lipase has enhanced stability to denaturation by surfactants and to heat deactivation, is resistant to removal from fabric during laundering, retains substantial activity after drying fabric at an elevated temperature, and retains activity during fabric storage or wear. Redeposition of oil and oil hydrolysis by-products during laundering of fabric is retarded by the lipase. Oil hydrolysis by-products are removable during laundering of fabric at a basic pH or in the presence of a surfactant.
摘要翻译： 将脂肪酶固定在表面上以促进从表面除油并改变表面的润湿性。 所述脂肪酶可从假单胞菌（Pseudomonas）生物体如恶臭假单胞菌ATCC 53552或表达在假单胞菌中发现或克隆的编码区的生物体分离。 特别优选的脂肪酶具有约30至35kd的分子量，并且可通过SDS凝胶电泳作为单一条带分解。 在织物上吸附的脂肪酶形成用于除油的织物 - 脂肪酶复合物。 脂肪酶可以在油渍之前或之后在织物上吸附，并且脂肪酶在洗涤溶液中活性水解干织物或织物上的油渍。 吸附的脂肪酶具有增强的表面活性剂变性和热失活的稳定性，在洗涤期间耐织物除去后，在高温下干燥织物后保留显着的活性，并且在织物储存或磨损期间保持活性。 在织物洗涤过程中油和水解副产物的重新沉积被脂肪酶阻滞。 在碱性pH下或在表面活性剂存在下，织物洗涤期间油水解副产物是可除去的。
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公开(公告)号：US6136857A
公开(公告)日：2000-10-24
申请号：US610908
申请日：1996-03-05
IPC分类号： A61K31/205
CPC分类号： A61K31/205
摘要： The present invention provides a new therapeutic use of the zwitterionic surfactants, specifically betaines and sulfobetaines, to treat cellular, neoplastic disorders.
摘要翻译： 本发明提供了两性离子表面活性剂，特别是甜菜碱和磺基甜菜碱治疗细胞，肿瘤性疾病的新的治疗用途。
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公开(公告)号：US5391812A
公开(公告)日：1995-02-21
申请号：US951238
申请日：1992-09-25
CPC分类号： C11D3/3907
摘要： Polyglycolate compounds are provided having the general structure: ##STR1## wherein n is an integer from 2 to about 10; R is C.sub.1-20 linear or branched alkyl, alkoxylated alkyl, cycloalkyl, aryl, alkylaryl, substituted aryl; R' and R" are independently H, C.sub.1-20 alkyl, aryl, C.sub.1-20 alkylaryl, substituted aryl, and NR.sub.3.sup..alpha.+, wherein R.sup..alpha. is C.sub.1-30 alkyl; and L is a leaving group displaceable in a peroxygen bleaching solution by perhydroxide anion. When this compound is combined with a source of peroxygen in aqueous solution, then a plurality of stain removing peracids are formed. Such peracids are formed substantially sequentially beginning with the carbonyl adjacent to the leaving group L. Thus, a first stain removing peracid having the structure ##STR2## will be formed in amounts approaching quantitative yield.
摘要翻译： 提供了具有以下通用结构的聚乙醇酸酯化合物：其中n为2至约10的整数; R为C 1-20直链或支链烷基，烷氧基化烷基，环烷基，芳基，烷基芳基，取代芳基; R'和R“独立地为H，C 1-20烷基，芳基，C 1-20烷基芳基，取代的芳基和NR 3α+，其中Rα为C 1-30烷基; L是在过氧漂白溶液中通过全氢氧化物阴离子置换的离去基团。 当该化合物与水溶液中的过氧源组合时，形成多个去污过酸。 这样的过酸基本上是从与离去基团L相邻的羰基开始形成的。因此，具有接近定量收率的量的第一种去除污垢的过酸的结构将形成。
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