摘要:
The invention relates to a process for producing paper, board and cardboard of high dry strength by separately adding a polymer comprising vinylamine units and a polymeric anionic compound to a paper pulp, dewatering the pulp and drying the paper products, which comprises using as polymeric anionic compound at least one copolymer obtainable by copolymerizing (a) at least one N-vinylcarboxamide of the formula in which R1 and R2 are H or C1- to C6 alkyl, (b) at least one monoethylenically unsaturated monomer comprising acid groups, and/or the alkali metal, alkaline earth metal or ammonium salts thereof, and if appropriate (c) other monoethylenically unsaturated monomers, and if appropriate (d) compounds having at least two ethylenically unsaturated double bonds in their molecule.
摘要:
The invention relates to a process for producing paper, board and cardboard of high dry strength by separately adding a polymer comprising vinylamine units and a polymeric anionic compound to a paper pulp, dewatering the pulp and drying the paper products, which comprises using as polymeric anionic compound at least one copolymer obtainable by copolymerizing (a) at least one N-vinylcarboxamide of the formula in which R1 and R2 are H or C1- to C6 alkyl, (b) at least one monoethylenically unsaturated monomer comprising acid groups, and/or the alkali metal, alkaline earth metal or ammonium salts thereof, and if appropriate (c) other monoethylenically unsaturated monomers, and if appropriate (d) compounds having at least two ethylenically unsaturated double bonds in their molecule.
摘要:
A starch modified with at least one cationic polymer is prepared by a process in which dry, free-flowing starch is initially taken and the cationic polymer is applied thereon without the starch particles sticking together, and the polymer-modified starch is used.
摘要:
Polymers containing .beta.-hydroxyalkylvinylamine units, which are obtainable by reacting polymers containing vinylamine units with epoxides of the formula ##STR1## where R=C.sub.2 -C.sub.28 -alkyl, phenyl, C.sub.1 -C.sub.18 -alkylphenyl or C.sub.2 -C.sub.18 -alkenyl, are described, as are a process for preparing the polymers and use of the polymers as retention and drainage aids and flocculants and as fixatives in paper making, as protective colloid for producing alkyldiketene dispersions or alkenylsuccinic anhydride dispersions, as emulsifier for producing aqueous filler suspensions and as corrosion inhibitor.
摘要:
Partially hydrolyzed polymers of N-vinylcarboxamides obtainable by sole polymerization of N-vinylcarboxamides of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 - to C.sub.6 -alkyl, and elimination from the polymers of from 0.5 to 95 mol % of the groups of the formula ##STR2## where R.sup.1 is hydrogen or C.sub.1 - to C.sub.6 -alkyl, can be used as paper, paperboard and cardboard dry strength enhancers.
摘要:
A monomer composition is described, containing A) vinyl-containing monomers in which the vinyl bears a hetero-atom selected from the group consisting of the halogens, nitrogen, oxygen, sulfur or silicon, andB) at least one N-oxyl compound of a secondary amine which does not bear hydrogen on the .alpha.-carbons, in an amount effective as stabilizer against premature polymerization.
摘要:
A monomer composition, which contains A) vinyl-containing monomers in which a heteroatom selected from the group consisting of the halogens, nitrogen, oxygen, sulfur and silicon is present on the vinyl group, and B) a compound or a mixture of compounds of the formula II where R4 is methyl, ethyl, isopropyl, n-propyl, n-butyl, isobutyl, sec-butyl, tert-butyl or trimethylsilyl.
摘要:
Finely divided, water-soluble polymers are prepared by polymerization of water-soluble, monoethylenically unsaturated monomers in not less than 20% strength by weight aqueous solution in the presence of a polymerization initiator in a kneader by a process in which from 0.1 to 10% by weight, based on the total monomers, of a surfactant are used in the polymerization, the polymerization initially being carried out to a conversion of the monomers of not less than 60% in the absence of the surfactant or in the presence of not more than 50% of the amount of surfactant, and the remaining amount of surfactant then being added to the reaction mixture and the polymerization completed. The addition of surfactant causes the polymer gel to disintegrate with formation of fine particles.
摘要:
Polymers in bead form are prepared from water-soluble ethylenically unsaturated monomers by a reverse suspension polymerization of a liquid in the presence of polymerization initiators and protective colloids obtainable by grafting polymers (A) containing (a) aromatic monovinyl monome from 40 to 100% by weight (b) C.sub.3-6 monoethylenically unsaturated carboxylic acid and/or maleic anhydride from 0 to 60% by weight (c) other monoethylenically unsaturated monomers from 0-20% by weight, as copolymerized units with the proviso that the sum of the weight (a) to (c) is always 100 and the polymer (A) has a molecular weight (number average) from 500 to 20,000 and a hydrogenation iodine number from 1.3 to 51 with a fixed monomer mixture at given concentration levels.
摘要:
Starch is modified with at least one cationic polymer P) and the modified starch is prepared by a process in which a) an anionically modified starch A) is reacted with a cationic polymer P) or b) a natural starch B) or a starch C) which has not been anionically modified is reacted with the cationic polymer P) in the presence of an anionic modifier M) and the polymer-modified starch is used.