公开(公告)号：US12281055B2

公开(公告)日：2025-04-22

申请号：US17841150

申请日：2022-06-15

Applicant: Arizona Board of Regents on behalf of Arizona State University

Inventor： Matthew Green ,  Sefaattin Tongay ,  Meng Wang ,  Ying Qin

IPC: C07C209/32 ,  C08F4/60 ,  C07C211/58

Abstract: Octaaminonaphthalene and a method of synthesizing octaaminonaphthalene are described. A two-dimensional coordination polymer and a method of synthesizing the two-dimensional coordination polymer are described. The two-dimensional coordination polymer includes ligands including anchorage sites, and metal linkers, each metal linker including a metal and an organic moiety. Each metal linker is coupled to two ligands via the anchorage sites. Synthesizing the two-dimensional coordination polymer includes contacting a first liquid precursor with a second liquid precursor at an interface, reacting the metal linker and the water-soluble ligand to yield a two-dimensional coordination polymer at the interface, and removing the two-dimensional coordination polymer from the interface.

公开(公告)号：US20240115989A1

公开(公告)日：2024-04-11

申请号：US18263691

申请日：2022-02-01

Applicant: ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY

Inventor： Matthew Green ,  Klaus Lackner

IPC: B01D53/22

CPC classification number: B01D53/228 ,  B01D2053/221 ,  B01D2257/504 ,  B01D2311/26 ,  B01D2313/28 ,  B01D2315/10 ,  B01D2325/42

Abstract: A continuous CO2 capture system, method, and device are disclosed. The device includes a CO2 pump membrane including a moisture-swing material, and a cavity having a first fluid. The CO2 pump membrane separates the first fluid from a second fluid, the fluids creating a water concentration gradient across the membrane and transport of water through the membrane. The water concentration gradient creates a carbon concentration gradient across the membrane that decreases moving from outside the cavity to inside the cavity. As water is continuously transported from the first fluid to the second fluid through the CO2 pump membrane because of the water concentration gradient, carbon dioxide is continuously captured from the second fluid by the moisture-swing material of the CO2 pump membrane and continuously pumped along the carbon concentration gradient across the CO2 pump membrane and into the first fluid within the cavity.

公开(公告)号：US11920002B2

公开(公告)日：2024-03-05

申请号：US17985288

申请日：2022-11-11

Applicant: Arizona Board of Regents on behalf of Arizona State University

Inventor： Matthew Green ,  Yi Yang

IPC: C08G75/23 ,  B01D71/68 ,  C02F1/44 ,  C02F103/08 ,  C08G65/40 ,  C08L81/06

CPC classification number: C08G75/23 ,  B01D71/68 ,  C02F1/44 ,  C08L81/06 ,  C02F2103/08 ,  C08G65/4056

Abstract: A zwitterionic polysulfone formed from an allyl-containing monomer, a phenol-containing monomer, and an aryl-halide-containing monomer. The zwitterionic polysulfone may be incorporated into a desalination membrane.

公开(公告)号：US20240003058A1

公开(公告)日：2024-01-04

申请号：US18039322

申请日：2022-01-20

Applicant: Arizona Board of Regents on behalf of Arizona State University

Inventor： Matthew Green ,  Mani Modayil Korah

IPC: D01D5/00 ,  B01J13/04 ,  B01J13/12 ,  D01D1/02 ,  D01D5/24

CPC classification number: D01D5/0038 ,  B01J13/043 ,  B01J13/125 ,  D01D1/02 ,  D01D5/24

Abstract: Systems and methods for preparing encapsulant-containing polymer capsules and fibers, as well as the encapsulant-containing polymer capsules and fibers and composites including the same are described. In one example, forming a plurality of encapsulant-containing polymer capsules includes preparing a mixture comprising a polymer, a solvent, an encapsulant, and a polymer that is soluble in the solvent, and removing some of the solvent from the mixture to yield the plurality of polymer capsules. Each polymer capsule include a shell formed of the polymer and contains the encapsulant. In another example, forming a plurality of polymer fibers containing an encapsulant includes providing the mixture to an electrospin apparatus and electrospinning the mixture to yield the plurality polymer fibers, where each polymer fiber defines a hollow core that contains the encapsulant.

公开(公告)号：US20230038851A1

公开(公告)日：2023-02-09

申请号：US17793925

申请日：2021-02-01

Applicant: ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY

Inventor： Matthew Green ,  Hoda Shokrollahzadeh Behbahani ,  Yi Yang

IPC: B01J20/26 ,  C08G75/23 ,  B01J20/28 ,  B01J20/30 ,  B01D53/62 ,  B01D53/81

Abstract: A quaternary ammonium-functionalized poly(arylene ether sulfone) copolymer for moisture-swing CO2 capture, and a method for producing the same, is disclosed. The copolymer includes a polysulfone copolymer having a copolymerization unit based on diallyl bisphenal A (DABA) and has quaternary ammonium functionalities. The method for preparation of a quaternary ammonium-functionalized poly(arylene ether sulfone) copolymer includes reacting diallyl bisphenol A (DABA) with bisphenol A (BPA) and 4,4'-difluorodiphenyl sulfone (DFDPS) to form an allyl-modified poly(arylene ether sulfone) (PAES-co-APAES) copolymer, then modifying the PAES-co-APAES copolymer to convert the allyl functionalities to tertiary amines, forming tertiary amine-modified PAES (PAES-co-TAPAES) copolymer. The method also includes converting the tertiary amine of the PAES-co-TAPAES copolymer to quaternary ammonium, forming quaternary ammonium-modified PAES. These quaternary ammonium-modified PAES may be processed into membranes, films, and hollow fibers.

公开(公告)号：US11524316B2

公开(公告)日：2022-12-13

申请号：US16778713

申请日：2020-01-31

Applicant: Arizona Board of Regents on behalf of Arizona State University

Inventor： Meng Wang ,  Yuxia Shen ,  Sefaattin Tongay ,  Matthew Green ,  Ying Qin ,  Sijie Yang

IPC: B05D1/18 ,  C08J7/06 ,  B05D1/38

Abstract: Forming a two-dimensional polymeric sheet includes translating a portion of a flexible substrate through a first liquid precursor to coat the portion of the flexible substrate with the first liquid precursor, thereby yielding a precursor-coated portion of the flexible substrate. The precursor-coated portion of the flexible substrate is translated through an interface between the first liquid precursor and a second liquid precursor, thereby reacting the first liquid precursor on the precursor-coated portion of the flexible substrate with the second liquid precursor to yield a polymer-coated portion of the flexible substrate.

公开(公告)号：US20240001333A1

公开(公告)日：2024-01-04

申请号：US18039338

申请日：2022-02-08

Applicant: Arizona Board of Regents on behalf of Arizona State University

Inventor： Matthew Green ,  Klaus Lackner ,  Jae Sang Lee ,  Meng Wang ,  Mani Modayil Korah ,  Husain Mithaiwala ,  Allen Wright

IPC: B01J20/20 ,  B01D53/62 ,  B01J20/04 ,  B01J20/26 ,  B01J20/28 ,  B01D53/96 ,  B01J20/30

CPC classification number: B01J20/20 ,  B01D53/62 ,  B01J20/043 ,  B01J20/267 ,  B01J20/28028 ,  B01J20/28038 ,  B01D53/96 ,  B01J20/3078 ,  B01J20/3007 ,  B01D2257/504 ,  B01D2258/06 ,  B01D2253/102 ,  B01D2253/202 ,  B01D2253/25 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2251/606

Abstract: A polymer composite includes a polymer substrate, activated carbon, and a carbonate salt. The activated carbon is infused with the carbonate salt. A hybrid composite includes a fibrous mat with activated carbon and potassium carbonate crystals adhered to the fibrous mat. Making a polymer composite includes combining activated carbon with a polymer to yield a mixture, and electrospinning the mixture to yield nanofibers, wherein the carbonate salt is adhered to or embedded in the nanofibers. Capturing carbon dioxide from a quantity of air includes contacting the polymer composite with the quantity of air in the presence of water vapor to yield potassium bicarbonate sorbed on the polymer composite.