SYNTHETIC PHYLLOSILICATES NOT CAPABLE OF SWELLING FOR POLYMER PHYLLOSILICATE (NANO)COMPOSITES
    1.
    发明申请
    SYNTHETIC PHYLLOSILICATES NOT CAPABLE OF SWELLING FOR POLYMER PHYLLOSILICATE (NANO)COMPOSITES 审中-公开
    合成不溶于聚合物硅藻土(NANO)复合材料的合成硅酸盐

    公开(公告)号:US20110204286A1

    公开(公告)日:2011-08-25

    申请号:US13120871

    申请日:2009-09-10

    IPC分类号: C08K3/34 C09K3/00

    CPC分类号: C01B33/44

    摘要: The present invention relates to a process for the production of non-swellable phyllosilicate tactoids, comprising A) producing a synthetic smectite of the formula I in a high-temperature-melt synthesis [Mn/Valenz]inter[MImMIIo]oct [MIII4]tet X10Y2  (I) B) if the interlayer cation M does not already have a hydration enthalpy from −6282 to −406 [kJ/mol], exchanging the interlayer cation M with a cation having a hydration enthalpy from −6282 to −406 [kJ/mol] by a cation-exchange method, C) dispersing phyllosilicate in an aqueous system, and D) exchanging M with a cation having a hydration enthalpy from −405 to 0 [kJ/mol], by a cation-exchange method.

    摘要翻译: 本发明涉及一种生产非溶胀性页硅酸盐触纹的方法,包括:A)在高温熔融合成[Mn / Valenz] inter [MImMIIo] oct [MIII4] tet中制备式I的合成蒙脱石 X10Y2(I)B)如果层间阳离子M尚未具有-6282至-406 [kJ / mol]的水合焓,则将层间阳离子M与水合焓的阳离子交换为-6282至-406 [kJ / mol],C)将页硅酸盐分散在水性体系中,以及D)通过阳离子交换法将M与水合焓的阳离子交换为-405〜0 [kJ / mol]。