Electrochemical power generation
    1.
    发明授权
    Electrochemical power generation 失效
    电化学发电

    公开(公告)号:US4652503A

    公开(公告)日:1987-03-24

    申请号:US835799

    申请日:1986-03-03

    CPC分类号: H01M6/26 H01M6/5077

    摘要: A power generation system utilizing an electrochemical cell comprising a reactive metal anode, a cathode spaced from the anode and an electrolyte comprising an aqueous solution of the hydroxide of the reactive metal is disclosed. The hydroxide concentration in the electrolyte is controlled by contacting the electrolyte with an acid anhydride to form an insoluble compound of the reactive metal. The insoluble compound is separated from the electrolyte and the electrolyte is recirculated to the electrochemical cell.

    摘要翻译: 公开了一种使用电化学电池的发电系统,该电化学电池包括反应性金属阳极,与阳极间隔开的阴极和包含反应性金属氢氧化物的水溶液的电解质。 电解质中的氢氧化物浓度通过使电解质与酸酐接触而形成不溶性的反应性金属化合物来控制。 将不溶性化合物与电解质分离,并将电解质再循环至电化学电池。

    Hydrogel loaded active layer in pressure tolerant gas diffusion
electrodes
    3.
    发明授权
    Hydrogel loaded active layer in pressure tolerant gas diffusion electrodes 失效
    水凝胶负载活性层在耐压气体扩散电极中

    公开(公告)号:US5092976A

    公开(公告)日:1992-03-03

    申请号:US435505

    申请日:1989-10-12

    摘要: Gas diffusion electrodes and gas generating or consuming electrochemical cells utilizing the same are disclosed. The electrode comprises an electronically conductive and electrochemically active porous body defining respective gas and electrolyte contacting surfaces, with a substantially gas impermeable material filling at least a portion of the pore volume of the body so as to prevent gas passage therethrough. The material comprises an electrolyte-insoluble, ionomeric ionically conductive hydrophilic hydrogel formed by coprecipitation between at least two precursor polymers.

    摘要翻译: PCT No.PCT / US88 / 00624 Sec。 371日期:1989年10月12日 102(e)日期1989年10月12日PCT PCT 3月2日PCT公布。 出版物WO88 / 06645 日期:1988年9月7日。公开了扩散电极和利用其的产生或消耗电化学电池的气体。 电极包括限定相应气体和电解质接触表面的电子导电和电化学活性多孔体,具有填充主体的孔体积的至少一部分的基本不透气材料,以防止气体通过。 该材料包括通过至少两种前体聚合物之间的共沉淀形成的电解质不溶性离聚物离子导电亲水性水凝胶。

    Solid state electrochemical pollution control device
    4.
    发明授权
    Solid state electrochemical pollution control device 失效
    固态电化学污染控制装置

    公开(公告)号:US5022975A

    公开(公告)日:1991-06-11

    申请号:US378831

    申请日:1989-07-12

    申请人: Arnold Z. Gordon

    发明人: Arnold Z. Gordon

    摘要: A solid state electrochemical cell adapted to alter the composition of gas streams passing therethrough comprising: a porous, high surface area electrolyte forming the body of the cell, said electrolyte having darkened electrocatalytic surfaces; a gas communicating passageway through the cell length; a first electronically conductive region and a second electrolytically conductive region, said regions disposed in opposing segments of the cell; a first electrode located in said first conductive region and a second opposing electrode located within said second conductive region, said solid electrolyte having a transference number of less than 1 and greater than 0.50 in a region between the electrodes.

    摘要翻译: 一种适于改变通过其中的气流的组成的固态电化学电池,包括:形成电池主体的多孔高表面积电解质,所述电解质具有变暗的电催化表面; 通过细胞长度的气体连通通道; 第一电子导电区域和第二电解导电区域,所述区域设置在电池的相对段中; 位于所述第一导电区域中的第一电极和位于所述第二导电区域内的第二相对电极,所述固体电解质在电极之间的区域中具有小于1且大于0.50的转移数。

    Electrochemical cell aqueous electrolyte and method
    5.
    发明授权
    Electrochemical cell aqueous electrolyte and method 失效
    电化学电池水电解液及方法

    公开(公告)号:US4816352A

    公开(公告)日:1989-03-28

    申请号:US622785

    申请日:1984-06-21

    申请人: Arnold Z. Gordon

    发明人: Arnold Z. Gordon

    IPC分类号: H01M6/04 H01M6/26 H01M12/06

    CPC分类号: H01M6/26 H01M12/06 H01M6/04

    摘要: An electrochemical cell and a method of controllably generating electricity with the cell wherein the cell comprises an anode of a metal which is highly reactive with water, a cathode of a nonreactive, electrically conductive material spaced from the anode, and an electrolyte which is an aqueous solution of a negatively charged electrolytic ionic specie and which is saturated with respect to the electrochemical reaction product between the anodic metal and the electrolytic ionic specie.The cell advantageously operates at elevated temperatures, is stable and safe, generates high current densities, provides a readily manageable electrolyte system and is controllable by control of the operating temperature alone.

    摘要翻译: 一种电化学电池和一种可控制地发电的电池,其中电池包括与水高度反应的金属的阳极,与阳极间隔开的非反应性导电材料的阴极,以及电解质是水性 负电荷的电解离子物质的溶液,并且相对于阳极金属和电解离子物质之间的电化学反应产物是饱和的。 电池有利地在高温下运行,稳定和安全,产生高电流密度,提供易于管理的电解质系统,并且可以通过仅控制工作温度来控制。

    Gas diffusion electrodes, electrochemical cells and methods exhibiting
improved voltage performance
    6.
    发明授权
    Gas diffusion electrodes, electrochemical cells and methods exhibiting improved voltage performance 失效
    气体扩散电极,电化学电池和显示出改进的电压性能的方法

    公开(公告)号:US4787964A

    公开(公告)日:1988-11-29

    申请号:US48386

    申请日:1987-05-11

    摘要: Gas diffusion electrodes, gas generating or consuming electrochemical cells utilizing such electrodes, and a method of preparing such electrodes are disclosed. The electrode comprises an electronically conductive porous body defining respective gas and electrolyte contacting surfaces. The electrode is prepared by forming the porous body, disposing the electrolyte contacting surface in contact with an electrolyte, and contacting the gas contacting surface with a gaseous atmosphere. Current is passed through the porous body at a degree of electrode polarization much higher than normal whereby modification of the electrode material is effected. If desired, a catalyst may be incorporated in the electrode and is subjected to pretreatment as well. The inventive electrodes exhibit superior voltage performance under oxygen polarization conditions.

    摘要翻译: 公开了气体扩散电极,利用这种电极的气体产生或消耗电化学电池,以及制备这种电极的方法。 电极包括限定相应气体和电解质接触表面的电子导电多孔体。 通过形成多孔体制备电极,将电解质接触表面与电解质接触,并使气体接触表面与气体气氛接触。 电流以比正常高的电极极化程度通过多孔体,由此实现电极材料的改性。 如果需要,也可以在电极中加入催化剂,并进行预处理。 本发明的电极在氧极化条件下表现出优异的电压性能。

    Electrochemical power generation
    7.
    发明授权
    Electrochemical power generation 失效
    电化学发电

    公开(公告)号:US4663249A

    公开(公告)日:1987-05-05

    申请号:US835770

    申请日:1986-03-03

    申请人: Arnold Z. Gordon

    发明人: Arnold Z. Gordon

    CPC分类号: H01M6/26 H01M6/5077

    摘要: A power generation system utilizing an electrochemical cell comprising a reactive metal anode, a cathode spaced from the anode and an electrolyte comprising an aqueous solution of the hydroxide of the reactive metal is disclosed. The hydroxide concentration in the electrolyte is controlled by contacting the electrolyte with acids or salts thereof having a first anion comprising at least two elements with at least one of the elements being a non-metal. Upon contact with the electrolyte, the anion hydrolyzes to yield at least second or third anions which react with the hydroxide of the reactive metal to yield compounds thereof which are insoluble in the electrolyte. The insoluble compounds are separated from the electrolyte and the electrolyte is recirculated to the electrochemical cell.

    摘要翻译: 公开了一种使用电化学电池的发电系统,该电化学电池包括反应性金属阳极,与阳极间隔开的阴极和包含反应性金属氢氧化物的水溶液的电解质。 通过使电解质与具有至少两个元素的第一阴离子的酸或其盐接触来控制电解质中的氢氧化物浓度,其中至少一种元素是非金属的。 当与电解质接触时,阴离子水解产生至少第二或第三阴离子,其与反应性金属的氢氧化物反应以产生其不溶于电解质的化合物。 不溶性化合物与电解质分离,电解质再循环到电化学电池中。