摘要:
A power generation system utilizing an electrochemical cell comprising a reactive metal anode, a cathode spaced from the anode and an electrolyte comprising an aqueous solution of the hydroxide of the reactive metal is disclosed. The hydroxide concentration in the electrolyte is controlled by contacting the electrolyte with an acid anhydride to form an insoluble compound of the reactive metal. The insoluble compound is separated from the electrolyte and the electrolyte is recirculated to the electrochemical cell.
摘要:
An electrical power generating device having a plurality of ceramic composite cells, each cell having a cathode and an anode. A thermal shell in which the ceramic composite cells are stacked or arranged in electrical series and gas parallel surrounded by shock absorbing and insulating materials, respectively, is preferably included. Also provided are an exhaust fan, thermocouple sensors, a fuel supply, a programmable computer controller with user interface, and a container supporting the assembly and having passageways for providing air ingress and egress to the device, and power output terminals for the electrical power from the device. Methods for manufacturing the ceramic composite cells are also provided, including a method for manufacturing stabilized zirconia for use in the ceramic materials used within the ceramic composite cell. The cell utilizes a ceramic composite body electrolyte which contains a metal member having a regular pattern of openings.
摘要:
Gas diffusion electrodes and gas generating or consuming electrochemical cells utilizing the same are disclosed. The electrode comprises an electronically conductive and electrochemically active porous body defining respective gas and electrolyte contacting surfaces, with a substantially gas impermeable material filling at least a portion of the pore volume of the body so as to prevent gas passage therethrough. The material comprises an electrolyte-insoluble, ionomeric ionically conductive hydrophilic hydrogel formed by coprecipitation between at least two precursor polymers.
摘要:
A solid state electrochemical cell adapted to alter the composition of gas streams passing therethrough comprising: a porous, high surface area electrolyte forming the body of the cell, said electrolyte having darkened electrocatalytic surfaces; a gas communicating passageway through the cell length; a first electronically conductive region and a second electrolytically conductive region, said regions disposed in opposing segments of the cell; a first electrode located in said first conductive region and a second opposing electrode located within said second conductive region, said solid electrolyte having a transference number of less than 1 and greater than 0.50 in a region between the electrodes.
摘要:
An electrochemical cell and a method of controllably generating electricity with the cell wherein the cell comprises an anode of a metal which is highly reactive with water, a cathode of a nonreactive, electrically conductive material spaced from the anode, and an electrolyte which is an aqueous solution of a negatively charged electrolytic ionic specie and which is saturated with respect to the electrochemical reaction product between the anodic metal and the electrolytic ionic specie.The cell advantageously operates at elevated temperatures, is stable and safe, generates high current densities, provides a readily manageable electrolyte system and is controllable by control of the operating temperature alone.
摘要:
Gas diffusion electrodes, gas generating or consuming electrochemical cells utilizing such electrodes, and a method of preparing such electrodes are disclosed. The electrode comprises an electronically conductive porous body defining respective gas and electrolyte contacting surfaces. The electrode is prepared by forming the porous body, disposing the electrolyte contacting surface in contact with an electrolyte, and contacting the gas contacting surface with a gaseous atmosphere. Current is passed through the porous body at a degree of electrode polarization much higher than normal whereby modification of the electrode material is effected. If desired, a catalyst may be incorporated in the electrode and is subjected to pretreatment as well. The inventive electrodes exhibit superior voltage performance under oxygen polarization conditions.
摘要:
A power generation system utilizing an electrochemical cell comprising a reactive metal anode, a cathode spaced from the anode and an electrolyte comprising an aqueous solution of the hydroxide of the reactive metal is disclosed. The hydroxide concentration in the electrolyte is controlled by contacting the electrolyte with acids or salts thereof having a first anion comprising at least two elements with at least one of the elements being a non-metal. Upon contact with the electrolyte, the anion hydrolyzes to yield at least second or third anions which react with the hydroxide of the reactive metal to yield compounds thereof which are insoluble in the electrolyte. The insoluble compounds are separated from the electrolyte and the electrolyte is recirculated to the electrochemical cell.
摘要:
An edge seal for a lithium or other consumable metal anode comprises a hydrophobic, chemically inert polymer coating having a high ratio of flexural modulus to flexural strength, a low Izod impact value, and low elongation properties.
摘要:
An electrical power generating device having a plurality of ceramic composite cells, each cell having a cathode and an anode. A thermal shell in which the ceramic composite cells are stacked or arranged in electrical series and gas parallel surrounded by shock absorbing and insulating materials, respectively, is preferably included. Also provided are an exhaust fan, thermocouple sensors, a fuel supply, a programmable computer controller with user interface, and a container supporting the assembly and having passageways for providing air ingress and egress to the device, and power output terminals for the electrical power from the device.Methods for manufacturing the ceramic composite cells are also provided, including a method for manufacturing stabilized zirconia and for use in the ceramic materials used within the ceramic composite cell.
摘要:
An electrical power generating device having a plurality of ceramic composite cells, each cell having a cathode and an anode. A thermal shell in which the ceramic composite cells are stacked or arranged in electrical series and gas parallel surrounded by shock absorbing and insulating materials, respectively, is preferably included. Also provided are an exhaust fan, thermocouple sensors, a fuel supply, a programmable computer controller with user interface, and a container supporting the assembly and having passageways for providing air ingress and egress to the device, and power output terminals for the electrical power from the device.Methods for manufacturing the ceramic composite cells are also provided, including a method for manufacturing stabilized zirconia and for use in the ceramic materials used within the ceramic composite cell.