公开(公告)号：US20160297943A1

公开(公告)日：2016-10-13

申请号：US15028259

申请日：2014-10-09

Applicant: BASF SE

Inventor： Christian DÄSCHLEIN ,  Peter GUTMANN ,  Jürgen AHLERS

IPC: C08J9/18 ,  B29C44/34 ,  B29C44/08 ,  C08J9/12

CPC classification number: C08J9/18 ,  B29C44/08 ,  B29C44/3415 ,  B29C44/3453 ,  B29C44/3461 ,  B29K2009/06 ,  B29K2019/00 ,  B29K2067/00 ,  B29K2075/00 ,  B29K2077/00 ,  B29K2096/04 ,  B29K2105/0005 ,  B29K2105/048 ,  B29K2105/251 ,  B29K2995/0037 ,  B29K2995/0039 ,  B29K2995/004 ,  B29K2995/0063 ,  B29K2995/007 ,  C08J9/122 ,  C08J9/232 ,  C08J9/236 ,  C08J2201/026 ,  C08J2201/034 ,  C08J2203/06 ,  C08J2203/182 ,  C08J2205/044 ,  C08J2205/046 ,  C08J2205/052 ,  C08J2300/22 ,  C08J2300/26 ,  C08J2325/10 ,  C08J2353/02 ,  C08J2367/02 ,  C08J2375/06 ,  C08J2375/08 ,  C08J2377/02 ,  C08J2377/04 ,  C08J2377/06

Abstract: A process for production of expanded thermoplastic elastomer beads in the presence of a gaseous medium that surrounds thermoplastic elastomer beads. The process comprises a) an impregnating step, in which the gaseous medium has an impregnating temperature Ta, and the absolute pressure of the gaseous medium is greater than ambient pressure, the thermoplastic elastomer beads impregnated with a blowing agent, b) an expanding step, in which the thermoplastic elastomer beads expand as they are exposed to a pressure reduction at a first expanding temperature Tb, and c) optionally a fusing step, in which the expanded thermoplastic elastomer beads are fused together at a fusing temperature Tc to form at least one shaped part.

公开(公告)号：US20160121524A1

公开(公告)日：2016-05-05

申请号：US14897746

申请日：2014-06-11

Applicant: BASF SE

Inventor： Christian DÄSCHLEIN ,  Peter GUTMANN ,  Frank PRISSOK ,  Uwe KEPPELER ,  Jürgen AHLERS

IPC: B29C44/34 ,  B29B9/14 ,  C08J9/16 ,  B29B9/06

CPC classification number: B29C44/3461 ,  B29B7/88 ,  B29B7/90 ,  B29B9/06 ,  B29B9/065 ,  B29B9/12 ,  B29B9/14 ,  B29C44/04 ,  B29C47/0011 ,  B29C47/0014 ,  B29C47/86 ,  B29K2021/003 ,  B29K2077/00 ,  B29K2105/0085 ,  B29K2105/16 ,  B29K2995/007 ,  B29K2995/0082 ,  C08J9/0066 ,  C08J9/122 ,  C08J9/16 ,  C08J9/34 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2300/22 ,  C08J2300/26 ,  C08J2377/06

Abstract: The invention relates to a process for production of expanded pellets from a thermoplastic elastomer having an elongation at break of more than 100% measured to DIN EN 150 527-2, said process comprising the steps of: (a) pressing a polymer melt comprising a blowing agent through a perforated disk (18) controlled to a temperature between 150° C. and 280° C. and into a pelletizing chamber (26), (b) using a cutting device (20) to comminute the polymer melt pressed through the perforated disk (18) into individual expanding pellets, (c) discharging the pellets from the pelletizing chamber (26) using a liquid stream (36), wherein the blowing agent comprises CO2 or N2 or a combination of CO2 and N2 and the amount of blowing agent in the polymer melt comprising a blowing agent lies in the range from 0.5 to 2.5 wt % and wherein the pelletizing chamber (26) is traversed by a stream of liquid which is controlled to a temperature between 5° C. and 90° C. and the pressure of which is from 0.1 bar to 20 bar above ambient pressure, the pressure and temperature for the liquid in the pelletizing chamber (26) and also the temperature for the perforated disk (18) being chosen such that the pellets are expanded in the pressurized liquid by the blowing agent they contain so as to produce expanded pellets having an uninterrupted skin.

Abstract translation: 本发明涉及从根据DIN EN 150 527-2测量的断裂伸长率大于100％的热塑性弹性体生产发泡颗粒的方法，所述方法包括以下步骤：（a）将包含 发泡剂通过控制在150℃和280℃之间的温度的多孔盘（18）进入造粒室（26），（b）使用切割装置（20）粉碎通过 （18）分成单独的膨胀颗粒，（c）使用液体流（36）从造粒室（26）排出颗粒，其中发泡剂包括CO 2或N 2或CO 2和N 2的组合， 包含发泡剂的聚合物熔体中的发泡剂在0.5至2.5重量％的范围内，并且其中造粒室（26）通过被控制在5℃和90℃之间的温度的液流 ，其压力为0.1b 在高于环境压力的情况下，选择造粒室（26）中的液体的压力和温度以及多孔板（18）的温度，使得颗粒在加压液体中由发泡剂膨胀， 包含以产生具有不间断皮肤的发泡颗粒。

公开(公告)号：US20160244587A1

公开(公告)日：2016-08-25

申请号：US15029686

申请日：2014-10-17

Applicant: BASF SE

Inventor： Peter GUTMANN ,  Christian DÄSCHLEIN ,  Jürgen AHLERS ,  Elke MARTEN ,  Torben KAMINSKY ,  Dirk KEMPFERT

IPC: C08J9/34 ,  C08G18/66 ,  C08G18/76 ,  C08J9/12

CPC classification number: C08J9/34 ,  B29B7/88 ,  B29B9/065 ,  B29B9/12 ,  B29C44/3461 ,  C08G18/6674 ,  C08G18/7671 ,  C08G2101/0033 ,  C08G2101/0058 ,  C08J9/0066 ,  C08J9/122 ,  C08J9/127 ,  C08J9/141 ,  C08J9/144 ,  C08J9/149 ,  C08J9/16 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2203/182 ,  C08J2300/22 ,  C08J2300/26 ,  C08J2375/06 ,  C08J2375/08

Abstract: The invention relates to a process for production of expanded thermoplastic elastomer, said process comprising the steps of: (e) adding monomers and/or oligomers used for producing the thermoplastic elastomer with or without further starting materials into a first stage of a polymer-processing machine, (f) mixing the monomers and/or oligomers and also the optionally added further starting materials and reacting the monomers and/or oligomers to give a polymer melt in the first stage of the polymer-processing machine, (g) passing the polymer melt into a second stage of a polymer-processing machine and adding a physical blowing agent with or without further starting materials to obtain a polymer melt comprising a blowing agent, (h) molding the polymer melt comprising a blowing agent into an expanded thermoplastic elastomer.

Abstract translation: 本发明涉及一种生产发泡热塑性弹性体的方法，所述方法包括以下步骤：（e）将具有或没有其它原料的热塑性弹性体制备的单体和/或低聚物加入聚合物加工的第一阶段 机器，（f）混合单体和/或低聚物以及任选加入的进一步原料并使单体和/或低聚物反应，以在聚合物加工机的第一阶段得到聚合物熔体，（g）使聚合物 熔化成聚合物加工机的第二阶段并加入具有或没有其它起始材料的物理发泡剂以获得包含发泡剂的聚合物熔体，（h）将包含发泡剂的聚合物熔体模制成发泡热塑性弹性体。