公开(公告)号：US20180036723A1

公开(公告)日：2018-02-08

申请号：US15550581

申请日：2016-02-12

申请人： BASF SE ,  Dow Global Technologies LLC

发明人： Dominic RIEDEL ,  Joaquim Henrique TELES ,  Daniel URBANCZYK ,  Ulrike WEGERLE ,  Luise SPISKE ,  Andrei-Nicolae PARVULESCU ,  Alexander SCHROEDER ,  Ulrich MUELLER ,  Meinolf WEIDENBACH ,  Werner J. WITZL

IPC分类号： B01J29/89 ,  C07D301/12 ,  B01J38/48 ,  B01J29/90 ,  B01J38/12

CPC分类号： B01J29/89 ,  B01J29/90 ,  B01J35/023 ,  B01J35/1061 ,  B01J38/12 ,  B01J38/48 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/085 ,  C07D301/12 ,  Y02P20/52 ,  Y02P20/584

摘要： The invention relates to process for the regeneration of a catalyst comprising a titanium containing zeolite as catalytically active material comprising a stage comprising introducing a feed stream comprising propene, hydrogen peroxide or a hydrogen peroxide source, and an organic solvent into a reactor containing a catalyst comprising the titanium containing zeolite, subjecting the feed stream in the reactor to epoxidation conditions in the presence of the catalyst, removing a product steam comprising propylene oxide and the organic solvent from the reactor, stopping introducing the feed stream, washing the catalyst with a liquid aqueous system and calcining the washed catalyst.

公开(公告)号：US20160176835A1

公开(公告)日：2016-06-23

申请号：US14908042

申请日：2014-07-16

申请人： BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

发明人： Dominic RIEDEL ,  Joaquim Henrique TELES ,  Ulrike WEGERLE ,  Andrei-Nicolae PARVULESCU ,  Alexander SCHROEDER ,  Luise SPISKE ,  Daniel URBANCZYK ,  Ulrich MUELLER ,  Werner WITZL ,  Meinolf Weidenbach

IPC分类号： C07D301/12 ,  B01J29/70 ,  B01J27/232 ,  B01J27/18 ,  B01J31/04 ,  C07D301/00 ,  B01J27/188

CPC分类号： C07D301/12 ,  B01J27/1806 ,  B01J27/188 ,  B01J27/232 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J31/04 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01B39/48 ,  C07D301/00 ,  C07D301/36 ,  C07D303/04 ,  Y02P20/52

摘要： A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt; (ii) passing the feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW, and subjecting the feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one potassium salt, optionally propene, and optionally pane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one potassium salt, optionally propene, and optionally propane.

摘要翻译： 一种用于制备环氧丙烷的连续方法，包括（i）提供包含丙烯，过氧化氢，乙腈，水，任选的丙烷和至少一种溶解的钾盐的液体进料流; （ii）将（i）中提供的进料流送入包含包含结构类型MWW的钛沸石的催化剂的环氧化反应器中，并使进料流在环氧化反应器中进行环氧化反应条件，得到包含环氧丙烷， 乙腈，水，至少一种钾盐，任选的丙烯，以及任选的玻璃; （iii）从环氧化反应器中除去流出物流，流出物流包含环氧丙烷，乙腈，水，至少一部分至少一种钾盐，任选的丙烯和任选的丙烷。

公开(公告)号：US20170298034A1

公开(公告)日：2017-10-19

申请号：US15636787

申请日：2017-06-29

申请人： BASF SE ,  DOW Global Technologies LLC

发明人： Dominic RIEDEL ,  Joaquim Henrique TELES ,  Ulrike WEGERLE ,  Andrei-Nicolae PARVULESCU ,  Alexander SCHROEDER ,  Luise SPISKE ,  Daniel URBANCZYK ,  Ulrich MUELLER ,  Werner WITZL ,  Meinolf Weidenbach

IPC分类号： C07D301/12 ,  C07D301/36 ,  B01J27/18 ,  B01J27/188 ,  B01J27/232 ,  B01J29/70 ,  B01J29/89 ,  B01J31/04 ,  C07D301/00 ,  C01B39/48 ,  C01B39/12 ,  C01B39/08 ,  C01B39/02 ,  B01J37/00 ,  B01J35/02 ,  B01J35/00 ,  C07D303/04 ,  B01J29/86

CPC分类号： C07D301/12 ,  B01J27/1806 ,  B01J27/188 ,  B01J27/232 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J31/04 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01B39/48 ,  C07D301/00 ,  C07D301/36 ,  C07D303/04 ,  Y02P20/52

摘要： A catalytic system containing a titanium zeolite of structure type MWW optionally containing zinc and containing at least one of an inorganic potassium salt and an organic potassium salt is provided. The catalyst system is useful in the preparation of propylene oxide.