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公开(公告)号：US4336241A
公开(公告)日：1982-06-22
申请号：US244844
申请日：1981-03-18
IPC分类号： B01J19/24 , C01B15/023 , C01B15/02
CPC分类号： B01J19/2475 , B01J19/2465 , C01B15/023
摘要： Hydrogen peroxide production by oxidation of a 2-alkyl-9,10-dihydroxyanthracene, especially the 2-(t-butyl) compound, and catalytic hydrogenation of the resulting 2-alkylanthraquinone back to the dihydroxy compound, using a water-insoluble (bipyridyl) rhodium complex as hydrogenation catalyst. Especially such process carried continuously in a cell in which an organic phase is separated by a porous membrane from an aqueous phase, and the anthraquinone is hydrogenated on the organic side of the cell and hydrogen peroxide is obtained from the aqueous phase. Preferably the rhodium complex is formed with a bipyridyl ligand attached to polystyrene beads, whereby to assure that rhodium is not carried into the hydrogen peroxide production side of the cell.
摘要翻译： 通过氧化2-烷基-9,10-二羟基蒽，特别是2-（叔丁基）化合物，并将所得2-烷基蒽醌催化氢化成二羟基化合物，使用水不溶性（联吡啶 ）铑络合物作为氢化催化剂。 特别地，这种方法在有机相通过多孔膜从水相中分离的电池中连续进行，并且在电池的有机侧上氢化蒽醌，并且从水相中获得过氧化氢。 优选地，铑络合物与连接到聚苯乙烯珠上的联吡啶配体形成，由此确保铑不被运送到电池的过氧化氢生产侧。
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2.发明授权
公开(公告)号：US4207305A
公开(公告)日：1980-06-10
申请号：US33766
申请日：1979-04-27
IPC分类号： C01B15/01 , C01B17/05 , C01B15/022 , C01B17/04
摘要： A process of reacting in the liquid phase a hexacoordinated ruthenium(II) complex with oxygen in the presence of a source of hydrogen ions under conditions forming hydrogen peroxide and the corresponding hexacoordinated ruthenium(III) complex and reacting the hexacoordinated ruthenium(III) complex with hydrogen sulfide to form elemental sulfur and regenerate the hexacoordinated ruthenium(II) complex, the hexacoordinated ruthenium(III) complex having a reduction potential of not more than +0.68. Five or six of the ligands of the ruthenium complexes are non-labile in both valence states.
摘要翻译： 在形成过氧化氢的条件和相应的六配位钌（III）络合物的条件下，在氢离子源存在下，使六配位钌（II）配合物在液相中与氧反应的过程，并使六配位钌（III）络合物与 硫化氢以形成元素硫并再生六配位的钌（II）络合物，具有还原电位不超过+ 0.68的六配位钌（III）络合物。 钌络合物的五或六个配体在两个价态都是非不稳定的。
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公开(公告)号：US4191696A
公开(公告)日：1980-03-04
申请号：US927194
申请日：1978-07-24
IPC分类号： C07C5/367 , B01J31/00 , B01J31/18 , B01J31/22 , B01J31/26 , C07B31/00 , C07B33/00 , C07B61/00 , C07C1/00 , C07C5/50 , C07C15/04 , C07C45/00 , C07C45/29 , C07C45/38 , C07C49/403 , C07C67/00 , C07F9/53 , C07C5/48 , C07C27/12 , C07C29/02 , C07C45/16
CPC分类号： B01J31/26 , B01J31/1805 , B01J31/2243 , B01J31/226 , C07C45/29 , C07C45/38 , C07C5/50 , B01J2231/70 , B01J2531/0252 , B01J2531/80 , B01J2531/845 , Y02P20/52
摘要： A new liquid phase oxidation process in which a metal nitro complex transfers an oxygen atom from the nitro ligand to a substrate; especially such process conducted cyclically or catalytically using molecular oxygen as the oxygen source. Metal nitrosyl complex is formed as a coproduct together with an oxidation product of the substrate. In a catalytic process, molecular oxygen maintains a concentration of nitro ligand in the reaction mixture. In a cyclic process, nitrosyl ligand of the metal nitrosyl coproduct is reoxidized by molecular oxygen in presence of a monodentate base such as pyridine to nitro ligand; and the nitro complex, thus regenerated, can be used again to oxidize the substrate, In particular the metal is a Group VIII metal, especially cobalt and the nitro complex is pyridine cobalt nitro saloph. To accelerate oxidation of the substrate at given temperature, a cocatalyst is included in the reaction mixture, e.g. an organic complex of a transition metal such as Mo(VI), Pd(II), or a compound of a trivalent metallic element with an element of Group VII, such as the compound BF.sub.3.
摘要翻译： 一种新的液相氧化工艺，其中金属硝基络合物将氧原子从硝基配体转移到底物; 特别是使用分子氧作为氧源循环或催化地进行该方法。 金属亚硝酰基络合物与基底的氧化产物一起形成副产物。 在催化过程中，分子氧维持反应混合物中硝基配体的浓度。 在环状过程中，亚硝酰基副产物的亚硝酰基配体在单齿碱如吡啶存在下，被分子氧再氧化成硝基配体; 并且再生的硝基络合物可以再次用于氧化底物。特别地，金属是Ⅷ族金属，特别是钴，硝基络合物是吡啶钴硝基sal oph。 为了在给定温度下加速底物的氧化，助催化剂包括在反应混合物中，例如， 过渡金属如Mo（VI），Pd（II）或具有第VII族元素的三价金属元素化合物如有机络合物，如化合物BF3。
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公开(公告)号：US4322562A
公开(公告)日：1982-03-30
申请号：US218321
申请日：1980-12-19
CPC分类号： B01J31/403 , B01J31/1805 , B01J31/1815 , C07C45/29 , C07C45/38 , C07C5/50 , B01J2531/80 , B01J2531/824 , B01J2531/845 , Y02P20/52 , Y02P20/584
摘要： An oxidation process in which a metal nitro complex transfers an oxygen atom from the nitro ligand to a substrate; especially such process conducted cyclically or catalytically using molecular oxygen as the oxygen source. Metal nitrosyl complex is formed as a coproduct together with an oxidation product of the substrate. In a cyclic process, nitrosyl ligand of the metal nitrosyl coproduct is reoxidized by molecular oxygen in presence of a monodentate base such as pyridine to nitro ligand; and the nitro complex, thus regenerated, can be used again to oxidize the substrate. In a catalytic process, using an activator such as a Lewis acid with alcohols or divalent palladium with olefins, elemental oxygen maintains a concentration of nitro ligand in the reaction mixture. In particular the metal is a Group VIII metal, especially cobalt and the ligand is saloph or tetraphenylporphyrin.
摘要翻译： 其中金属硝基络合物将氧原子从硝基配体转移到底物的氧化方法; 特别是使用分子氧作为氧源循环或催化地进行该方法。 金属亚硝酰基络合物与基底的氧化产物一起形成副产物。 在环状过程中，亚硝酰基副产物的亚硝酰基配体在单齿碱如吡啶存在下，被分子氧再氧化成硝基配体; 并且因此再生的硝基络合物可以再次用于氧化底物。 在催化方法中，使用活化剂如路易斯酸与醇或二价钯与烯烃，元素氧保持反应混合物中硝基配体的浓度。 特别地，金属是VIII族金属，特别是钴，配体是鲑鱼或四苯基卟啉。
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公开(公告)号：US5218052A
公开(公告)日：1993-06-08
申请号：US793821
申请日：1991-11-18
IPC分类号： C08F10/06 , C08F2/38 , C08F4/60 , C08F4/654 , C08F4/656 , C08F10/00 , C08F110/06 , C08F210/06 , C08F297/08
CPC分类号： C08F110/06 , C08F297/083 , C08F10/06 , C08F210/06
摘要： A multistage method for making a homopolymer or copolymer of an alpha-olefin having increased stiffness and broadened molecular weight distribution.
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6.发明授权Olefin polymerization catalyst system producing polymer with low active chloride 失效烯烃聚合催化剂体系生产低活性氯化物的聚合物
公开(公告)号：US4567155A
公开(公告)日：1986-01-28
申请号：US653211
申请日：1984-09-24
CPC分类号： C08F10/00
摘要： A catalyst system especially suited for polymerizing alpha-olefins in the gas-phase to polymers containing essentially no active chloride comprises (A) a titanium-containing component supported on a hydrocarbon-insoluble magnesium-containing compound in combination with an electron donor compound and (B) a co-catalyst comprising (a) at least one trialkylaluminum compound (b) an aromatic acid ester and (c) an unhindered secondary amine, optionally reacted with a dialkylaluminum hydride, in substantial absence of compounds containing an Al-Cl bond.
摘要翻译： 特别适用于将气相中的α-烯烃聚合成基本上不含活性氯化物的聚合物的催化剂体系包括（A）负载在不溶于烃的化合物上的含钛组分与电子给体化合物的组合和（ B）助催化剂，其包含（a）至少一种三烷基铝化合物（b）芳族酸酯和（c）基本上不含有Al-Cl键的化合物的任选与氢化二烷基铝反应的未受阻胺。
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7.发明授权Method and apparatus for minimizing polymer agglomerate or lump formation in a gas-phase polypropylene polymerization reactor 失效在气相聚丙烯聚合反应器中最小化聚合物团块或团块形成的方法和装置
公开(公告)号：US4921919A
公开(公告)日：1990-05-01
申请号：US202092
申请日：1988-06-03
CPC分类号： B01J19/18 , B01J19/002 , B01J8/36 , B01J8/382 , C08F10/00 , B01J2208/00 , B01J2219/00184 , B01J2219/182 , B01J2219/1943 , C08F2400/02 , Y10S526/901 , Y10S526/919
摘要： The process and the system are used for carrying out the quench-cooled, vapor-phase polymerization of olefin monomer in a horizontally disposed reactor vessel which comprises contacting olefin monomer, or a mixture of olefin monomers, with a polymerization catalyst system in the presence of hydrogen in the reactor vessel to form a polymer product. The improvement comprises introducing a titanium-containing catalyst component of the catalyst system into the top side of the reactor vessel at a point adjacent to the upstream end of the reactor vessel and introducing a cocatalyst plus modifer component of the catalyst system into the top side of the reactor vessel at a distance, downstream of the point of introduction of the titanium-containing catalyst component, which is equal to 25% of the inside diameter of the reactor vessel.
摘要翻译： 该方法和系统用于在水平设置的反应器容器中进行烯烃单体的骤冷，气相聚合，其包括使烯烃单体或烯烃单体的混合物与聚合催化剂体系在存在 氢气在反应器容器中形成聚合物产物。 改进之处在于将催化剂体系的含钛催化剂组分引入到与反应器容器的上游端相邻的位置的反应容器的顶侧，并将催化剂体系的助催化剂加改性剂组分引入到 反应器容器在相对于反应器容器的内径的25％的距离处，引入含钛催化剂组分的下游。
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8.发明授权Silane-modified supported polyolefin catalyst to produce a broadened molecular weight distribution product 失效硅烷改性的负载型聚烯烃催化剂，以产生扩展的分子量分布产物
公开(公告)号：US4990478A
公开(公告)日：1991-02-05
申请号：US410663
申请日：1989-09-21
CPC分类号： C08F10/00
摘要： An olefin polymerization catalyst system comprises a solid, hydrocarbon-insoluble, magnesium-containing, titanium-containing, electron donor-containing component; an alkyl aluminum compound; and organosilane compound selected from the group consisting of branched C.sub.3 -C.sub.10 alkyl-t-butoxydimethoxysilanes.
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9.发明授权Alpha-olefin polymerization catalyst system including an advantageous modifier component 失效包括有利的改性剂组分的α-烯烃聚合催化剂体系
公开(公告)号：US4829038A
公开(公告)日：1989-05-09
申请号：US186360
申请日：1988-04-25
CPC分类号： C08F10/00
摘要： An olefin polymerization catalyst system comprises a solid, hydrocarbon-insoluble, magnesium-containing, titanium-containing, electron donor-containing component; an alkyl aluminum compound; and organosilane compound selected from the group consisting of diisobutyldimethoxysilane, diisopropyldimethoxysilane, t-butyltrimethoxysilane and di-t-butyldimethoxysilane, and mixtures thereof.
摘要翻译： 烯烃聚合催化剂体系包含固体，不溶于烃，含镁，含钛，含电子给体的组分; 烷基铝化合物; 和选自二异丁基二甲氧基硅烷，二异丙基二甲氧基硅烷，叔丁基三甲氧基硅烷和二叔丁基二甲氧基硅烷的有机硅烷化合物及其混合物。
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10.发明授权
公开(公告)号：US4579836A
公开(公告)日：1986-04-01
申请号：US736941
申请日：1985-05-22
CPC分类号： C08F10/00 , Y10S526/904
摘要： An exhaustively prepolymerized supported olefin polymerization catalyst component comprises solid, hydrocarbon-insoluble, magnesium-containing, titanium-containing catalyst particles which have been contacted with an olefin monomer and an organo-aluminum co-catalyst under exhaustive prepolymerization conditions at an Al/Ti atomic ratio such that the weight of prepolymer formed is less than 10 times the weight of such catalyst particles and the resulting prepolymerized catalyst particles essentially are inactive to further polymerization.
摘要翻译： 全部预聚的负载型烯烃聚合催化剂组分包括固体，烃不溶性，含镁，含钛的催化剂颗粒，其在Al / Ti原子的完全预聚合条件下已经与烯烃单体和有机铝助催化剂接触 比例使得形成的预聚物的重量小于这种催化剂颗粒的重量的10倍，并且所得预聚催化剂颗粒基本上对于进一步聚合是无活性的。
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