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1.发明申请公开(公告)号：US20080029435A1
公开(公告)日：2008-02-07
申请号：US11812484
申请日：2007-06-19
CPC分类号： B01J29/90 , B01J29/7038 , C10G29/205 , C10G50/00
摘要： A method of rejuvenating a deactivated molecular sieve catalyst, deactivated by use in an olefin oligomerization or aromatics alkylation process, which method comprises contacting the deactivated catalyst with a stream of rejuvenation gas comprising a hydrocarbon product fraction from the process at an elevated temperature and pressure for a time sufficient to effect an increase in catalytic activity of the deactivated catalyst.
摘要翻译： 一种使失活的分子筛催化剂恢复活化的方法，其通过用于烯烃低聚或芳烃烷基化方法失活，该方法包括使失活的催化剂与包含烃产物馏分的再生气体流在升高的温度和压力下接触， 足以使失活催化剂的催化活性增加的时间。
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公开(公告)号：US20070185359A1
公开(公告)日：2007-08-09
申请号：US11698813
申请日：2007-01-29
申请人： Benjamin S. Umansky , Arthur P. Werner , Amanda K. Miller , Tomas R. Melli , Christopher M. Dean , Niveen S. Ismail , Garland B. Brignac
发明人： Benjamin S. Umansky , Arthur P. Werner , Amanda K. Miller , Tomas R. Melli , Christopher M. Dean , Niveen S. Ismail , Garland B. Brignac
CPC分类号： B01J29/7038 , B01J29/70 , C10G50/00 , C10G57/02 , C10G2400/02
摘要： A process unit for the zeolite-catalyzed conversion of light refinery olefins from an FCC unit such as ethylene, propylene, and butylene to gasoline boiling range motor fuels comprises at least two sequential, serially connected reactors connected in parallel to a fractionation section with at one or two fractionators for separating the reactor effluents into product fraction with an optional recycle stream or streams. The configurations according to this scheme allow the adjustment of reactor temperature and/or pressure and/or space velocity to be based on the reactivities of the olefin compounds present in the LPG streams so that the gasoline produced in each reactor will be separated immediately, to reduce over-polymerization of the gasoline in the low severity reactor and to ensure that gasoline formed in the low severity reactor will not be sent to the higher severity reactor e.g. with a higher reactor temperature, where excessive polymerization to undesirable higher molecular with products may take place.
摘要翻译： 沸石催化的轻质炼油烯烃从FCC装置如乙烯，丙烯和丁烯转化成汽油沸程的发动机燃料的处理单元包括至少两个连续的串联连接的反应器，其与一个分离部分并联连接 或两个分离器，用于将反应器流出物与任选的再循环流或物流分离成产物级分。 根据该方案的配置允许基于LPG流中存在的烯烃化合物的反应性来调节反应器温度和/或压力和/或空间速度，使得在每个反应器中产生的汽油将立即分离， 减少低严重性反应器中汽油的过度聚合，并确保低浓度反应器中形成的汽油不会送到较高级别的反应器，如 具有较高的反应器温度，其中可能发生过度聚合成不期望的较高分子与产物。
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公开(公告)号：US20080116112A1
公开(公告)日：2008-05-22
申请号：US11898674
申请日：2007-09-14
IPC分类号： C10G17/00
CPC分类号： C10G29/205 , B01J29/40 , B01J29/70 , B01J29/90 , B01J2229/42 , C10G21/00 , C10G27/00 , C10G45/12 , C10G61/10 , Y02P20/52
摘要： A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range. The LCN and HCN are then fractionated to remove light ends and higher boiling sulfur reaction products (disulfides, alkylated thiophenes) boiling above the gasoline boiling range.
摘要翻译： 烯烃，轻质催化石脑油（LCN）和烯烃重催化作用，通过将裂解石脑油分馏成相对低沸点的方法，除去含有苯，有机硫化合物和烯烃的催化裂化石脑油的硫化合物和苯的方法 石脑油（HCN）沸点高于LCN的范围，LCN和HCN的沸点范围由选择为将LCN中的裂解石脑油中的大部分苯保持在沸点范围内的烯烃所限定的切割点 LCN。 对LCN进行任选的非氢化脱硫步骤，然后进行固定床烷基化步骤，其中LCN中的苯用该馏分中所含的烯烃烷基化。 通过类似的烷基化步骤处理HCN，使用该级分中所含的烯烃烷基化硫化合物，形成沸点高于汽油沸程的烷基化产物。 然后将LCN和HCN分馏以除去沸点高于汽油沸程的轻馏分和较高沸点硫反应产物（二硫化物，烷基化噻吩）。
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公开(公告)号：US07837861B2
公开(公告)日：2010-11-23
申请号：US11898674
申请日：2007-09-14
CPC分类号： C10G29/205 , B01J29/40 , B01J29/70 , B01J29/90 , B01J2229/42 , C10G21/00 , C10G27/00 , C10G45/12 , C10G61/10 , Y02P20/52
摘要： A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range. The LCN and HCN are then fractionated to remove light ends and higher boiling sulfur reaction products (disulfides, alkylated thiophenes) boiling above the gasoline boiling range.
摘要翻译： 烯烃，轻质催化石脑油（LCN）和烯烃重催化作用，通过将裂解石脑油分馏成相对低沸点的方法，除去含有苯，有机硫化合物和烯烃的催化裂化石脑油的硫化合物和苯的方法 石脑油（HCN）沸点高于LCN的范围，LCN和HCN的沸点范围由选择为将LCN中的裂解石脑油中的大部分苯保持在沸点范围内的烯烃所限定的切割点 LCN。 对LCN进行任选的非氢化脱硫步骤，然后进行固定床烷基化步骤，其中LCN中的苯用该馏分中所含的烯烃烷基化。 通过类似的烷基化步骤处理HCN，使用该级分中所含的烯烃烷基化硫化合物，形成沸点高于汽油沸程的烷基化产物。 然后将LCN和HCN分馏以除去沸点高于汽油沸程的轻馏分和较高沸点硫反应产物（二硫化物，烷基化噻吩）。
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5.发明授权Method for separating conjunct polymeric byproducts from mixture containing hydrofluoric acid and a sulfone 失效从包含氢氟酸和砜的混合物中分离结合的聚合副产物的方法
公开(公告)号：US5264652A
公开(公告)日：1993-11-23
申请号：US991921
申请日：1992-12-17
申请人： Jonathan E. Child , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
发明人： Jonathan E. Child , Edward H. Edelson , Anagha A. Gupte , Rafi Jalkian , Tomas R. Melli , Sergei Yurchak
CPC分类号： C01B7/195 , C07C2/62 , C07C9/16 , C07C2527/1206
摘要： The present invention provides a method for separating conjunct polymers which are formed as byproducts of acid catalyzed isoparaffin-olefin alkylation and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) separating hydrofluoric acid from said mixture to provide an intermediate stream containing less than about 30 percent hydrofluoric acid by weight;(b) gravitationally separating said intermediate stream into a more dense sulfolane-enriched stream and a less dense conjunct polymer-enriched stream;(c) distilling said more dense sulfolane-enriched stream of step (b) to provide an overhead stream containing a higher sulfolane concentration than said more dense sulfolane-enriched stream of step (b) and a bottom stream enriched in conjunct polymers.
摘要翻译： 本发明提供一种从含有结合聚合物，环丁砜和氢氟酸的混合物中分离出作为酸催化的异链烷烃 - 烯烃烷基化和环丁砜的副产物形成的结合聚合物的方法，包括以下顺序步骤：（a）将氢氟酸与所述 混合物以提供含有按重量计小于约30％氢氟酸的中间料流; （b）将所述中间物流重力分离成更稠密的富含环丁砜的物流和不太致密的结合聚合物富集料流; （c）蒸馏步骤（b）的所述更稠密的富含环丁砜的物流，以提供比步骤（b）的所述更致密的富含环丁砜的物流高的环丁砜浓度的塔顶物流和富含结合聚合物的塔底物流。
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公开(公告)号：US07976710B2
公开(公告)日：2011-07-12
申请号：US11369613
申请日：2006-03-07
CPC分类号： B01D71/28 , B01D61/025 , B01D61/027 , B01D61/362 , B01D61/58 , B01D71/38 , B01D2317/022 , B01D2325/30 , C01B17/88
摘要： A cross-linked polyvinyl sulfate, copolymer of polyvinyl sulfate and polyvinyl alcohol, or Nafion® membrane is used for recovering sulfuric acid from a feed mixture comprising predominantly acid and water under reverse osmosis conditions wherein sulfuric acid is enriched in the retentate stream and water is removed in the permeate stream.
摘要翻译： 交联聚乙烯硫酸盐，聚乙烯硫酸盐和聚乙烯醇的共聚物或Nafion膜用于从反渗透条件下主要含有酸和水的进料混合物回收硫酸，其中硫酸富集在滞留物流中，水是 在渗透物流中除去。
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公开(公告)号：US5262579A
公开(公告)日：1993-11-16
申请号：US991918
申请日：1992-12-17
IPC分类号： C01B7/19 , C07C2/62 , C07D333/48 , C07C7/10
CPC分类号： C07D333/48 , C01B7/195 , C07C2/62 , C07C2527/1206
摘要： The present invention provides a method for separating sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising the sequential steps of:(a) removing HF from said mixture to provide an intermediate stream containing less than about 30 weight percent HF;(b) contacting said intermediate stream with water;(c) contacting said intermediate stream with an aliphatic hydrocarbon co-solvent having from about 3 to about 20 carbon atoms concurrently with said water-contacting step (b);(d) recovering an extract stream enriched in sulfolane and hydrofluoric acid; and(e) recovering a raffinate stream enriched in conjunct polymers.
摘要翻译： 本发明提供了从含有结合聚合物，环丁砜和氢氟酸的混合物中分离环丁砜的方法，其包括以下顺序步骤：（a）从所述混合物中除去HF以提供含有少于约30重量％HF的中间物流; （b）使所述中间物流与水接触; （c）使所述中间物流与具有约3至约20个碳原子的脂族烃共溶剂与所述水接触步骤（b）同时接触; （d）回收富含环丁砜和氢氟酸的萃取物流; 和（e）回收富含结合聚合物的萃余液流。
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公开(公告)号：US08002983B2
公开(公告)日：2011-08-23
申请号：US11783486
申请日：2007-04-10
摘要： A strainer device for a fluid flow circuit removes debris and solid particles from the fluid flow to prevent plugging and reduce fouling of the system. The assembly includes a chamber that can be hydrocyclonic, a collection area, a screen assembly and a distributor that allows selective connection to a flushing fluid. The fluid flows through the chamber past the strainer device, with large particles collecting in the collection area under the influence of gravity and smaller solid particles being collected in the screen assembly. Particles can be flushed from the system by selectively activating the distributor to back flush the screen assembly and sweep the collection area free of solid particles without disassembling the system.
摘要翻译： 用于流体流动回路的过滤器装置从流体流中去除碎屑和固体颗粒以防止堵塞并减少系统的结垢。 组件包括可以是水力旋流器的腔室，收集区域，筛网组件和分配器，其允许选择性地连接到冲洗流体。 流体经过过滤器装置流过腔室，大量颗粒在重力作用下收集在收集区域，较小的固体颗粒被收集在筛网组件中。 可以通过选择性地启动分配器来将系统中的颗粒冲洗回来冲洗筛网组件，并且在不拆卸系统的情况下扫掠没有固体颗粒的收集区域。
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公开(公告)号：US07803276B2
公开(公告)日：2010-09-28
申请号：US10579175
申请日：2004-12-01
CPC分类号： C10G21/28 , C10G17/10 , C10G2300/202 , C10G2300/4081
摘要： This invention relates to a process for recycling acid used to remove nitrogen contaminants from hydrocarbons using polymeric membranes to separate spent acid from the acid extraction of hydrocarbons into acid for recycle and acid for regeneration.
摘要翻译： 本发明涉及一种使用聚合物膜从碳氢化合物中除去氮污染物的方法，以将废酸从碳酸的酸萃取中分离出来，再循环酸和用于再生。
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公开(公告)号：US5258568A
公开(公告)日：1993-11-02
申请号：US965306
申请日：1992-10-23
CPC分类号： C07C2/62 , C07C2527/054 , C07C2527/1206
摘要： A single path process for alkylating a hydrocarbon feedstock containing an olefin and an isoparaffin is disclosed. The process includes dispersing an acid-based liquid alkylation catalyst into a reaction zone for contact with a continuous hydrocarbon phase. The process further includes separating the hydrocarbon phase from the acid catalyst upon completion of the alkylation reaction and providing a continuous on-line regeneration of the entire volume of catalyst once it has been separated from the hydrocarbon phase.
摘要翻译： 公开了用于烷基化含有烯烃和异链烷烃的烃原料的单程方法。 该方法包括将酸基液体烷基化催化剂分散在与连续烃相接触的反应区中。 该方法还包括在烷基化反应完成时从酸催化剂中分离出烃相，并且一旦将其从烃相中分离出来，就提供了整个体积催化剂的连续在线再生。
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