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1.发明申请公开(公告)号：US20080029435A1
公开(公告)日：2008-02-07
申请号：US11812484
申请日：2007-06-19
CPC分类号： B01J29/90 , B01J29/7038 , C10G29/205 , C10G50/00
摘要： A method of rejuvenating a deactivated molecular sieve catalyst, deactivated by use in an olefin oligomerization or aromatics alkylation process, which method comprises contacting the deactivated catalyst with a stream of rejuvenation gas comprising a hydrocarbon product fraction from the process at an elevated temperature and pressure for a time sufficient to effect an increase in catalytic activity of the deactivated catalyst.
摘要翻译： 一种使失活的分子筛催化剂恢复活化的方法，其通过用于烯烃低聚或芳烃烷基化方法失活，该方法包括使失活的催化剂与包含烃产物馏分的再生气体流在升高的温度和压力下接触， 足以使失活催化剂的催化活性增加的时间。
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公开(公告)号：US20070185359A1
公开(公告)日：2007-08-09
申请号：US11698813
申请日：2007-01-29
申请人： Benjamin S. Umansky , Arthur P. Werner , Amanda K. Miller , Tomas R. Melli , Christopher M. Dean , Niveen S. Ismail , Garland B. Brignac
发明人： Benjamin S. Umansky , Arthur P. Werner , Amanda K. Miller , Tomas R. Melli , Christopher M. Dean , Niveen S. Ismail , Garland B. Brignac
CPC分类号： B01J29/7038 , B01J29/70 , C10G50/00 , C10G57/02 , C10G2400/02
摘要： A process unit for the zeolite-catalyzed conversion of light refinery olefins from an FCC unit such as ethylene, propylene, and butylene to gasoline boiling range motor fuels comprises at least two sequential, serially connected reactors connected in parallel to a fractionation section with at one or two fractionators for separating the reactor effluents into product fraction with an optional recycle stream or streams. The configurations according to this scheme allow the adjustment of reactor temperature and/or pressure and/or space velocity to be based on the reactivities of the olefin compounds present in the LPG streams so that the gasoline produced in each reactor will be separated immediately, to reduce over-polymerization of the gasoline in the low severity reactor and to ensure that gasoline formed in the low severity reactor will not be sent to the higher severity reactor e.g. with a higher reactor temperature, where excessive polymerization to undesirable higher molecular with products may take place.
摘要翻译： 沸石催化的轻质炼油烯烃从FCC装置如乙烯，丙烯和丁烯转化成汽油沸程的发动机燃料的处理单元包括至少两个连续的串联连接的反应器，其与一个分离部分并联连接 或两个分离器，用于将反应器流出物与任选的再循环流或物流分离成产物级分。 根据该方案的配置允许基于LPG流中存在的烯烃化合物的反应性来调节反应器温度和/或压力和/或空间速度，使得在每个反应器中产生的汽油将立即分离， 减少低严重性反应器中汽油的过度聚合，并确保低浓度反应器中形成的汽油不会送到较高级别的反应器，如 具有较高的反应器温度，其中可能发生过度聚合成不期望的较高分子与产物。
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公开(公告)号：US07837861B2
公开(公告)日：2010-11-23
申请号：US11898674
申请日：2007-09-14
CPC分类号： C10G29/205 , B01J29/40 , B01J29/70 , B01J29/90 , B01J2229/42 , C10G21/00 , C10G27/00 , C10G45/12 , C10G61/10 , Y02P20/52
摘要： A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range. The LCN and HCN are then fractionated to remove light ends and higher boiling sulfur reaction products (disulfides, alkylated thiophenes) boiling above the gasoline boiling range.
摘要翻译： 烯烃，轻质催化石脑油（LCN）和烯烃重催化作用，通过将裂解石脑油分馏成相对低沸点的方法，除去含有苯，有机硫化合物和烯烃的催化裂化石脑油的硫化合物和苯的方法 石脑油（HCN）沸点高于LCN的范围，LCN和HCN的沸点范围由选择为将LCN中的裂解石脑油中的大部分苯保持在沸点范围内的烯烃所限定的切割点 LCN。 对LCN进行任选的非氢化脱硫步骤，然后进行固定床烷基化步骤，其中LCN中的苯用该馏分中所含的烯烃烷基化。 通过类似的烷基化步骤处理HCN，使用该级分中所含的烯烃烷基化硫化合物，形成沸点高于汽油沸程的烷基化产物。 然后将LCN和HCN分馏以除去沸点高于汽油沸程的轻馏分和较高沸点硫反应产物（二硫化物，烷基化噻吩）。
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公开(公告)号：US20080116112A1
公开(公告)日：2008-05-22
申请号：US11898674
申请日：2007-09-14
IPC分类号： C10G17/00
CPC分类号： C10G29/205 , B01J29/40 , B01J29/70 , B01J29/90 , B01J2229/42 , C10G21/00 , C10G27/00 , C10G45/12 , C10G61/10 , Y02P20/52
摘要： A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range. The LCN and HCN are then fractionated to remove light ends and higher boiling sulfur reaction products (disulfides, alkylated thiophenes) boiling above the gasoline boiling range.
摘要翻译： 烯烃，轻质催化石脑油（LCN）和烯烃重催化作用，通过将裂解石脑油分馏成相对低沸点的方法，除去含有苯，有机硫化合物和烯烃的催化裂化石脑油的硫化合物和苯的方法 石脑油（HCN）沸点高于LCN的范围，LCN和HCN的沸点范围由选择为将LCN中的裂解石脑油中的大部分苯保持在沸点范围内的烯烃所限定的切割点 LCN。 对LCN进行任选的非氢化脱硫步骤，然后进行固定床烷基化步骤，其中LCN中的苯用该馏分中所含的烯烃烷基化。 通过类似的烷基化步骤处理HCN，使用该级分中所含的烯烃烷基化硫化合物，形成沸点高于汽油沸程的烷基化产物。 然后将LCN和HCN分馏以除去沸点高于汽油沸程的轻馏分和较高沸点硫反应产物（二硫化物，烷基化噻吩）。
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公开(公告)号：US07525002B2
公开(公告)日：2009-04-28
申请号：US11362128
申请日：2006-02-27
CPC分类号： C10L1/06 , C10G2400/02
摘要： A process for the production of high octane number gasoline from light refinery olefins, typically from the catalytic cracking unit, and benzene-containing aromatic streams such as reformate. A portion of the light olefins including ethylene and propylene is polymerized to form a gasoline boiling range product and another portion is used to alkylate the light aromatic stream. The alkylation step may be carried out in successive stages with an initial low temperature stage using a catalyst comprising an MWW zeolite followed by a higher temperature stage using a catalyst comprising an intermediate pore size zeolite such as ZSM-5. Using this staged approach, the alkylation may be carried out in the vapor phase. Alternatively, the alkylation may be carried out in the liquid phase using the heavier olefins (propylene, butene) dissolved into the aromatic stream by selective countercurrent extraction; a separate alkylation step using the ethylene not taken up in the extraction is carried out at a higher temperature.
摘要翻译： 一种从轻质炼油烯烃（通常来自催化裂化装置）和含苯芳族物流如重整产物生产高辛烷值汽油的方法。 一部分轻质烯烃（包括乙烯和丙烯）聚合形成汽油沸程产物，另一部分用于烷基化轻芳烃流。 烷基化步骤可以在初始低温阶段中使用包含MWW沸石的催化剂，随后使用包含中等孔径沸石如ZSM-5的催化剂进行更高温度阶段的连续阶段进行。 使用这种分级方法，烷基化可以在气相中进行。 或者，烷基化可以使用通过选择性逆流萃取溶解到芳族物流中的较重烯烃（丙烯，丁烯）在液相中进行; 在较高温度下进行使用在萃取中未溶解的乙烯的单独的烷基化步骤。
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公开(公告)号：US07498474B2
公开(公告)日：2009-03-03
申请号：US11362255
申请日：2006-02-27
IPC分类号： C07C2/66
CPC分类号： C10G29/205
摘要： A process for the production of high octane number gasoline from light refinery olefins and benzene-containing aromatic streams such as reformate. The process achieves good utilization of both the ethylene and the propylene present in the mixed olefin feed from the unsaturated gas plant while reducing gasoline benzene levels. The light olefins including ethylene and propylene are reacted with the light aromatic stream containing benzene and other single ring aromatic compounds to form a gasoline boiling range product containing akylaromatics. The reaction is carried out with a two-catalyst system which comprises a member of the MWW family of zeolites and an intermediate pore size zeolite such as ZSM-5 using a fixed catalyst bed in both stages. Use of the two catalyst system enables the conversion of the ethylene and propylene components of the olefin feed to be converted to alkylaromatics under favorable conditions.
摘要翻译： 一种从轻质炼油烯烃和含苯芳族物流如重整油生产高辛烷值汽油的方法。 该方法可以很好地利用来自不饱和气体装置的混合烯烃进料中存在的乙烯和丙烯，同时降低汽油苯的含量。 包括乙烯和丙烯的轻质烯烃与含有苯和其它单环芳族化合物的轻芳烃物流反应，形成含烷基芳族化合物的汽油沸程产品。 该反应用两催化剂体系进行，该双催化剂体系包括MWW沸石族的成员和中等孔径的沸石如ZSM-5，其使用两个阶段的固定催化剂床。 使用这两种催化剂体系可使烯烃进料的乙烯和丙烯成分转化成有利条件下的烷基芳族化合物。
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公开(公告)号：US20140294041A1
公开(公告)日：2014-10-02
申请号：US14226997
申请日：2014-03-27
申请人： Yibing Zhang , Limin Song , Geoff Keiser , Michael L. Hergenrother , Berne K. Stober , Patricia H. Kalamaras , Benjamin S. Umansky
发明人： Yibing Zhang , Limin Song , Geoff Keiser , Michael L. Hergenrother , Berne K. Stober , Patricia H. Kalamaras , Benjamin S. Umansky
CPC分类号： G01N25/18 , G01F1/661 , G01F1/684 , G01F1/6884 , G01F1/74 , G01K11/3206 , G01N25/00
摘要： Systems and methods for determining the flow distribution of a fluid through a component with a sensing cable including an optical fiber sensor array aligned with a heating element disposed in the component. An excitation source is configured to propagate at least one heat pulse through the heating element along at least a portion of the sensing cable to affect an exchange of thermal energy between the heating element and the fluid exposed to the sensing cable. An optical signal is adapted to receive a signal from each of a plurality of sensor locations and measure a temperature profile corresponding to the heat pulse at the sensor locations. A control unit is configured to determine a flow of the fluid by determining one or more properties of the fluid exposed to the sensing cable at each of the plurality of sensor locations based on the temperature profile corresponding thereto. The present invention can be effective in accurate and high spatial resolution of flow distributions through vessel components, such as a particulate bed (such as a reactor catalyst bed), a wash bed including packing material, an absorbent bed, a structured bed, a filter, or the like.
摘要翻译： 用于通过传感电缆确定流体通过部件的流动分布的系统和方法，所述传感电缆包括与设置在所述部件中的加热元件对准的光纤传感器阵列。 激励源被配置为沿着感测电缆的至少一部分传播至少一个热脉冲通过加热元件，以影响加热元件和暴露于感测电缆的流体之间的热能交换。 光信号适于接收来自多个传感器位置中的每一个的信号，并且测量对应于传感器位置处的加热脉冲的温度分布。 控制单元被配置为基于与其对应的温度分布，通过确定在多个传感器位置中的每一个处暴露于感测电缆的流体的一个或多个属性来确定流体的流动。 本发明可以有效地准确和高空间地分辨通过容器部件的流动分布，例如颗粒床（例如反应器催化剂床），包括填充材料的洗涤床，吸收床，结构化床，过滤器 ，等等。
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公开(公告)号：US08591726B2
公开(公告)日：2013-11-26
申请号：US13168240
申请日：2011-06-24
IPC分类号： C10G3/00
CPC分类号： C10G65/12 , B01D3/141 , B01D3/143 , C10G2300/1011 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2300/304 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/04 , C10L1/08 , Y02P30/20
摘要： A divided wall column can allow for fractionation of multiple streams while maintaining separate product qualities. Effluents from multiple stages of a reaction system can be processed in a single divided wall column. The divided wall column can produce multiple cuts from each separated area, as well as at least one output from a common area. At least one reaction stage can advantageously have a continuous liquid phase environment.
摘要翻译： 分隔壁柱可以允许分离多个流，同时保持单独的产品质量。 来自反应体系的多个阶段的流出物可以在单个分隔壁塔中进行处理。 分隔壁柱可以从每个分离的区域产生多个切割，以及从公共区域产生至少一个输出。 至少一个反应阶段可以有利地具有连续的液相环境。
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9.发明授权Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion 有权在高苯转化率下通过苯烷基化制备苯酚含量降低的高辛烷值汽油的方法公开(公告)号：US08395006B2
公开(公告)日：2013-03-12
申请号：US12720345
申请日：2010-03-09
申请人： Michael C. Clark , Benjamin S. Umansky , Elizabeth A. Nye , Mark J. Reichensperger , William C. Lewis
发明人： Michael C. Clark , Benjamin S. Umansky , Elizabeth A. Nye , Mark J. Reichensperger , William C. Lewis
IPC分类号： C07C2/64
CPC分类号： C10G35/065 , B01J29/7038 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G2300/1092 , C10G2300/1096 , C10G2300/301 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , Y02P20/52 , C07C15/085
摘要： A process for the alkylation of a benzene-containing refinery stream such as reformate with light refinery olefins which is capable of achieving high benzene conversion levels operates in a fixed bed of an MWW zeolite catalyst, preferably MCM-22, in single pass mode in the liquid phase at a relatively low to moderate temperatures with pressure maintained at a value adequate to ensure subcritical operation. High levels of benzene conversion with conversions of at least 90% and higher, e.g. 92% or 95% or even higher are achievable. A high octane product is produced, comprising mono-, di- and tri-alkylbenzenes with lesser levels of the tetra-substituted products. By operating with staged olefin injection, the end point of the alkylation product can be maintained at a low value while, at the same time, achieving high levels of benzene and olefin conversion.
摘要翻译： 使用能够获得高苯转化水平的轻炼油烯烃的含苯精炼料流如重整油的烷基化方法在MWW沸石催化剂（优选MCM-22）的固定床中以单程模式在 液相在相对低至中等温度下，压力保持在足以确保亚临界操作的值。 高转化率的苯转化率至少为90％以上，例如。 可达到92％或95％甚至更高。 产生高辛烷值的产物，包括具有较低含量的四取代产物的单烷基苯，二烷基苯和三烷基苯。 通过使用分段烯烃注入操作，烷基化产物的终点可以保持在低值，同时实现高水平的苯和烯烃转化。
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公开(公告)号：US20120156111A1
公开(公告)日：2012-06-21
申请号：US13325148
申请日：2011-12-14
申请人： Antonio O. Ramos , Benjamin S. Umansky , William J. Tracy, III , Ramesh X. Gandhi , Hans G. Korsten , Enrique Feliz
发明人： Antonio O. Ramos , Benjamin S. Umansky , William J. Tracy, III , Ramesh X. Gandhi , Hans G. Korsten , Enrique Feliz
CPC分类号： B01J8/008 , B01J8/0015 , B01J8/003 , B01J8/0035 , B01J8/02 , B01J8/025 , B01J8/0453 , B01J2208/00884 , B01J2208/00938 , B01J2219/00024 , B01J2219/185 , Y10T29/49826
摘要： A structure and method are provided for adding a catalyst bed platform to an existing reactor without welding to the structural portion of the reactor walls. The structure is constructed from components that can be passed through an existing opening in a reactor. The structure allows a catalyst bed in an existing reactor to be divided into catalyst beds with a reduced length to diameter ratio.
摘要翻译： 提供了一种用于将催化剂床平台添加到现有反应器而不与反应器壁的结构部分焊接的结构和方法。 该结构由可以通过反应器中的现有开口的部件构成。 该结构允许将现有反应器中的催化剂床分成具有减小的长径比的催化剂床。
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