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32 条记录 (耗时 0.028 秒)

    Activating supports with controlled distribution of OH groups
    7.
    发明授权
    Activating supports with controlled distribution of OH groups 失效
    激活支持与控制分布的OH基团

    公开(公告)号：US08524627B2

    公开(公告)日：2013-09-03

    申请号：US13318547

    申请日：2010-04-29

    申请人： Gaëlle Pannier ,  Christophe Boisson ,  Roger Spitz

    发明人： Gaëlle Pannier ,  Christophe Boisson ,  Roger Spitz

    IPC分类号： C08F4/02 ,  C08F4/653 ,  C08F4/6592

    CPC分类号： C08F210/16 ,  B01J21/08 ,  B01J31/0272 ,  B01J37/0209 ,  C08F4/659 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  C08F4/65916 ,  C08F4/025 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/24

    摘要： The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerization of olefins comprising the steps of: I) providing a support consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalizing the support with a solution containing a metallic salt; IV) heating the functionalized support of step c) under an inert gas or hydrogen; V) oxidizing the support of step IV by treatment under N2O and then under oxygen; VI) retrieving an active support having a controlled number of OH groups. That activating support is used to activate a metallocene catalyst component for the polymerization of olefins.

    摘要翻译： 本发明涉及一种在烯烃聚合中制备茂金属络合物的活化载体的方法，包括以下步骤：I）提供由至少一种多孔矿物氧化物形成的颗粒组成的载体; II）任选地将硅烷醇的速率固定在载体的表面上; III）使用含有金属盐的溶液官能化载体; IV）在惰性气体或氢气下加热步骤c）的官能化载体; V）通过在N 2 O下处理然后在氧气下氧化步骤IV的载体; VI）检索具有受控数量的OH基团的活性载体。 该活化载体用于活化用于烯烃聚合的茂金属催化剂组分。

    Borohydride Metallocene Complex of a Lanthanide, Catalytic System Including The Said Complex, Polymerisation Method Using Same and Ethylene/Butadiene Copolymer Obtained using Said Method
    8.
    发明申请
    Borohydride Metallocene Complex of a Lanthanide, Catalytic System Including The Said Complex, Polymerisation Method Using Same and Ethylene/Butadiene Copolymer Obtained using Said Method 有权
    镧系元素的硼氢化物茂金属络合物，包括所述络合物的催化体系，使用相同的聚合方法和使用所述方法获得的乙烯/丁二烯共聚物

    公开(公告)号：US20120165492A1

    公开(公告)日：2012-06-28

    申请号：US13290617

    申请日：2011-11-07

    申请人： Julien Thuilliez ,  Christophe Boisson ,  Roger Spitz

    发明人： Julien Thuilliez ,  Christophe Boisson ,  Roger Spitz

    IPC分类号： C08F236/06

    CPC分类号： C08F210/02 ,  C07F17/00 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/52 ,  C08F236/06

    摘要： Borohydride metallocene complex of lanthanide, preparation process, catalytic system incorporating it, copolymerization of olefins employing catalytic system and ethylene/butadiene copolymer, the butadiene units comprise 1,2-cyclohexane or 1,2- and 1,4-cyclohexane links. The complex corresponds to of formulae A and/or B: where, in A two ligands Cp1 and Cp2, each of a fluorenyl group, are connected to the lanthanide Ln, where, in B, a ligand molecule, composed of two fluorenyl groups Cp1 and Cp2 are connected via bridge P of formula MR1R2, is an element from group IVa, R1 and R2, which are identical or different, represent an alkyl group comprising from 1 to 20 carbon atoms, connected to lanthanide Ln, L is alkali metal, N is molecule of a complexing solvent, x is integral or non-integral number ≧0 and p is integer ≧1.

    摘要翻译： 镧系元素的硼氢化物茂金属络合物，制备方法，结合其的催化体系，使用催化体系的烯烃共聚和乙烯/丁二烯共聚物，丁二烯单元包括1,2-环己烷或1,2-和1,4-环己烷连接。 络合物对应于式A和/或B：其中在A两配体Cp1和Cp2中，每个芴基连接到镧系元素Ln，其中在B中，由两个芴基Cp1组成的配体分子 Cp2通过式MR1R2的桥P连接，是相同或不同的来自IVa，R1和R2的元素，代表与镧系元素Ln连接的含有1至20个碳原子的烷基，L是碱金属， N是络合溶剂的分子，x是整数或非整数，≧0，p是整数≧1。

    Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers
    9.
    发明授权
    Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers 有权
    用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系

    公开(公告)号：US08039565B2

    公开(公告)日：2011-10-18

    申请号：US12453333

    申请日：2009-05-07

    申请人： Christophe Boisson ,  Vincent Monteil ,  Roger Spitz

    发明人： Christophe Boisson ,  Vincent Monteil ,  Roger Spitz

    IPC分类号： C08F4/52 ,  C08F236/04 ,  C08F236/06 ,  B01J31/22

    CPC分类号： C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/14 ,  C08F210/16 ,  C08F236/04 ,  Y10S526/943 ,  C08F4/52 ,  C08F236/06

    摘要： A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described. This catalytic system includes: (i) an organometallic complex represented by the following formula: {[P(Cp)(Fl)Ln(X)(LX)}p  (1) where Ln represents a lanthanide atom to which is attached a ligand molecule comprising cyclopentadienyl Cp and fluorenyl Fl groups linked to one another by a bridge P of the formula MR1R2, M is an element from column IVa of Mendeleev's periodic table and R1 and R2 each represent alkyl groups of 1 to 20 carbon atoms or cycloalkyl or phenyl groups of 6 to 20 carbon atoms, X represents a halogen atom, L represents an optional complexing molecule, such as an ether, and optionally a substantially less complexing molecule, such as toluene, p is a natural integer greater than or equal to 1 and x is greater than or equal to 0, and (ii) a co-catalyst selected from alkylmagnesiums, alkyllithiums, alkylaluminums, Grignard reagents and mixtures of these constituents.

    摘要翻译： 一种可用于共聚二烯和至少一种单烯烃的催化体系，该催化体系的制备方法，使用所述催化体系制备共轭二烯和至少一种单烯烃的共聚物的方法，所述共聚物 被描述。 该催化体系包括：（i）由下式表示的有机金属络合物：{[P（Cp）（Fl）Ln（X）（LX）} p（1）其中Ln表示连接有配体的镧系元素 包含通过式MR1R2的桥P彼此连接的环戊二烯基Cp和芴基F1基团的分子，M是门多列夫元素周期表第IVa列的元素，R 1和R 2各自表示1-20个碳原子的烷基或环烷基或苯基 6至20个碳原子的基团，X表示卤素原子，L表示任选的络合分子，例如醚，以及任选的基本上较少络合的分子，例如甲苯，p是大于或等于1的天然整数， x大于或等于0，和（ii）选自烷基镁，烷基锂，烷基铝，格氏试剂和这些组分的混合物的助催化剂。

    Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers
    10.
    发明申请
    Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers 有权
    用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系

    公开(公告)号：US20090270578A1

    公开(公告)日：2009-10-29

    申请号：US12453333

    申请日：2009-05-07

    申请人： Christophe Boisson ,  Vincent Monteil ,  Roger Spitz

    发明人： Christophe Boisson ,  Vincent Monteil ,  Roger Spitz

    IPC分类号： C08F236/04

    CPC分类号： C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/14 ,  C08F210/16 ,  C08F236/04 ,  Y10S526/943 ,  C08F4/52 ,  C08F236/06

    摘要： A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described. This catalytic system includes: (i) an organometallic complex represented by the following formula: {[P(Cp)(Fl)Ln(X)(LX)}p  (1) where Ln represents a lanthanide atom to which is attached a ligand molecule comprising cyclopentadienyl Cp and fluorenyl Fl groups linked to one another by a bridge P of the formula MR1R2, M is an element from column IVa of Mendeleev's periodic table and R1 and R2 each represent alkyl groups of 1 to 20 carbon atoms or cycloalkyl or phenyl groups of 6 to 20 carbon atoms, X represents a halogen atom, L represents an optional complexing molecule, such as an ether, and optionally a substantially less complexing molecule, such as toluene, p is a natural integer greater than or equal to 1 and x is greater than or equal to 0, and (ii) a co-catalyst selected from alkylmagnesiums, alkyllithiums, alkylaluminums, Grignard reagents and mixtures of these constituents.

    摘要翻译： 一种可用于共聚二烯和至少一种单烯烃的催化体系，该催化体系的制备方法，使用所述催化体系制备共轭二烯和至少一种单烯烃的共聚物的方法，所述共聚物 被描述。 该催化体系包括：（i）由下式表示的有机金属络合物：{[P（Cp）（Fl）Ln（X）（LX）} p（1）其中Ln表示连接有配体的镧系元素 包含通过式MR1R2的桥P彼此连接的环戊二烯基Cp和芴基F1基团的分子，M是门多列夫元素周期表第IVa列的元素，R 1和R 2各自表示1-20个碳原子的烷基或环烷基或苯基 6至20个碳原子的基团，X表示卤素原子，L表示任选的络合分子，例如醚，以及任选的基本上较少络合的分子，例如甲苯，p是大于或等于1的天然整数， x大于或等于0，和（ii）选自烷基镁，烷基锂，烷基铝，格氏试剂和这些组分的混合物的助催化剂。