公开(公告)号：US09162215B2

公开(公告)日：2015-10-20

申请号：US14354126

申请日：2012-10-04

申请人： Biju M. Devassy ,  Albert C. Liu ,  Hwaili Soo

发明人： Biju M. Devassy ,  Albert C. Liu ,  Hwaili Soo

IPC分类号： C07C29/10 ,  C07C41/03 ,  B01J23/50 ,  B01J23/66 ,  B01J35/10 ,  B01J37/02 ,  B01J23/68 ,  C07D301/10 ,  C07C213/04 ,  C07D317/04

CPC分类号： B01J23/688 ,  B01J23/50 ,  B01J23/66 ,  B01J23/683 ,  B01J35/1009 ,  B01J35/1076 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0205 ,  C07C29/106 ,  C07C41/03 ,  C07C213/04 ,  C07D301/10 ,  C07D317/04

摘要： Methods are provided for producing epoxidation catalysts. The present methods are able to produce catalysts having the desired loading levels of catalytic species at a lower vacuum level (having a higher minimum residual pressure) than previously appreciated by the art, thereby providing equipment cost and time savings.

摘要翻译： 提供了制备环氧化催化剂的方法。 本发明的方法能够以比本领域先前所理解的更低的真空度（具有较高的最小残余压力）制备具有催化物质所需负载水平的催化剂，从而提供设备成本和时间节省。

公开(公告)号：US08845975B2

公开(公告)日：2014-09-30

申请号：US12974439

申请日：2010-12-21

申请人： William H. Henstock ,  Juliana G. Serafin ,  Albert C. Liu ,  Hwaili Soo ,  Yujun Liu ,  Manuk Colakyan ,  Sagar Petkar

发明人： William H. Henstock ,  Juliana G. Serafin ,  Albert C. Liu ,  Hwaili Soo ,  Yujun Liu ,  Manuk Colakyan ,  Sagar Petkar

IPC分类号： B01J8/00 ,  C07D301/03 ,  C07D301/10 ,  C07D301/36 ,  C07D301/32

CPC分类号： C07D301/10 ,  C07D301/32 ,  C07D301/36 ,  Y02P20/582

摘要： A plant and process for producing alkylene oxides to control the production of silver chloride on a high efficiency silver catalyst is disclosed and described. The process involves reacting an alkylene and an organic chloride gas phase promoter with oxygen over the high efficiency silver catalyst. The sulfur concentration in the alkylene oxide reactor feed is controlled to reduce the production of silver chloride which acts as a catalyst poison.

摘要翻译： 公开和描述了一种用于生产烯化氧以控制高效率银催化剂上的氯化银生产的设备和方法。 该方法包括在高效率银催化剂上使亚烷基和有机氯化物气相促进剂与氧反应。 控制环氧烷反应器进料中的硫浓度以减少作为催化剂毒物的氯化银的产生。

公开(公告)号：US20100267969A1

公开(公告)日：2010-10-21

申请号：US12760044

申请日：2010-04-14

申请人： Albert C. Liu ,  Hwaili Soo

发明人： Albert C. Liu ,  Hwaili Soo

IPC分类号： C07D317/36 ,  B01J27/055 ,  C07D301/10 ,  C07C29/00 ,  C07C213/04 ,  C07C41/03

CPC分类号： C07D301/10 ,  B01J21/04 ,  B01J23/6567 ,  B01J35/1009 ,  B01J35/1042 ,  B01J35/1076 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0213 ,  B01J37/26 ,  C07C29/00 ,  C07C41/03 ,  C07C213/04 ,  C07D317/36

摘要： The present invention provides rhenium-promoted epoxidation catalysts based upon shaped porous bodies comprising a minimized percentage of their total pore volume being present in pores having diameters of less than one micron, and a surface area of at least about 1.0 m2/g. Processes of making the catalysts and using them in epoxidation processes are also provided.

摘要翻译： 本发明提供了基于成形多孔体的铼促进的环氧化催化剂，其包含直径小于1微米，表面积至少约1.0m 2 / g的孔体积的最小百分比。 还提供了制备催化剂并将其用于环氧化方法中的方法。

公开(公告)号：US08765630B2

公开(公告)日：2014-07-01

申请号：US12713020

申请日：2010-02-25

申请人： Juliana G. Serafin ,  Albert C. Liu ,  Seyed R. Seyedmonir ,  Hwaili Soo ,  Thomas Szymanski

发明人： Juliana G. Serafin ,  Albert C. Liu ,  Seyed R. Seyedmonir ,  Hwaili Soo ,  Thomas Szymanski

IPC分类号： B01J21/00 ,  B01J23/58 ,  B01J23/56 ,  B01J23/02 ,  B01J23/04 ,  B01J23/00

CPC分类号： C07D301/10 ,  B01J21/066 ,  B01J23/50 ,  B01J23/66 ,  B01J23/686 ,  B01J23/688 ,  B01J35/1009 ,  B01J35/1042 ,  B01J35/1076 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0203

摘要： A catalyst for the manufacture of alkylene oxide, for example ethylene oxide, by the vapor-phase epoxidation of alkene containing impregnated silver and at least one efficiency-enhancing promoter on an inert, refractory solid support, said support incorporating a sufficient amount of zirconium component (present and remaining substantially as zirconium silicate) as to enhance at least one of catalyst activity, efficiency and stability as compared to a similar catalyst which does not contain the zirconium component.

摘要翻译： 用于通过气相环氧化含烯烃的浸渍的银和至少一种在惰性耐火固体载体上的效率增强促进剂来制备环氧烷烃例如环氧乙烷的催化剂，所述载体包含足量的锆组分 （存在并基本上保持为硅酸锆），与不含锆组分的类似催化剂相比，可提高催化剂活性，效率和稳定性中的至少一种。

公开(公告)号：US08513156B2

公开(公告)日：2013-08-20

申请号：US12846984

申请日：2010-07-30

申请人： Juliana G. Serafin ,  Seyed R. Seyedmonir ,  Albert C. Liu ,  Hwaili Soo ,  Thomas Szymanski

发明人： Juliana G. Serafin ,  Seyed R. Seyedmonir ,  Albert C. Liu ,  Hwaili Soo ,  Thomas Szymanski

IPC分类号： B01J23/48 ,  B01J23/50 ,  B01J23/00 ,  B01J23/08 ,  B01J21/00

CPC分类号： C07D301/10 ,  B01J21/066 ,  B01J23/50 ,  B01J23/66 ,  B01J23/686 ,  B01J23/688 ,  B01J35/1009 ,  B01J35/1042 ,  B01J35/1076 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0203

摘要： A catalyst for the manufacture of alkylene oxide, for example ethylene oxide, by the vapor-phase epoxidation of alkene containing impregnated silver and at least one efficiency-enhancing promoter on an inert, refractory solid support, said support incorporating a sufficient amount of zirconium component (present and remaining substantially as zirconium silicate) as to enhance at least one of catalyst activity, efficiency and stability as compared to a similar catalyst which does not contain the zirconium component.

摘要翻译： 用于通过气相环氧化含烯烃的浸渍的银和至少一种在惰性耐火固体载体上的效率增强促进剂来制备环氧烷烃例如环氧乙烷的催化剂，所述载体包含足量的锆组分 （存在并基本上保持为硅酸锆），与不含锆组分的类似催化剂相比，可提高催化剂活性，效率和稳定性中的至少一种。

公开(公告)号：US20190118167A1

公开(公告)日：2019-04-25

申请号：US16176786

申请日：2018-10-31

申请人： Manuel A.W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A.W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： B01J27/055 ,  B01J23/58 ,  C07C209/60 ,  B01J37/02 ,  B01J35/02 ,  B01J23/68 ,  C07D301/10 ,  B01J23/50 ,  B01J21/04 ,  B01J37/16

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

公开(公告)号：US20160082423A9

公开(公告)日：2016-03-24

申请号：US13624131

申请日：2012-09-21

申请人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： B01J27/055 ,  B01J23/68 ,  C07D301/10 ,  C07C29/10 ,  B01J35/02 ,  C07C41/02 ,  B01J37/02 ,  B01J23/66 ,  C07C209/16

CPC分类号： B01J27/055 ,  B01J21/04 ,  B01J23/50 ,  B01J23/58 ,  B01J23/688 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0244 ,  B01J37/16 ,  C07C209/60 ,  C07D301/10 ,  Y02P20/52

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

公开(公告)号：US20100173771A1

公开(公告)日：2010-07-08

申请号：US12713020

申请日：2010-02-25

申请人： Juliana G. Serafin ,  Albert C. Liu ,  Seyed R. Seyedmonir ,  Hwaili Soo ,  Thomas Szymanski

发明人： Juliana G. Serafin ,  Albert C. Liu ,  Seyed R. Seyedmonir ,  Hwaili Soo ,  Thomas Szymanski

IPC分类号： B01J21/06 ,  B01J21/04 ,  B01J23/50

CPC分类号： C07D301/10 ,  B01J21/066 ,  B01J23/50 ,  B01J23/66 ,  B01J23/686 ,  B01J23/688 ,  B01J35/1009 ,  B01J35/1042 ,  B01J35/1076 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0203

摘要： A catalyst for the manufacture of alkylene oxide, for example ethylene oxide, by the vapor-phase epoxidation of alkene containing impregnated silver and at least one efficiency-enhancing promoter on an inert, refractory solid support, said support incorporating a sufficient amount of zirconium component (present and remaining substantially as zirconium silicate) as to enhance at least one of catalyst activity, efficiency and stability as compared to a similar catalyst which does not contain the zirconium component.

摘要翻译： 用于通过气相环氧化含烯烃的浸渍的银和至少一种在惰性耐火固体载体上的效率增强促进剂来制备环氧烷烃例如环氧乙烷的催化剂，所述载体包含足量的锆组分 （存在并基本上保持为硅酸锆），与不含锆组分的类似催化剂相比，可提高催化剂活性，效率和稳定性中的至少一种。

公开(公告)号：US20140088316A1

公开(公告)日：2014-03-27

申请号：US13624131

申请日：2012-09-21

申请人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： B01J27/02 ,  B01J23/68 ,  C07C41/02 ,  C07C29/10 ,  C07C209/16 ,  B01J23/66 ,  C07D301/10

CPC分类号： B01J27/055 ,  B01J21/04 ,  B01J23/50 ,  B01J23/58 ,  B01J23/688 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0244 ,  B01J37/16 ,  C07C209/60 ,  C07D301/10 ,  Y02P20/52

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

摘要翻译： 负载型银催化剂及其在通过氧气或含氧气体直接氧化亚烷基的环氧乙烷生产方法中的用途，其中催化剂提供改进的稳定性和改善对反应器不稳定性的回弹性， 及时恢复，以大大预测催化剂活性和/或效率的水平。 在一些实施方案中，催化剂还表现出改进的活性。 能够以至少87％的选择性生产环氧乙烷的催化剂，同时在不高于235℃的温度下实现至少184kg / h / m3的工作速率，当在进料进料至 含有催化剂的反应器包括乙烯，氧气和二氧化碳，其中入口进料中二氧化碳的浓度大于或等于2摩尔％。

公开(公告)号：US08513444B2

公开(公告)日：2013-08-20

申请号：US12763477

申请日：2010-04-20

申请人： Michael Habenschuss ,  Hwaili Soo ,  Paul V. Hinman ,  Albert C. Liu

发明人： Michael Habenschuss ,  Hwaili Soo ,  Paul V. Hinman ,  Albert C. Liu

IPC分类号： C07D301/10 ,  C07D301/03

CPC分类号： C07D301/10 ,  C07D301/03 ,  C07D301/04 ,  C07D301/22 ,  G06F19/702 ,  Y02P20/52 ,  Y10T436/142222

摘要： A method of producing an alkylene oxide includes passing a reaction mixture comprising alkylene, oxygen and a gaseous chlorine-containing promoter species over a supported catalyst containing silver and a promoting amount of rhenium to undergo an epoxidation reaction at a first operating condition. The method further includes subsequently performing the epoxidation reaction at a preferred operating condition. The preferred operating condition is characterized by an efficiency of the epoxidation reaction toward the alkylene oxide where the efficiency is lower than that of a maximum efficiency achievable at an operating temperature corresponding to the preferred operating condition.