摘要:
A two-stage cascade polymerization process for the production of multimodal polyethylene film resins with improved bubble stability is provided. The process comprises polymerizing ethylene or a mixture of ethylene and a C4-8 α-olefin in two reactors arranged in series using a mixed single-site catalyst comprised of a bridged and a non-bridged indenoindolyl transition metal complex to form a multimodal polyethylene resin comprised of a lower molecular weight, higher density component and a higher molecular weight, lower density component.
摘要:
A two-stage cascade polymerization process for the production of multimodal polyethylene film resins with improved bubble stability is provided. The process comprises polymerizing ethylene or a mixture of ethylene and a C4-8 α-olefin in two reactors arranged in series using a mixed single-site catalyst comprised of a bridged and a non-bridged indenoindolyl transition metal complex to form a multimodal polyethylene resin comprised of a lower molecular weight, higher density component and a higher molecular weight, lower density component.
摘要:
A thick film and process to prepare polyethylene useful for the film are disclosed. Ethylene is polymerized in two reaction zones with a C6-C10 α-olefin in the presence of a catalyst system comprising an activator, a supported bridged zirconium complex, and a supported non-bridged zirconium complex. The process yields medium density to linear low density polyethylene having a melt index from 0.20 to 1.0 dg/min. Thick films from the polyethylene have a superior combination of high impact strength and high modulus.
摘要:
A thick film and process to prepare polyethylene useful for the film are disclosed. Ethylene is polymerized in two reaction zones with a C6-C10 α-olefin in the presence of a catalyst system comprising an activator, a supported bridged zirconium complex, and a supported non-bridged zirconium complex. The process yields medium density to linear low density polyethylene having a melt index from 0.20 to 1.0 dg/min. Thick films from the polyethylene have a superior combination of high impact strength and high modulus.
摘要:
Disclosed are polyethylene blends and films. The blend comprises from 1 to 99%, based on the weight of the blend, of a medium density polyethylene (MDPE) and from 1 to 99% a polyolefin selected from the group consisting of high density polyethylene (HDPE), linear low density polyethylene (LLDPE), low density polyethylene (LDPE), polypropylene, polybutene, and mixtures thereof. The MDPE is made by high pressure, free radical polymerization and has a density within the range of greater than 0.928 to 0.940 g/cm3 and an MI2 within the range of 0.1 to 1 dg/min. The shrink films made from the blend have strong contraction force and low creep.
摘要:
A multilayer film having as one surface layer thereof a support layer containing a thermoplastic resin able to withstand temperatures up to 200 degrees C. without softening and the other surface layer an adhesive layer containing a thermoplastic resin having a melting point ranging from about 100 to 200 degrees C. Optionally, a tie layer may be employed between the support layer and the adhesive layer. The multilayer film is useful as a protective carrier sheet for a cladding metal foil used in the production of printed circuit boards. The carrier sheet provides temporary, peelable surface protection for the cladding metal foil preventing contamination and physical damage to the foil both before and during printed circuit board formation. Adhesion of the carrier sheet to the cladding metal foil, measured using a 180 degree peel test is less than 0.4 pounds/in-width and greater than 0.005 pounds/in-width, and preferably less than 0.1 pounds/in-width and greater than 0.01 pounds/in-width.
摘要:
Disclosed is a method for improving the barrier properties of polyethylene films The method comprises mixing a substantially linear, high density polyethylene with a nucleating agent and converting the mixture into a film The film made by the method of the invention has at least a 15% improvement on the water vapor barrier property and/or in the oxygen barrier property compared with the control film made from the same substantially linear, high density polyethylene but does not contain the nucleating agent.
摘要:
A blend comprising a high molecular weight, medium density polyethylene (HMW, MDPE) and a linear low density polyethylene (LLDPE) is disclosed. The blend comprises from about 20 wt % to about 80 wt % of HMW MDPE. The HMW MDPE has a density from about 0.92 to about 0.944 g/cc, a melt index MI2 from about 0.01 to about 0.5 dg/min, and a melt flow ratio MFR from about 50 to about 300. The blend also comprises about 20 wt % to about 80 wt % of LLDPE. The LLDPE has a density within the range of about 0.90 to about 0.925 g/cc and an MI2 within the range of about 0.50 to about 50 dg/min. The blend provides films with significantly improved toughness and tear strength compared to MDPE or HDPE, and high modulus compared to LLDPE.
摘要:
Disclosed is a method for improving the barrier properties of polyethylene films. The method comprises mixing a substantially linear, high density polyethylene with a nucleating agent and converting the mixture into a film. The film made by the method of the invention has at least a 15% improvement on the water vapor barrier property and/or in the oxygen barrier property compared with the control film made from the same substantially linear, high density polyethylene but does not contain the nucleating agent.
摘要:
A polyolefin composition is disclosed. The composition comprises a single-site linear low density polyethylene (mLLDPE) and an elastoplastic polypropylene. The elastoplastic polypropylene is present in an amount sufficient to improve the processability and physical property of the mLLDPE. The composition preferably comprises from 70 wt % to 99 wt % of mLLDPE and from 1 wt % to 30 wt % of the elastoplastic polypropylene. The polyolefin composition of the invention exhibits improved bubble stability in the blown film extrusion compared to the mLLDPE and improved film properties such as tear strength and modulus compared to the traditional blend of mLLDPE and low density polyethylene.