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1.发明授权Process for the use of magnesium-aluminum-phosphorus-silicon-oxide molecular sieve compositions 失效使用镁 - 铝 - 磷 - 氧化硅分子筛组合物的方法
公开(公告)号：US4882038A
公开(公告)日：1989-11-21
申请号：US155696
申请日：1988-02-16
IPC分类号： B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G47/02
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having a three-dimensional microporous framework structures of MgO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of magnesium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed.
摘要翻译： 公开了具有MgO 2，AlO 2，SiO 2和PO 2四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（MgwAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（MgwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的镁，铝，磷和硅的摩尔分数。 公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4822478A
公开(公告)日：1989-04-18
申请号：US46453
申请日：1987-05-06
IPC分类号： B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/04 , C10G47/04
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： An novel class of iron-aluminum-phosphorus-silicon-oxide molecular sieves is disclosed which contain as framework constituents FeO.sub.2.sup.-, and/or FeO.sub.2.sup.-2, AlO.sub.2.sup.-, PO.sub.2.sup.+ and SiO.sub.2 tetrahedral oxide units. These compositions are prepared hydrothermally, preferably using organic templating agents and are suitably employed as adsorbents and catalysts.
摘要翻译： 公开了一种新型的铁 - 铝 - 磷 - 氧化硅分子筛，其包含作为骨架组分FeO 2 - 和/或FeO 2 -2，AlO 2 - ，PO 2 +和SiO 2四面体氧化物单元。 这些组合物水热制备，优选使用有机模板剂，适合用作吸附剂和催化剂。
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公开(公告)号：US4985151A
公开(公告)日：1991-01-15
申请号：US409531
申请日：1989-09-19
申请人： Brent M. T. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
发明人： Brent M. T. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S95/902
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of elements(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有ELO2，SiO2和PO2骨架氧化物单元的三维微孔骨架结构的结晶分子筛。 分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（ELwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（ELwAlxPySiz）O 2存在的“R”摩尔量; “EL”表示能够形成骨架氧化物单元的至少一种元素; 和“w”，“x”，“y”和“z”分别表示作为骨架氧化物存在的元素“EL”，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4973785A
公开(公告)日：1990-11-27
申请号：US182738
申请日：1988-04-18
申请人： Brent M. T. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
发明人： Brent M. T. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有ELO2，AlO2，SiO2和PO2骨架氧化物单元的三维微孔骨架结构的结晶分子筛。 分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（ELwAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（ELwAlxPySiz）O 2存在的“R”摩尔量; “EL”表示能够形成骨架氧化物单元的至少一种元素; 和“w”，“x”，“y”和“z”分别表示作为骨架氧化物存在的元素“EL”，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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5.发明授权
公开(公告)号：US4935216A
公开(公告)日：1990-06-19
申请号：US600170
申请日：1984-04-13
IPC分类号： C07C2/66 , B01J20/18 , B01J29/00 , B01J29/85 , C01B37/08 , C07C1/00 , C07C2/12 , C07C2/54 , C07C4/18 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C07C6/12 , C07C9/00 , C07C15/08 , C07C67/00
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/84 , Y10S423/30
摘要： Crystalline molecular sieves having three-dimentional microporous framework structures of ZnO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Zn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Zn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of zinc, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有ZnO 2，AlO 2，SiO 2和PO 2四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（ZnwAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（ZnwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示以四面体氧化物存在的锌，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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6.发明授权
公开(公告)号：US4973460A
公开(公告)日：1990-11-27
申请号：US218494
申请日：1988-07-06
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of LiO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of lithium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有LiO 2，AlO 2，PO 2和SiO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（LiwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（LiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锂，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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7.发明授权
公开(公告)号：US4917876A
公开(公告)日：1990-04-17
申请号：US195474
申请日：1988-05-17
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of FeO.sub.2, TiO.sub.2, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "M" represents iron and titanium, "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represnt the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有FeO 2，TiO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “M”表示铁和钛，“m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4759919A
公开(公告)日：1988-07-26
申请号：US830756
申请日：1986-02-19
CPC分类号： B01J29/84 , C01B39/00 , C07C2527/173 , C07C2529/84
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of CrO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Cr.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Cr.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of chromium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CrO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（CrxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CrxAlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的铬，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4952384A
公开(公告)日：1990-08-28
申请号：US197407
申请日：1988-05-20
申请人： Brent M. T. Lok , Bonita K. Marcus , Celeste A. Messina , Stephen T. Wilson , Edith M. Flanigen
发明人： Brent M. T. Lok , Bonita K. Marcus , Celeste A. Messina , Stephen T. Wilson , Edith M. Flanigen
IPC分类号： B01J29/84 , B01J29/85 , C01B25/45 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/84 , B01J29/85 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C01B39/00 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of MO.sub.2.sup.n, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR : (M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "M" represents iron and/or titanium, and at least one of cobalt, magnesium, manganese and zinc; "n" is O, -1 or -2; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有MO2n，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “M”表示铁和/或钛，以及钴，镁，锰和锌中的至少一种; “n”为O，-1或-2; “m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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10.发明授权Hydrocarbon conversion process using titanium-aluminum-phosphorus-silicon-oxide molecular sieves as catalyst 失效使用钛 - 铝 - 磷 - 氧化硅分子筛作为催化剂的烃转化过程
公开(公告)号：US4880520A
公开(公告)日：1989-11-14
申请号：US260689
申请日：1988-10-21
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of TiO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Ti.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Ti.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of titanium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有TiO 2，AlO 2，SiO 2和PO 2四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（TiwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（TiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的钛，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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