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公开(公告)号：US4343721A
公开(公告)日：1982-08-10
申请号：US207848
申请日：1980-11-18
CPC分类号： C08F10/00 , Y10S526/906
摘要： A process for the preparation of an olefin polymerization catalyst component which comprises contacting a solid composition obtained by combining a magnesium halide, an electron donor and a tetravalent titanium compound, this composition being substantially free from aluminum compounds, with a liquid medium comprising a halide of B, Al, Ga, In, Tl, Sn or Sb, these elements being present in their highest valency state or a halide of tetravalent Te, and removing from the catalyst component substantially all metal halide originating from the liquid medium as by washing the catalyst component with a hydrocarbon or halohydrocarbon liquid.
摘要翻译： 一种制备烯烃聚合催化剂组分的方法，该方法包括将通过将卤化镁，电子给体和四价钛化合物组合而获得的固体组合物与该液体介质相接触，该组合物基本上不含铝化合物， B，Al，Ga，In，Tl，Sn或Sb，这些元素以其最高价态存在或四价Te的卤化物，并且通过洗涤催化剂从催化剂组分基本上除去源自液体介质的所有金属卤化物 组分与烃或卤代烃液体。
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公开(公告)号：US4419501A
公开(公告)日：1983-12-06
申请号：US345900
申请日：1982-02-04
CPC分类号： C08F10/00 , Y10S526/906
摘要： A process for the preparation of an olefin polymerization catalyst component which comprises contacting a solid composition obtained by combining a magnesium halide, an electron donor and a tetravalent titanium compound, this composition being substantially free from aluminum compounds, with a liquid medium comprising a halide of B, Al, Ga, In, Tl, Sn or Sb, these elements being present in their highest valency state or a halide of tetravalent Te, and removing from the catalyst component substantially all metal halide originating from the liquid medium as by washing the catalyst component with a hydrocarbon or halohydrocarbon liquid.
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公开(公告)号：US4943670A
公开(公告)日：1990-07-24
申请号：US441124
申请日：1989-11-22
IPC分类号： C07C2/86
CPC分类号： C07C2/86 , C07C2531/04 , C07C2531/24
摘要： A process for the preparation of a compound of general formula ##STR1## in which R.sup.1 represents a hydrogen atom or a methyl group, one of R.sup.2 and R.sup.3 represents a hydrogen atom and the other of R.sup.2 and R.sup.3 is the same as R.sup.1, which comprises reacting a compound of the general formulaR.sup.1 CH.dbd.C.dbd.CH.sub.2 (II)with a salt of formic acid in the presence of a catalyst system comprising a palladium salt and a phosphorus compound of general formulaP(OX).sub.n (X).sub.3-n (III)in which n is 0,1,2 or 3 and each X independently represents an alkyl, alkenyl, aryl, aralkyl, alkaryl or cycloalkyl group, and recovering the desired compound of formula (I).
摘要翻译： 制备通式为（I）的化合物的方法，其中R 1表示氢原子或甲基，R 2和R 3之一表示氢原子，R 2和R 3中的另一个与R 1相同 其包括在包含钯盐和通式P（OX）n（X））的磷化合物的催化剂体系的存在下使通式为R 1 CH = C = CH 2（II）的化合物与甲酸盐反应， 3-n（III），其中n为0,1,2或3，并且每个X独立地表示烷基，烯基，芳基，芳烷基，烷芳基或环烷基，并回收所需的式（I）化合物。
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公开(公告)号：US20130289324A1
公开(公告)日：2013-10-31
申请号：US13996425
申请日：2011-12-27
IPC分类号： C10G3/00
CPC分类号： C10G3/49 , B01J29/046 , B01J29/084 , B01J29/085 , B01J29/405 , B01J37/0201 , B01J2029/062 , C10G3/42 , C10G3/44 , C10G3/54 , C10G3/55 , C10G2300/1014 , C10G2300/104 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/4025 , C10G2400/02 , C10G2400/30 , C10L1/06 , Y02P30/20
摘要： Renewable oils are converted to aromatics, by contact with a catalytically-active form of gallium, for use in the petrochemical industry and/or for fuel blending components or additives. The renewable oil(s) feature high oxygen content, high H/C mole ratios, and high fatty acid or fatty acid ester content prior to heating and contact with the catalyst. The catalyst may be, for example, a gallium-doped version of one or more zeolite-alumina matrix catalysts with pore sizes having 10 oxygen atoms in the pore mouth, such as ZSM-5, ZSM-11, ZSM-23, MCM-70, SSZ-44, SSZ-58, SSZ-35, and ZSM-22. Aromatics-production from the renewable oils is enhanced at higher gallium-cation levels, with the preferred level being about 1.0 Ga/framework-Al. While various renewable oils, or “bio-oils,” may be used, algae oil has exhibited very high BTEX yields over the gallium cation catalyst, under conditions at or near 1 atm and approximately 400 degrees C.
摘要翻译： 可再生油通过与催化活性形式的镓接触而转化为芳族化合物，用于石化工业和/或用于燃料调配组分或添加剂。 在加热和与催化剂接触之前，可再生油具有高氧含量，高H / C摩尔比和高脂肪酸或脂肪酸酯含量。 催化剂可以是例如孔隙中具有10个氧原子的一种或多种沸石 - 氧化铝基质催化剂的镓掺杂形式，例如ZSM-5，ZSM-11，ZSM-23，MCM- 70，SSZ-44，SSZ-58，SSZ-35和ZSM-22。 在更高的镓阳离子水平下，来自可再生油的芳烃生产得到增强，优选的水平为约1.0Ga /框架-Al。 尽管可以使用各种可再生油或“生物油”，但是在等于或接近1atm和约400℃的条件下，藻油在镓阳离子催化剂上表现出非常高的BTEX产率。
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公开(公告)号：US20080282606A1
公开(公告)日：2008-11-20
申请号：US12103294
申请日：2008-04-15
申请人： John P. Plaza , Brian L. Goodall
发明人： John P. Plaza , Brian L. Goodall
摘要： In embodiments of the present invention, systems for producing a biodiesel product from multiple feedstocks may include a biodiesel reactor, a decanter, a flash evaporator and a distillation column. In other embodiments of the present invention, a process for producing a biodiesel comprises distilling a biodiesel reaction product to remove tocopherols and sterol glucosides and, optionally, adding biodiesel stabilizers to the resultant biodiesel to enhance thermal stability. The components of the system are interrelated so that parameters may be regulated to allow production of a custom biodiesel product.
摘要翻译： 在本发明的实施方案中，用于从多种原料生产生物柴油产品的系统可包括生物柴油反应器，滗析器，闪蒸蒸发器和蒸馏塔。 在本发明的其它实施方案中，生产生物柴油的方法包括蒸馏生物柴油反应产物以除去生育酚和固醇糖苷，以及任选地将生物柴油稳定剂加入到所得生物柴油中以增强热稳定性。 系统的组件是相互关联的，因此可以调节参数以允许生产定制的生物柴油产品。
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公开(公告)号：US07022790B2
公开(公告)日：2006-04-04
申请号：US10465511
申请日：2003-06-19
申请人： Edmund Elce , Takashi Hirano , Jeffrey C. Krotine, Jr. , Larry F. Rhodes , Brian L. Goodall , SaiKumar Jayaraman , W. Chris McDougall , Shenliang Sun
发明人： Edmund Elce , Takashi Hirano , Jeffrey C. Krotine, Jr. , Larry F. Rhodes , Brian L. Goodall , SaiKumar Jayaraman , W. Chris McDougall , Shenliang Sun
IPC分类号： C08F10/00
CPC分类号： G03F7/0382 , C08G59/3218 , C08G61/02 , C08G61/06
摘要： A copolymer composition including a copolymer having repeat units of structural formula I: where X is selected from —CH2—, —CH2—CH2— and O; m is an integer from 0 to 5; and each occurrence of R1–R4 are independently selected from H; C1 to C25 linear, branched, and cyclic alkyl, aryl, aralkyl, alkaryl, alkenyl and alkynyl that can include one or more hetero atoms selected from O, N, and Si; a group that contains an epoxy functionality; —(CH2)nC(O)OR5; —(CH2)nC(O)OR6; —(CH2)nOR6; —(CH2)nOC(O)R6; —(CH2)nC(O)R6; —(CH2)nOC(O)OR6; and any combination of two of R1, R2, R3, and R4 linked together by a linking group. A portion of the repeat units having structural formula I contain at least one epoxy functional pendant group. The copolymer composition can be included with a material that photonically forms a catalyst in a photodefinable dielectric composition, which can be used to form a photodefinable layer on a substrate.
摘要翻译： 一种共聚物组合物，其包含具有结构式I的重复单元的共聚物：其中X选自-CH 2 - ， - CH 2 -CH 2 > - 和O; m是0至5的整数; 并且每次出现的R 1 -R 4独立地选自H; C 1至C 25直链，支链和环状的烷基，芳基，芳烷基，烷芳基，烯基和炔基，其可以包括一个或多个选自O，N， 和Si; 含有环氧官能团的基团; - （CH 2）2 C（O）OR 5; - （CH 2）2 C（O）OR 6; - （CH 2 2）n - 或 - 6 - - （CH 2）n OC（O）R 6; - （CH 2 CH 2）n C（O）R 6; - （CH 2）n OC（O）OR 6; 并且R 1，R 2，R 3，R 4和R 4中的两个的任何组合通过 连接组。 具有结构式I的重复单元的一部分含有至少一个环氧官能侧基。 该共聚物组合物可以包含在可光致定影的电介质组合物中光子形成催化剂的材料，该组合物可用于在基底上形成光可定义层。
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公开(公告)号：US06525153B1
公开(公告)日：2003-02-25
申请号：US09521351
申请日：2000-03-09
申请人： Saikumar Jayaraman , Brian L. Goodall , Richard Vicari , John-Henry Lipian , Robert David Allen , Juliann Opitz , Thomas I. Wallow
发明人： Saikumar Jayaraman , Brian L. Goodall , Richard Vicari , John-Henry Lipian , Robert David Allen , Juliann Opitz , Thomas I. Wallow
IPC分类号： C08F1000
CPC分类号： C08G61/122 , C08G61/08 , G03F7/0045 , G03F7/039 , G03F7/0395
摘要： Polymers comprising polycyclic repeating units containing pendant anhydride moieties are disclosed. The polymer can be polymerized from polycycloolefins containing pendant anhydride moieties in the presence of a nickel containing single component catalyst. In optional embodiments the polycycloolefin monomer containing the pendant anhydride functionality can be copolymerized with other polycycloolefin monomers that contain pendant functional groups to yield random copolymer products.
摘要翻译： 公开了包含含有侧链酸酐部分的多环重复单元的聚合物。 聚合物可以在含镍单组分催化剂的存在下由含有侧链酸酐部分的聚环烯烃聚合。 在任选的实施方案中，含有侧链官能团的聚环烯烃单体可与含有侧链官能团的其它聚环烯烃单体共聚以产生无规共聚物产物。
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8.发明授权Mold addition polymerization of norbornene-type monomers using group 10 metal complexes 有权使用第10族金属络合物对降冰片烯型单体进行加模聚合公开(公告)号：US06350832B1
公开(公告)日：2002-02-26
申请号：US09456780
申请日：1999-12-08
IPC分类号： C08F480
CPC分类号： C08F232/08 , C08F32/00 , C08F232/00
摘要： A catalyst system and a process for the bulk addition polymerization or of polycyclic olefins, such as norbornene, methylnorbornene, ethylnorbornene, butylnorbornene or hexylnorbornene, 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonapthalene, 5,5′-(1,2-ethanediyl)bisbicyclo[2.2.1]hept-2-ene, and 1,4,4a,4b,5,8,8a,8b-octahydro-1,4:5,8-dimethanobiphenylene are disclosed. The catalyst includes an organonickel or organopalladium transition metal procatalyst and an activator compound. Polymerization can be carried out in a reaction injection molding process to yield thermoplastic and thermoset molded polymeric articles possessing high glass transition temperatures.
摘要翻译： 催化剂体系和本体加成聚合方法或降冰片烯，甲基降冰片烯，乙基降冰片烯，丁基降冰片烯或己基降冰片烯等多环烯烃，1,2,3,4,4a，5,8,8a-八氢-1,4： 5,8-二甲基萘，5,5' - （1,2-乙二基）双双环[2.2.1]庚-2-烯和1,4,4a，4b，5,8,8a，8b-八氢-1 ，4：5,8-二甲基亚二苯基。 催化剂包括有机金属或有机钯过渡金属前催化剂和活化剂化合物。 可以在反应注射成型工艺中进行聚合以产生具有高玻璃化转变温度的热塑性和热固性模塑聚合物制品。
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9.发明授权Aldehyde-telechelic polyisobutylenes, catalytic method for preparing the same with high conversion and selectivity, and block copolymers made therefrom 失效醛 - 遥爪聚异丁烯，具有高转化率和选择性的催化方法，以及由其制备的嵌段共聚物
公开(公告)号：US5442015A
公开(公告)日：1995-08-15
申请号：US227071
申请日：1994-04-13
CPC分类号： C08F8/00 , C08F110/10 , C08F8/26 , C08F2810/30 , C08F2810/40
摘要： Aldehyde-telechelic polyisobutylenes free of other end groups such as alcohols, olefins, etc., are made by the hydroformylation of polyisobutylene having one or more olefinic end groups in the presence of a rhodium catalyst in combination with an organic phosphorus ligand. Very high conversions of olefin to aldehyde are obtained. Depending upon the number of aldehyde end groups per macromolecule, the telechelic polyisobutylene polymers can be utilized as precursors to form various types of block copolymers, e.g., AB, ABA, or radial block copolymers, with other polymers such as polyurethanes, polyesters, polyamines, and the like.
摘要翻译： 通过在铑催化剂与有机磷配体的组合的存在下，具有一个或多个烯属端基的聚异丁烯的加氢甲酰基化来制备不含其它端基的醇 - 遥爪聚异丁烯，例如醇，烯烃等。 获得非常高的烯烃与醛的转化率。 根据每个大分子的醛端基的数目，遥爪聚异丁烯聚合物可以用作前体以形成各种类型的嵌段共聚物，例如AB，ABA或径向嵌段共聚物，与其它聚合物如聚氨酯，聚酯，聚胺， 等等。
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公开(公告)号：US4600757A
公开(公告)日：1986-07-15
申请号：US725196
申请日：1985-04-18
申请人： John C. Chadwick , Brian L. Goodall
发明人： John C. Chadwick , Brian L. Goodall
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F4/655 , C08F36/00 , C08F136/00 , C08F136/08 , C08F236/00 , C08F36/08
CPC分类号： C08F136/08
摘要： A process for the preparation of polyisoprene by polymerizing isoprene in the presence of a beta-TiCl.sub.3 containing catalyst is disclosed thereby an activator is prepared by reacting a hydrocarbylaluminum compound and a hydroxy-aromatic compound, having at both ortho-places with respect to the hydroxy-group a secondary or tertiary alkyl-group.
摘要翻译： 公开了通过在含有β-TiCl 3的催化剂存在下聚合异戊二烯来制备聚异戊二烯的方法，由此通过使烃基铝化合物和羟基 - 芳族化合物在两个邻位上相对于羟基 - 组合仲或叔烷基。
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