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公开(公告)号：US06596157B2
公开(公告)日：2003-07-22
申请号：US09815686
申请日：2001-03-23
申请人： Brij Gupta , John P. Greeley , Thomas R. Halbert
发明人： Brij Gupta , John P. Greeley , Thomas R. Halbert
IPC分类号： C10G6514
CPC分类号： C10G65/16 , C10G45/00 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2400/02
摘要： The invention relates to a method and dual reactor system for hydrotreating a wide cut cat naphtha stream comprising heavy cat naphtha (HCN) and intermediate cat naphtha (ICN). Accordingly, a HCN fraction is hydrotreated under non-selective hydrotreating conditions and an ICN fraction is hydrotreated under selective hydrotreating conditions. The hydrotreated HCN and ICN effluents may be conducted to heat exchangers to pre-heat the ICN feed, obviating the need for a furnace.
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公开(公告)号：US20090166263A1
公开(公告)日：2009-07-02
申请号：US12006160
申请日：2007-12-31
IPC分类号： C10G45/04
CPC分类号： C10G45/08 , C10G2400/02
摘要： A low hydrogen partial pressure process for desulfurizing naphtha in the presence of a hydrodesulfurization catalyst which catalyst is selective for suppressing hydrogenation of olefins and in the presence. This invention also relates to the use of optimum metals loading for achieving a high level of hydrodesulfurization with a low level of olefin saturation.
摘要翻译： 在加氢脱硫催化剂存在下，用于脱氢石脑油的低氢分压方法，该催化剂选择性地抑制烯烃的氢化和存在。 本发明还涉及使用最佳金属负载来实现具有低水平烯烃饱和度的高水平加氢脱硫。
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公开(公告)号：US07244352B2
公开(公告)日：2007-07-17
申请号：US10359860
申请日：2003-02-07
申请人： Thomas R. Halbert , Craig A. McKnight , John P. Greeley , Bruce R. Cook , Garland B. Brignac , Mark A. Greaney , Robert C. Welch
发明人： Thomas R. Halbert , Craig A. McKnight , John P. Greeley , Bruce R. Cook , Garland B. Brignac , Mark A. Greaney , Robert C. Welch
CPC分类号： C10G67/0418 , C10G67/12 , C10L1/02
摘要： A process for producing a naphtha having a decreased amount of sulfur by selective hydroprocessing a petroleum feedstream comprising cracked naphtha to reduce its sulfur content with minimum loss of octane. The reduced sulfur naphtha stream contains mercaptan sulfur reversion products that are removed preferably by use of an aqueous base solution containing a catalytically effective amount of a phase transfer catalyst.
摘要翻译： 通过选择性加氢处理包含裂化石脑油的石油原料流来制造具有减少硫含量的石脑油的方法，以最小的辛烷值损失降低其硫含量。 还原硫石脑油流含有硫醇硫还原产物，其优选通过使用含有催化有效量的相转移催化剂的碱性水溶液来除去。
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4.发明授权公开(公告)号：US06231753B1
公开(公告)日：2001-05-15
申请号：US09448961
申请日：1999-11-24
申请人： Craig A. McKnight , Thomas R. Halbert , John P. Greeley , Garland B. Brignac , Richard A. Demmin , William E. Winter, Jr. , Bruce R. Cook
发明人： Craig A. McKnight , Thomas R. Halbert , John P. Greeley , Garland B. Brignac , Richard A. Demmin , William E. Winter, Jr. , Bruce R. Cook
IPC分类号： C10G45104
CPC分类号： C10G45/08 , B01J23/85 , B01J23/882 , B01J35/0006 , C10G65/04 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2400/02
摘要： Selective and deep desulfurization of a high sulfur content mogas naphtha, with reduced product mercaptans and olefin loss, is achieved by a two stage, vapor phase hydrodesulfurization process with interstage separation of at least 80 vol. % of the H2S formed in the first stage from the first stage, partially desulfurized naphtha vapor effluent fed into the second stage. At least 70 wt. % of the sulfur is removed in the first stage and at least 80 wt. % of the remaining sulfur is removed in the second stage, to achieve a total at least 95 wt. % feed desulfurization, with no more than a 60 vol. % feed olefin loss. The second stage temperature and space velocity are preferably greater than in the first. The hydrodesulfurization catalyst preferably contains a low metal loading of Co and Mo metal catalytic components on an alumina support.
摘要翻译： 通过两级气相加氢脱硫工艺实现了具有降低产物硫醇和烯烃损失的高硫含量的沼气石脑油的选择性和深度脱硫，其中级间分离至少为80体积％。 在第一阶段的第一阶段形成的H2S的％，部分脱硫的石脑油蒸汽流出物进料到第二阶段。 至少70wt。 在第一阶段中除去硫的百分比，并且至少80wt。 在第二阶段除去剩余硫的％，以达到总计至少95wt。 ％进料脱硫，不超过60体积。 ％进料烯烃损失。 第二级温度和空间速度优选大于第一级。 加氢脱硫催化剂优选在氧化铝载体上含有Co和Mo金属催化组分的低金属负载量。
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5.发明授权Multi-stage hydrodesulfurization of cracked naphtha streams with a stacked bed reactor 有权用层叠反应器对裂化石脑油流进行多级加氢脱硫公开(公告)号：US07297251B2
公开(公告)日：2007-11-20
申请号：US10424332
申请日：2003-04-28
申请人： Edward S. Ellis , Richard A. Demmin , John P. Greeley , Gary B. McVicker , Bruce R. Cook , Garland B. Brignac , Thomas R. Halbert
发明人： Edward S. Ellis , Richard A. Demmin , John P. Greeley , Gary B. McVicker , Bruce R. Cook , Garland B. Brignac , Thomas R. Halbert
IPC分类号： C10G45/04
CPC分类号： B01J35/10 , B01J21/04 , B01J23/85 , B01J23/882 , B01J35/0006 , B01J35/1061 , C10G2400/02
摘要： A process for the selective hydrodesulfurization of naphtha streams containing a substantial amount of olefins and organically bound sulfur. The naphtha stream is selectively hydrodesulfurized by passing it through a first reaction zone containing a bed of a first hydrodesulfurization catalyst, then passing the resulting product stream through a second reaction zone containing a bed of a second hydrodesulfurization catalyst, which second hydrodesulfurization catalyst contains a lower level of catalytic metals than the first hydrodesulfurization catalyst.
摘要翻译： 用于选择性加氢脱硫含有大量烯烃和有机结合硫的石脑油流的方法。 通过使该石脑油流过含有第一加氢脱硫催化剂床的第一反应区，然后将所得产物流通过含有第二加氢脱硫催化剂床的第二反应区，该第二反应区含有较低的 催化金属的含量高于第一加氢脱硫催化剂。
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公开(公告)号：US07220352B2
公开(公告)日：2007-05-22
申请号：US10372864
申请日：2003-02-24
IPC分类号： G10G45/02
CPC分类号： C10G45/02 , C10G2400/02
摘要： A process for the selective hydrodesulfurization of naphtha streams containing sulfur and olefins. A substantially olefins-free naphtha stream is blended with an olefins/sulfur-containing naphtha stream and hydrodesulfurized resulting in the substantial removal of sulfur without excessive olefin saturation.
摘要翻译： 含有硫和烯烃的石脑油流的选择性加氢脱硫的方法。 将基本上不含烯烃的石脑油流与烯烃/含硫石脑油流混合并进行加氢脱硫，从而实质上除去硫而没有过度的烯烃饱和。
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公开(公告)号：US07422679B2
公开(公告)日：2008-09-09
申请号：US10427480
申请日：2003-05-01
申请人： Edward S. Ellis , Thomas R. Halbert , Garland B. Brignac , John P. Greeley , Richard A. Demmin , Theresa A. Lalain
发明人： Edward S. Ellis , Thomas R. Halbert , Garland B. Brignac , John P. Greeley , Richard A. Demmin , Theresa A. Lalain
IPC分类号： C10G45/04
CPC分类号： C10G45/02 , B01J23/882 , B01J27/0515 , B01J37/20 , C10G2400/02
摘要： Naphtha hydrodesulfurization selectivity is increased by reducing the amount of COX (CO plus ½ CO2) in the hydrodesulfurization reaction zone to less than 100 vppm. While this is useful for non-selective hydrodesulfurization, it is particularly useful for selectively desulfurizing an olefin-containing naphtha without octane loss due to olefin saturation by hydrogenation. The COX reduction is achieved by removing COX from the treat gas before it is passed into the reaction zone.
摘要翻译： 通过将加氢脱硫反应区中的CO 2 CO 2（CO + 1/2 CO 2）的量减少到小于100vppm来增加石脑油加氢脱硫选择性。 虽然这对于非选择性加氢脱硫是有用的，但是通过氢化由于烯烃饱和而没有辛烷值损失选择性脱硫含烯烃的石脑油特别有用。 在处理气体进入反应区之前，通过从处理气体中除去CO x X而实现CO 2还原。
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公开(公告)号：US08894844B2
公开(公告)日：2014-11-25
申请号：US13424683
申请日：2012-03-20
CPC分类号： C10G65/04 , B01J21/08 , B01J23/882 , B01J35/1042 , B01J35/1047 , B01J35/1061 , C10G45/08 , C10G65/06 , C10G69/04 , C10G2300/1044 , C10G2300/202
摘要： The invention includes a hydrotreating method for increased CO content comprising: contacting an olefinic naphtha feedstream with a hydrogen-containing treat gas stream and a hydrotreating catalyst in a reactor under hydrotreating conditions sufficient to at least partially hydrodesulfurize and/or hydrodenitrogenate the feedstream, wherein the feedstream and the hydrogen-containing treat gas stream collectively have greater than 10 vppm CO content and/or wherein the reactor inlet sees an average CO concentration of greater than 10 vppm, wherein the hydrotreating catalyst comprises a catalyst having cobalt and molybdenum disposed on a silica-based support, and wherein the hydrotreating conditions are selected such that the catalyst has a relative HDS activity at least 10% greater than an identical catalyst under identical conditions except for a collective CO content of the feedstream and/or hydrogen-containing treat gas being
摘要翻译： 本发明包括用于增加CO含量的加氢处理方法，其包括：使烯烃石脑油进料流与含氢处理气流和加氢处理催化剂在反应器中在足以至少部分加氢脱硫和/或加氢脱氮进料流的加氢处理条件下接触，其中 原料流和含氢处理气体流共同地具有大于10vppm的CO含量和/或其中反应器入口看到平均CO浓度大于10vppm，其中加氢处理催化剂包括设置在二氧化硅上的钴和钼的催化剂 并且其中选择加氢处理条件使得催化剂在相同条件下具有比相同催化剂大至少10％的相对HDS活性，除了进料流和/或含氢处理气体的总CO含量为 <10 vppm和/或反应器入口CO含量<10 vppm。
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公开(公告)号：US20120241360A1
公开(公告)日：2012-09-27
申请号：US13424683
申请日：2012-03-20
CPC分类号： C10G65/04 , B01J21/08 , B01J23/882 , B01J35/1042 , B01J35/1047 , B01J35/1061 , C10G45/08 , C10G65/06 , C10G69/04 , C10G2300/1044 , C10G2300/202
摘要： The invention includes a hydrotreating method for increased CO content comprising: contacting an olefinic naphtha feedstream with a hydrogen-containing treat gas stream and a hydrotreating catalyst in a reactor under hydrotreating conditions sufficient to at least partially hydrodesulfurize and/or hydrodenitrogenate the feedstream, wherein the feedstream and the hydrogen-containing treat gas stream collectively have greater than 10 vppm CO content and/or wherein the reactor inlet sees an average CO concentration of greater than 10 vppm, wherein the hydrotreating catalyst comprises a catalyst having cobalt and molybdenum disposed on a silica-based support, and wherein the hydrotreating conditions are selected such that the catalyst has a relative HDS activity at least 10% greater than an identical catalyst under identical conditions except for a collective CO content of the feedstream and/or hydrogen-containing treat gas being
摘要翻译： 本发明包括用于增加CO含量的加氢处理方法，其包括：使烯烃石脑油进料流与含氢处理气流和加氢处理催化剂在反应器中在足以至少部分加氢脱硫和/或加氢脱氮进料流的加氢处理条件下接触，其中 原料流和含氢处理气体流共同地具有大于10vppm的CO含量和/或其中反应器入口看到平均CO浓度大于10vppm，其中加氢处理催化剂包括设置在二氧化硅上的钴和钼的催化剂 并且其中选择加氢处理条件使得催化剂在相同条件下具有比相同催化剂大至少10％的相对HDS活性，除了进料流和/或含氢处理气体的总CO含量为 <10 vppm和/或反应器入口CO含量<10 vppm。
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公开(公告)号：US07875167B2
公开(公告)日：2011-01-25
申请号：US12006160
申请日：2007-12-31
CPC分类号： C10G45/08 , C10G2400/02
摘要： A low hydrogen partial pressure process for desulfurizing naphtha in the presence of a hydrodesulfurization catalyst which catalyst is selective for suppressing hydrogenation of olefins and in the presence. This invention also relates to the use of optimum metals loading for achieving a high level of hydrodesulfurization with a low level of olefin saturation.
摘要翻译： 在加氢脱硫催化剂存在下，用于脱氢石脑油的低氢分压方法，该催化剂选择性地抑制烯烃的氢化和存在。 本发明还涉及使用最佳金属负载来实现具有低水平烯烃饱和度的高水平加氢脱硫。
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