公开(公告)号：US20180327935A1

公开(公告)日：2018-11-15

申请号：US16045470

申请日：2018-07-25

Applicant: CYTEC INDUSTRIES INC.

Inventor： Shao C. Chiu

IPC: D01F11/12 ,  D01F9/22 ,  D06M101/40

CPC classification number: D01F11/128 ,  D01F9/22 ,  D01F11/122 ,  D06M11/34 ,  D06M11/60 ,  D06M2101/40

Abstract: A gas phase surface treatment for treating carbon fiber including (a) exposing a carbon fiber to a gaseous oxidizing atmosphere to form a modified carbon fiber with an oxidized fiber surface; followed by (b) exposing the oxidized fiber surface to a gaseous nitrogen-containing atmosphere to form a modified carbon fiber with a nitrogen-enriched surface, wherein the nitrogen-enriched surface exhibits an increase in surface nitrogen to surface carbon (N/C) ratio as compared to the surface of the carbon fiber prior to exposure at (a). Steps (a) and (b) are carried out continuously without any additional intervening surface treatment.

公开(公告)号：US20160263803A1

公开(公告)日：2016-09-15

申请号：US15043771

申请日：2016-02-15

Applicant: Cytec Industries Inc.

Inventor： John Desmond Cook ,  Thomas Taylor ,  Girish Vishnukant Deshpande ,  Longgui Tang ,  Barry DeWayne Meece ,  Suzanne Crawford ,  Shao C. Chiu ,  Billy D. Harmon ,  Alan Thomas

IPC: B29C47/00 ,  D01F9/12

CPC classification number: D01D5/06 ,  B29C48/022 ,  B29C48/05 ,  B29K2033/20 ,  B29L2031/731 ,  D01F6/18 ,  D01F6/38 ,  D01F9/12 ,  D01F9/22 ,  D01F9/225

Abstract: The present disclosure relates generally to carbon fibers having high tensile strength and modulus of elasticity, as well as a process for the manufacture of such carbon fiber. The process comprises spinning a polymer/solvent solution into a solvent/water bath in the range of 78%-85% solvent, thereby producing a dense fiber structure, and subsequently carbonizing the polymer precursor fiber at a lower than typical carbonization temperature to form carbon fibers.

Abstract translation: 本公开一般涉及具有高拉伸强度和弹性模量的碳纤维，以及制造这种碳纤维的方法。 该方法包括将聚合物/溶剂溶液在78％-85％溶剂范围内的溶剂/水浴中纺丝，从而产生致密的纤维结构，随后在低于典型的碳化温度下使聚合物前体纤维碳化以形成碳 纤维。

公开(公告)号：US11479881B2

公开(公告)日：2022-10-25

申请号：US15315220

申请日：2016-02-15

Applicant: Cytec Industries Inc.

Inventor： John Desmond Cook ,  Thomas Taylor ,  Girish Vishnukant Deshpande ,  Longgui Tang ,  Barry DeWayne Meece ,  Suzanne Crawford ,  Shao C. Chiu ,  Billy D. Harmon ,  Alan Thomas

IPC: B29C48/05 ,  D01D5/06 ,  B29C48/00 ,  D01F6/18 ,  D01F9/22 ,  D01F9/12 ,  D01F6/38 ,  B29K33/20 ,  B29L31/00

Abstract: The present disclosure relates generally to carbon fibers having high tensile strength and modulus of elasticity, as well as a process for the manufacture of such carbon fiber. The process comprises spinning a polymer/solvent solution into a solvent/water bath in the range of 78%-85% solvent, thereby producing a dense fiber structure, and subsequently carbonizing the polymer precursor fiber at a lower than typical carbonization temperature to form carbon fibers.

公开(公告)号：US10060053B2

公开(公告)日：2018-08-28

申请号：US15382832

申请日：2016-12-19

Applicant: Cytec Industries Inc.

Inventor： Shao C. Chiu

IPC: D01F11/00 ,  D01F11/12 ,  D01F9/22

CPC classification number: D01F11/128 ,  C08J5/06 ,  D01F9/22 ,  D01F11/122 ,  D06M11/34 ,  D06M11/60 ,  D06M2101/40

Abstract: A gas phase surface treatment for treating carbon fiber including (a) exposing a carbon fiber to a gaseous oxidizing atmosphere to form a modified carbon fiber with an oxidized fiber surface; followed by (b) exposing the oxidized fiber surface to a gaseous nitrogen-containing atmosphere to form a modified carbon fiber with a nitrogen-enriched surface, wherein the nitrogen-enriched surface exhibits an increase in surface nitrogen to surface carbon (N/C) ratio as compared to the surface of the carbon fiber prior to exposure at (a). Steps (a) and (b) are carried out continuously without any additional intervening surface treatment.

公开(公告)号：US20160221034A1

公开(公告)日：2016-08-04

申请号：US14551128

申请日：2014-11-24

Applicant: Cytec Industries Inc.

Inventor： Shao C. Chiu ,  Longgui Tang ,  Billy D. Harmon

IPC: B05D3/00 ,  B05D3/02 ,  B05D1/18

CPC classification number: B05D3/007 ,  B05D1/18 ,  B05D3/0254 ,  B05D3/107 ,  B05D7/24 ,  B05D2203/00 ,  B05D2203/30 ,  B05D2256/00 ,  B05D2401/20 ,  B05D2401/21 ,  B05D2504/00 ,  B05D2505/50 ,  B05D2508/00 ,  D06M15/327 ,  D06M15/53 ,  D06M15/55 ,  D06M15/59 ,  D06M15/63 ,  D06M23/10 ,  D06M2101/40

Abstract: Various embodiments directed towards methods of applying sizing to fibers are disclosed herein. In some embodiments, solvent can be used to dissolve a sizing material into a solution, which can then be used to coat the fibers. In some embodiments, a water bath is used to coagulate a sizing on the fiber surface and to remove the remove solvent after coating the fibers, so that water vapor can be created during a subsequent drying step as opposed to solvent vapors. In some embodiments, strong acids or strong bases can be used as the solvent.

Abstract translation: 本文公开了针对纤维施加尺寸的方法的各种实施方案。 在一些实施方案中，可以使用溶剂将上浆材料溶解到溶液中，然后可以将其涂覆在纤维上。 在一些实施方案中，水浴用于凝结纤维表面上的上浆并且在涂覆纤维之后去除除去溶剂，使得在随后的干燥步骤中可以产生水蒸汽，而不是溶剂蒸气。 在一些实施方案中，可以使用强酸或强碱作为溶剂。

公开(公告)号：US09757768B2

公开(公告)日：2017-09-12

申请号：US14551128

申请日：2014-11-24

Applicant: Cytec Industries Inc.

Inventor： Shao C. Chiu ,  Longgui Tang ,  Billy D. Harmon

IPC: B05D1/18 ,  B05D3/10 ,  B05D3/00 ,  B05D7/24 ,  D06M15/327 ,  D06M15/53 ,  D06M15/55 ,  D06M15/59 ,  D06M15/63 ,  D06M23/10 ,  B05D3/02 ,  D06M101/40

CPC classification number: B05D3/007 ,  B05D1/18 ,  B05D3/0254 ,  B05D3/107 ,  B05D7/24 ,  B05D2203/00 ,  B05D2203/30 ,  B05D2256/00 ,  B05D2401/20 ,  B05D2401/21 ,  B05D2504/00 ,  B05D2505/50 ,  B05D2508/00 ,  D06M15/327 ,  D06M15/53 ,  D06M15/55 ,  D06M15/59 ,  D06M15/63 ,  D06M23/10 ,  D06M2101/40

Abstract: Various embodiments directed towards methods of applying sizing to fibers are disclosed herein. In some embodiments, solvent can be used to dissolve a sizing material into a solution, which can then be used to coat the fibers. In some embodiments, a water bath is used to coagulate a sizing on the fiber surface and to remove the remove solvent after coating the fibers, so that water vapor can be created during a subsequent drying step as opposed to solvent vapors. In some embodiments, strong acids or strong bases can be used as the solvent.

公开(公告)号：US20170175298A1

公开(公告)日：2017-06-22

申请号：US15382832

申请日：2016-12-19

Applicant: Cytec Industries Inc.

Inventor： Shao C. Chiu

IPC: D01F11/12 ,  D01F9/22

CPC classification number: D01F11/128 ,  D01F9/22 ,  D01F11/122 ,  D06M2101/40

Abstract: A gas phase surface treatment for treating carbon fiber including (a) exposing a carbon fiber to a gaseous oxidizing atmosphere to form a modified carbon fiber with an oxidized fiber surface; followed by (b) exposing the oxidized fiber surface to a gaseous nitrogen-containing atmosphere to form a modified carbon fiber with a nitrogen-enriched surface, wherein the nitrogen-enriched surface exhibits an increase in surface nitrogen to surface carbon (N/C) ratio as compared to the surface of the carbon fiber prior to exposure at (a). Steps (a) and (b) are carried out continuously without any additional intervening surface treatment.