摘要:
The instant invention pertains to a concentrated aqueous dispersion of organic light stabilizers with a particle size of less than 1000 nm, prepared by heterophase radical polymerization of ethylenically unsaturated monomers in the presence of the light stabilizers, wherein the weight ratio of light stabilizer to polymeric carrier is greater than 50/100. Another aspect of the invention is a process for the preparation of such aqueous dispersions with high light stabilizer content. Aqueous dispersions prepared according to this process are useful ingredients for adhesives, aqueous emulsions of natural or synthetic rubbers, water based inks or a water based coating compositions, which are consequently also subjects of the invention.
摘要:
The instant invention pertains to a concentrated aqueous dispersion of organic light stabilizers with a particle size of less than 1000 nm, prepared by heterophase radical polymerization of ethylenically unsaturated monomers in the presence of the light stabilizers, wherein the weight ratio of light stabilizer to polymeric carrier is greater than 50/100. Another aspect of the invention is a process for the preparation of such aqueous dispersions with high light stabilizer content. Aqueous dispersions prepared according to this process are useful ingredients for adhesives, aqueous emulsions of natural or synthetic rubbers, water based inks or a water based coating compositions, which are consequently also subjects of the invention.
摘要:
The invention relates to a concentrated aqueous polymer dispersion with an average particle size of less than 1000 nm comprising a) a polymer carrier prepared by heterophase radical polymerization of at least one ethylenically unsaturated monomer in the presence of b) a photoinitiator and/or photolatent catalyst and c) optionally a non-ionic, cationic or anionic surfactant, wherein the weight ratio of the photoinitiator and/or photolatent catalyst to the polymer carrier is greater than 20 parts of photoinitiator and/or photolatent catalyst per 100 parts of polymer carrier, preferably equal or greater than 35 parts of photoinitiator and/or photolatent catalyst per 100 parts of polymer carrier.
摘要:
The present invention relates to a homogenous liquid blend comprising a photoinitiator and an alkoxylate surfactant for incorporation into aqueous based and solvent based radiation curable systems. In particular the invention relates to a homogenous liquid blend which is liquid at room temperature comprising at least 30% by weight with regard to the whole blend of a solid photoinitiator of the radical type and 1-70% by weight of at least one alkoxylated liquid surface active agent and optionally an organic diluent.
摘要:
The present invention relates to a homogenous liquid blend comprising a photoinitiator and an alkoxylate surfactant for incorporation into aqueous based and solvent based radiation curable systems. In particular the invention relates to a homogenous liquid blend which is liquid at room temperature comprising at least 30% by weight with regard to the whole blend of a solid photoinitiator of the radical type and 1-70% by weight of at least one alkoxylated liquid surface active agent and optionally an organic diluent.
摘要:
The invention relates to new reactive diluents of the formulae (Ia, Ib, Ic, Id, Ie) and to an alkyd coating composition comprising them. In a preferred embodiment R1 and R2 are hydrogen; R3 is (meth)acryloyloxy-methyl or phenyl para substituted by vinyl, R4 is phenyl or phenyl para substituted by vinyl or (meth)acryloyloxy; or a substituted phenyl residue of the formula —C6H4CH2—W, wherein W is (meth)acryloyloxy, or an aliphatic residue of the formula —CH2—Y-A, wherein Y is a bond, O—C1-C12alkylene, wherein the alkylene linker is linear or branched and may be interrupted once or more than once by oxygen, A is hydroxy, C1-C6alkoxy, acetoxy, (meth)acryloyloxy, or a phthalate- or maleate-residue; R5 is hydrogen; n is 1; X is —(CH2)—. The invention further relates to a solvent-based or water-based alkyd coating composition comprising 0.3 to 10 wt. % of a mono-, bis- or trisacylphosphinoxide photoinitiator, especially Irgacure 819.
摘要:
A business management machine within a business management system may access a business model and a solution model, and the business management machine may generate a connection map based on the business model and the solution model. The business management machine may detect a business activity. Based on the detecting of the business activity, the business management machine may initiate an access of a connection map that indicates a correspondence between a business solution within the solution model and the one or more context descriptors within the business model that define the business context. The business management machine may perform the access of the connection map. Based on the access of the connection map, the detecting of the business activity, or both, the business management machine may present a reference to the business solution or to a document pertinent to the business solution or to the business context.
摘要:
There is provided a tin lid for use with cans of oblong shape in Hansa format, which includes in its lid image section a tear-open portion defined by a self-contained recessed line capable of being broken up at one end of the lid by means of a pull-open ring attached to this end. At the other end, said recessed line includes a straight recessed line portion which extends in chordal-type fashion with respect to the core wall shaped like an arc of a circle and which is positioned perpendicular and symmetrically to the longitudinal lid center line and is further connected with the other recessed line components through an also chordal-type or polygonal recessed line connecting portion. This tear-open portion area defined by the polygonal arrangement of the recessed line, above all, is stiffened by a group of like and completely uniformly distributed beads, which are further associated with the chordal-type recessed line portion in predetermined manner, to so ensure the tear-open portion's final separation from the remaining lid section virtually without any remarkable capacity of the lid image section to undergo spring movement itself.
摘要:
The surfaces of nano silica particles are modified with siloxane substituents containing aldehyde functional groups providing particles which are readily incorporated into compositions, such as polymeric coating compositions, to improve scratch resistance, dirt pick-up resistance, anti-adhesion properties and while maintaining excellent film forming properties. Provided are the novel silica particles, a simple economic process for their preparation and dirt repellent coatings and polymeric molding compositions containing them.
摘要:
Compounds of formula (I), wherein Y is, for example, C3-C,12alkylene, butenylene, butynylene, or C4-C,12alkylene interrupted one or more times by non-consecutive —O— or —NR2—; R1 is a reactive group selected from OH, SH, NR3R4, —(CO)—OH, —(CO)—NH2, SO3H, —C(R5)═CR6R7, oxiranyl, —O—(CO)—NH—R8—NCO and —O—(CO)—R9—(CO)—X; R2 is hydrogen, C1-C4alkyl or C2-C4 hydroxyalkyl; R3 and R4 are each independently of the other hydrogen, C1-C4alkyl or C2-C4hydroxyalkyl; R5, R6 and R7 are each independently of the others hydrogen or methyl; R8 is, for example, linear or branched C4-C12alkylene, or phenylene; R9 is, for example, linear branched C1-C16alkylene, —CH═CH—, —CH═CH—CH2—, C6-cycloalkylene, phenylene or naphthylene; and X, X1 and X2 are each independently of the others OH, Cl, OCH3 or OC2H5; are suitable as photoinitiators that can be incorporated in a formulation to be cured.
摘要翻译:式(I)的化合物,其中Y为例如C 3 -C 12亚烷基,亚丁烯基,亚丁炔基或C 4-14亚烷基, C 1 -C 12亚烷基被非连续的-O-或-NR 2 - 2间隔一次或多次; R 1是选自OH,SH,NR 3 R 4, - (CO)-OH, - (CO) - NH 2,SO 3 H,-C(R 5) - CR 6 R 7, /(CO)-NH-R 8 -NCO和-O-(CO)-R 9 - (CO)-X; R 2是氢,C 1 -C 4烷基或C 2 -C 4烷基或C 2 -C 4 - 羟基烷基; R 3和R 4分别独立地为氢,C 1 -C 4烷基或C 1 -C 4烷基, S 2 -C 4羟烷基; R 5,R 6和R 7各自独立地为氢或甲基; R 8是例如直链或支链C 4 -C 12亚烷基或亚苯基; R 9是例如直链支链C 1 -C 16亚烷基,-CH-CH-,-CH-CH-CH 3, 亚磺酰基,亚苯基或亚萘基; 和X,X 1和X 2各自独立地为OH,Cl,OCH 3或OC 2 SUB 5 H 5; 适合作为可引入待固化制剂中的光引发剂。