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    Process for upgrading a hydrocarbon oil
    1.
    发明授权
    Process for upgrading a hydrocarbon oil 失效
    烃油改质工艺

    公开(公告)号：US5928501A

    公开(公告)日：1999-07-27

    申请号：US17587

    申请日：1998-02-03

    Applicant: Chakka Sudhakar ,  Mark T. Caspary ,  Stephen J. DeCanio

    Inventor： Chakka Sudhakar ,  Mark T. Caspary ,  Stephen J. DeCanio

    IPC: C10G45/08 ,  C10G45/16 ,  C10G17/00 ,  C10G45/04

    CPC classification number: C10G45/08 ,  C10G45/16

    Abstract: A process for treating a hydrocarbon oil feed to reduce total acid number (TAN) and increase API gravity employs a catalyst which includes one or more metals of non-noble Group VIII of the periodic table (e.g., iron, cobalt and nickel), and at least one metal selected from Group VIB (e.g., chromium, tungsten and molybdenum) on a phosphorus treated carbon support, the phosphorus treated carbon support being comprised of phosphorus bound to the carbon surface predominantly as polyphosphate species characterized by peaks between -5 and -30 ppm in the solid-state magic angle spinning .sup.31 P nuclear magnetic resonance spectrum. The process includes blending the catalyst with the hydrocarbon oil feed to form a slurry which is then treated with hydrogen at moderate temperature and pressure in, for example, a tubular reactor. Deposit formation is minimized or avoided.

    Abstract translation: 用于处理烃油进料以减少总酸值（TAN）并增加API重力的方法使用包括一种或多种周期表非贵重族VIII（例如铁，钴和镍）的金属的催化剂，以及 在磷处理的碳载体上选自VIB族（例如，铬，钨和钼）中的至少一种金属，磷处理的碳载体由磷结合的磷组成，主要作为多磷酸盐物质，其特征在于-5和 - 30ppm的固态魔角旋转31P核磁共振谱。 该方法包括将催化剂与烃油进料混合以形成浆料，然后在中等温度和压力下用例如管式反应器的氢气处理。 沉积物形成最小化或避免。

    Selective hydrodesulfurization of cracked naphtha using novel manganese oxide octahedral molecular sieve supported catalysts
    4.
    发明授权
    Selective hydrodesulfurization of cracked naphtha using novel manganese oxide octahedral molecular sieve supported catalysts 失效
    使用新型氧化锰八面体分子筛负载型催化剂对裂化石脑油进行选择性加氢脱硫

    公开(公告)号：US5846406A

    公开(公告)日：1998-12-08

    申请号：US620148

    申请日：1996-03-22

    Applicant: Chakka Sudhakar ,  Chi-Lin O'Young

    Inventor： Chakka Sudhakar ,  Chi-Lin O'Young

    IPC: C10G45/04 ,  C10G45/12 ,  C10G69/04

    CPC classification number: B01J23/34 ,  B01J23/8892 ,  C10G45/12 ,  C10G69/04

    Abstract: Selective hydrodesulfurization of cracked naphtha, with minimum attendant hydrogenation of olefins, is effected over a novel catalyst composition comprising a sulfided, "manganese oxide octahedral molecular sieve" supported catalyst bearing (i) at least one non-noble Group VIII metal, (ii) at least one Group VI-B metal, optionally (iii) at least one metal of Group I-A, II-A, III-B, or the lanthanide series of rare earths, and optionally (iv) at least one metal of Group I-B. The catalyst of the present invention is highly selective in minimizing the olefin saturation and the resulting octane loss in the cracked naphtha hydrodesulfurization process.

    Abstract translation: 裂解石脑油的选择性加氢脱硫，最少伴随着烯烃的加氢，对包含硫化的“锰氧化物八面体分子筛”负载的催化剂（i）至少一种非贵金属VIII族金属的新催化剂组合物进行，（ii） 至少一种VI-B族金属，任选地（iii）至少一种IA，II-A，III-B族金属或稀土镧系稀土金属，和任选地（iv）至少一种IB族金属。 本发明的催化剂在使裂化石脑油加氢脱硫过程中的烯烃饱和度和所得辛烷值损失最小化方面具有高选择性。

    Process for pretreatment of hydrocarbon oil prior to hydrocracking and fluid catalytic cracking
    6.
    发明授权
    Process for pretreatment of hydrocarbon oil prior to hydrocracking and fluid catalytic cracking 失效
    在加氢裂化和流化催化裂化前预处理烃油的工艺

    公开(公告)号：US5624547A

    公开(公告)日：1997-04-29

    申请号：US556473

    申请日：1995-11-13

    Applicant: Chakka Sudhakar ,  Paul O. Fritz ,  Carl J. Kjellson ,  Hua-Min Huang ,  Gerald G. Sandford

    Inventor： Chakka Sudhakar ,  Paul O. Fritz ,  Carl J. Kjellson ,  Hua-Min Huang ,  Gerald G. Sandford

    IPC: B01J21/02 ,  B01J23/85 ,  B01J27/188 ,  C10G45/50 ,  C10G45/00

    CPC classification number: C10G45/50 ,  B01J21/02 ,  B01J23/85 ,  B01J27/188

    Abstract: Disclosed is a process for pretreatment of hydrocarbon feed containing sulfur and nitrogen compounds and aromatics prior to hydrocracking or fluid catalytic cracking which comprises:contacting said feedstock with a sulfided catalyst comprising a metal of non-noble Group VIII and Group VIB, and, optionally one or more elements selected from Group IIIA and Group VA of the Periodic Table on a carbon support consisting essentially of activated carbon, optionally on a carbon support treated with phosphorus, having a B.E.T. (Braunauer-Emmett Teller) surface area of at least 100 m.sup.2 /g and an average Pore Diameter greater than 12.ANG. and a Total Pore Volume greater than 0.3 cc/g.

    Abstract translation: 公开了一种用于在加氢裂化或流化催化裂化之前预处理含有硫和氮化合物和芳族化合物的烃进料的方法，其包括：使所述原料与包含非贵金属VIII族和VIB族的硫化催化剂接触，以及任选的一种 或更多选自元素周期表的IIIA族和VA族元素的碳载体，其基本上由活性炭组成，任选地在用磷处理的碳载体上，具有BET （Braunauer-Emmett Teller）表面积至少为100m 2 / g，平均孔径大于12，总孔体积大于0.3cc / g。

    Process for hydrodearomatization of hydrocarbon oils using carbon supported metal sulfide catalysts promoted by phosphate
    8.
    发明授权
    Process for hydrodearomatization of hydrocarbon oils using carbon supported metal sulfide catalysts promoted by phosphate 失效
    使用由磷酸盐促进的碳负载型金属硫化物催化剂，加氢脱氢化烃油的方法

    公开(公告)号：US5472595A

    公开(公告)日：1995-12-05

    申请号：US287738

    申请日：1994-08-09

    Applicant: Chakka Sudhakar ,  Frank Dolfinger, Jr. ,  Max R. Cesar ,  Mahendra S. Patel

    Inventor： Chakka Sudhakar ,  Frank Dolfinger, Jr. ,  Max R. Cesar ,  Mahendra S. Patel

    IPC: B01J21/18 ,  B01J27/188 ,  C07B61/00 ,  C10G45/08 ,  C10G45/50 ,  C10G45/46

    CPC classification number: B01J27/188 ,  B01J21/18 ,  C10G45/50

    Abstract: A process for treating a charge hydrocarbon oil containing undesired aromatic components, sulfur and nitrogen compounds, which comprisesmaintaining a bed of a sulfided catalyst comprising 0.1 to 15% by weight of nickel; and from 1 to 50% by weight of tungsten and 0.01 to 10% by weight of phosphorus, on an activated carbon support, andpassing a charge hydrocarbon feed in the presence of hydrogen into contact with said catalyst at hydrotreating conditions, thereby effecting hydrodearomatization, hydrodesulfurization and hydrodenitrogenation of said charge hydrocarbon feed containing undesired aromatic components, sulfur and nitrogen, and forming a product stream of hydrocarbon containing a lesser quantity of undesired aromatic components, sulfur and nitrogen; andrecovering said product stream of hydrocarbon containing a lesser quantity of undesired aromatic components, sulfur and nitrogen.

    Abstract translation: 一种处理含有不需要的芳族组分，硫和氮化合物的电荷烃油的方法，其包括保持包含0.1至15重量％镍的硫化催化剂床; 和1至50重量％的钨和0.01至10重量％的磷，在活性炭载体上，并使氢气存在下的电荷烃进料在加氢处理条件下与所述催化剂接触，从而进行加氢脱芳构化， 所述含有不需要的芳族组分，硫和氮的加料烃进料的加氢脱硫和加氢脱氮，并形成含有较少量的不需要的芳族组分，硫和氮的烃的产物流; 并回收含有较少量的不需要的芳族组分，硫和氮的烃的产物流。

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