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    Catalyst formulation for hydrogenation
    2.
    发明授权
    Catalyst formulation for hydrogenation 有权
    用于氢化的催化剂配方

    公开(公告)号：US08460937B2

    公开(公告)日：2013-06-11

    申请号：US13431964

    申请日：2012-03-27

    申请人： Marvin M. Johnson ,  Edward R. Peterson ,  Sean C. Gattis

    发明人： Marvin M. Johnson ,  Edward R. Peterson ,  Sean C. Gattis

    IPC分类号： G01N31/10 ,  B01J31/00 ,  B01J31/40 ,  B01J37/00 ,  B01J38/72 ,  B01J23/00 ,  C08F4/02 ,  C08F4/60

    CPC分类号： B01J23/50 ,  B01J23/44 ,  B01J23/48 ,  B01J23/52 ,  B01J23/60 ,  B01J23/62 ,  B01J23/6562 ,  B01J23/66 ,  B01J35/002 ,  B01J37/0036 ,  B01J37/009 ,  B01J37/0205 ,  B01J37/18 ,  C10G45/34 ,  C10G45/40 ,  C10G2400/20

    摘要： A method of screening catalysts for liquid-phase selective hydrogenation by preparing a test catalyst by adding a promoter to a reference catalyst; preparing a liquid reactant stream comprising C2H2 dissolved in n-methyl-2-pyrrolidone; testing the test and reference catalysts by contacting the reactant stream and gas mixture comprising hydrogen and carbon monoxide in continuous flow with the test catalyst and reference catalyst, respectively, at selective hydrogenation reaction conditions to produce a product stream, condensing substantially all of the n-methyl-2-pyrrolidone from the product stream; measuring the concentrations of products comprising C2H2, C2H4, and C2H6 in the product stream at steady state; determining performance parameters for the test catalyst and the reference catalyst comprising the respective C2H2 conversion Sc and C2H4 selectivity relative to C2H6 Ss; and comparing the test catalyst performance parameters to those for the reference catalyst.

    摘要翻译： 一种筛选用于液相选择性氢化的催化剂的方法，通过向参考催化剂中加入助催化剂制备试验催化剂; 制备包含溶解在正甲基-2-吡咯烷酮中的C2H2的液体反应物流; 通过在选择性氢化反应条件下分别使包含氢气和一氧化碳的反应物流和连续流动的气体混合物与测试催化剂和参考催化剂分别接触来测试测试和参考催化剂，以产生产物流，基本上将所有的n- 甲基-2-吡咯烷酮; 在稳定状态下测量产物流中包含C2H2，C2H4和C2H6的产物的浓度; 确定测试催化剂和参考催化剂的性能参数，其包含相对于C 2 H 6 S的相应的C 2 H 2转化率Sc和C 2 H 4选择性; 并将试验催化剂性能参数与参考催化剂的参数进行比较。

    CATALYST FORMULATION FOR HYDROGENATION
    4.
    发明申请
    CATALYST FORMULATION FOR HYDROGENATION 有权
    催化剂用于氢化反应

    公开(公告)号：US20120190117A1

    公开(公告)日：2012-07-26

    申请号：US13431964

    申请日：2012-03-27

    申请人： Marvin M. Johnson ,  Edward R. Peterson ,  Sean C. Gattis

    发明人： Marvin M. Johnson ,  Edward R. Peterson ,  Sean C. Gattis

    IPC分类号： G01N31/10 ,  B01J23/08 ,  B01J23/34 ,  B01J23/06 ,  B01J23/44

    CPC分类号： B01J23/50 ,  B01J23/44 ,  B01J23/48 ,  B01J23/52 ,  B01J23/60 ,  B01J23/62 ,  B01J23/6562 ,  B01J23/66 ,  B01J35/002 ,  B01J37/0036 ,  B01J37/009 ,  B01J37/0205 ,  B01J37/18 ,  C10G45/34 ,  C10G45/40 ,  C10G2400/20

    摘要： A method of screening catalysts for liquid-phase selective hydrogenation by preparing a test catalyst by adding a promoter to a reference catalyst; preparing a liquid reactant stream comprising C2H2 dissolved in n-methyl-2-pyrrolidone; testing the test and reference catalysts by contacting the reactant stream and gas mixture comprising hydrogen and carbon monoxide in continuous flow with the test catalyst and reference catalyst, respectively, at selective hydrogenation reaction conditions to produce a product stream, condensing substantially all of the n-methyl-2-pyrrolidone from the product stream; measuring the concentrations of products comprising C2H2, C2H4, and C2H6 in the product stream at steady state; determining performance parameters for the test catalyst and the reference catalyst comprising the respective C2H2 conversion Sc and C2H4 selectivity relative to C2H6 Ss; and comparing the test catalyst performance parameters to those for the reference catalyst.

    摘要翻译： 一种筛选用于液相选择性氢化的催化剂的方法，通过向参考催化剂中加入助催化剂制备试验催化剂; 制备包含溶解在正甲基-2-吡咯烷酮中的C2H2的液体反应物流; 通过在选择性氢化反应条件下分别使包含氢气和一氧化碳的反应物流和连续流动的气体混合物与测试催化剂和参考催化剂分别接触来测试测试和参考催化剂，以产生产物流，基本上将所有的n- 甲基-2-吡咯烷酮; 在稳定状态下测量产物流中包含C2H2，C2H4和C2H6的产物的浓度; 确定测试催化剂和参考催化剂的性能参数，其包含相对于C 2 H 6 S的相应的C 2 H 2转化率Sc和C 2 H 4选择性; 并将试验催化剂性能参数与参考催化剂的参数进行比较。

    Methods of recovery of pore-forming agents for mesostructured materials
    9.
    发明申请
    Methods of recovery of pore-forming agents for mesostructured materials 有权
    中孔结构材料成孔剂回收方法

    公开(公告)号：US20090110631A1

    公开(公告)日：2009-04-30

    申请号：US12009894

    申请日：2008-01-23

    申请人： Javier Garcia-Martinez ,  Marvin M. Johnson

    发明人： Javier Garcia-Martinez ,  Marvin M. Johnson

    IPC分类号： C01B39/02

    CPC分类号： C01B39/026 ,  B01D11/0203 ,  B01D11/0288

    摘要： The invention provides methods of recovering a pore-forming agent from an inorganic material that defines a plurality of mesopores having a controlled cross sectional area to form a mesostructure having long-range crystallinity and also to methods of making one or more mesostructures that features removal, recovery, and/or reuse of the pore-forming agent. Suitable pore-forming agents include, for example, surfactants.

    摘要翻译： 本发明提供从限定具有受控横截面积的多个介孔的无机材料回收成孔剂的方法，以形成具有远程结晶度的介观结构，以及制备一种或多种特征为除去的介孔结构的方法， 回收和/或再利用。 合适的成孔剂包括例如表面活性剂。