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公开(公告)号：US5300696A
公开(公告)日：1994-04-05
申请号：US998177
申请日：1992-12-29
CPC分类号： C07C41/06
摘要： A combination of an etherification process and a process for the isomerization of linear alkenes to isoalkenes uses an adsorptive separation zone that receives an effluent fraction from the etherification reaction zone and separates the fraction at low efficiency to produce an isomerization feed stream comprising normal butenes and butanes, and a butane stream that is rejected from the process. The rejection of butanes at low efficiency reduces or eliminates the loss of butenes with the rejection of butane. A low efficiency adsorptive separation to reject butanes also benefits the isomerization process by inhibiting coking.
摘要翻译： 醚化方法和将线性烯烃异构化为异烯烃的方法的组合使用吸附分离区，其接收来自醚化反应区的流出物部分并以低效率分离馏分以产生包含正丁烯和丁烷的异构化进料流 ，以及从流程中拒绝的丁烷流。 以低效率排斥丁烷可以降低或消除丁烷的排斥与丁烷的排斥。 抑制焦炭的低效吸附分离也有利于异构化过程。
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公开(公告)号：US5135639A
公开(公告)日：1992-08-04
申请号：US528403
申请日：1990-05-24
摘要： A process combination is disclosed to reduce the aromatics content of a key component of gasoline blends. Paraffins contained in catalytic reformates are conserved and upgraded by separation and isomerization, reducing the reforming severity required to achieve a given product octane with concomitant reduction in paraffin aromatization and cracking. Light reformate may be separated and isomerized, and heavier paraffins are separated from the reformate by solvent extraction or adsorption and isomerized. A gasoline component having a reduced aromatics content relative to reformate of the same octane number is blended from the net products of the separation and isomerization steps.
摘要翻译： 公开了一种方法组合以降低汽油混合物的关键组分的芳族化合物含量。 包含在催化重整产物中的石蜡通过分离和异构化被保存和升级，降低了获得给定产物辛烷值同时降低链烷烃芳构化和开裂所需的重整严重性。 轻质重整物可以分离和异构化，并且较重的链烷烃通过溶剂萃取或吸附与重整产物分离并异构化。 从分离和异构化步骤的净产物中混合相对于相同辛烷值的重整产物具有降低的芳族化合物含量的汽油组分。
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公开(公告)号：US5672265A
公开(公告)日：1997-09-30
申请号：US288707
申请日：1994-08-15
IPC分类号： C10G35/095 , C10G61/04 , C10G61/06 , C10G45/00 , C10G45/10
CPC分类号： C10G61/04 , C10G35/095 , C10G61/06
摘要： A processing step is added to an existing catalytic reforming unit to increase the yield of aromatic product. The additional processing comprises separation of product from the reforming unit into an aromatic concentrate and a low-octane recycle stream which is upgraded by aromatization. The separation preferably is effected using a large-pore molecular sieve, and the aromatization with a nonacidic L-zeolite contained within the hydrogen circuit of the existing catalytic reforming unit.
摘要翻译： 将加工步骤加入到现有的催化重整单元中以提高芳族产物的产率。 附加处理包括将产物从重整单元分离成芳族浓缩物和通过芳构化升级的低辛烷值再循环料流。 优选使用大孔分子筛进行分离，并且使用包含在现有催化重整单元的氢回路内的非酸性L-沸石进行芳构化。
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4.发明授权公开(公告)号：US06334985B1
公开(公告)日：2002-01-01
申请号：US09135682
申请日：1998-08-18
IPC分类号： F28D300
CPC分类号： F28F3/04 , B01J8/20 , B01J19/006 , B01J19/0073 , B01J19/32 , B01J2208/0015 , B01J2219/00085 , B01J2219/00765 , B01J2219/3221 , B01J2219/32213 , B01J2219/32217 , B01J2219/32237 , B01J2219/32475 , F28D9/0006 , F28D9/0037 , F28D2021/0052
摘要： A tubular reactor passes a flowing stream of reactants through a plurality of mixing devices that simultaneously provide indirect heat exchange of the reactants to improve the uniformity of reactant temperatures and concentrations. The mixing devices provide intimate mixing by passing the reactants through a plurality of narrow channels defined by parallel plate elements that channel a heat exchange fluid on their opposite side to provide the simultaneous indirect heat exchange. The heat exchange channels can have any desired degree of mixing intensity by providing irregularities in the channel walls or flow path that supply the desired degree of fluid shear. Preferably the mixing reactor provides a series of mixing devices with heat exchange along the length of the conduit flow path with space between the devices for remixing of the fluid reactants.
摘要翻译： 管式反应器通过多个混合装置使反应物流动流同时提供反应物的间接热交换以提高反应物温度和浓度的均匀性。 混合装置通过使反应物通过由平行板元件限定的多个窄通道提供紧密混合，所述窄通道在其相对侧上引导热交换流体以提供同时的间接热交换。 通过在通道壁或提供期望程度的流体剪切的流动路径上提供不规则性，热交换通道可以具有任何期望的混合强度。 优选地，混合反应器提供一系列混合装置，沿着管道流动路径的长度进行热交换，在装置之间具有空间，用于再混合流体反应物。
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公开(公告)号：US5294328A
公开(公告)日：1994-03-15
申请号：US922935
申请日：1992-07-31
摘要： A process combination is disclosed to reduce the aromatics content of a key component of gasoline blends. Paraffins contained in catalytic reformates are conserved and upgraded by separation and isomerization, reducing the reforming severity required to achieve a given product octane with concomitant reduction in paraffin aromatization and cracking. Light reformate may be separated and isomerized, and heavier paraffins are separated from the reformate by solvent extraction or adsorption; the recovered heavy paraffins are isomerized, optionally at a substoichiometric hydrogen ratio. A gasoline component having a reduced aromatics content relative to reformate of the same octane number is blended from the net products of the separation and isomerization steps.
摘要翻译： 公开了一种方法组合以降低汽油混合物的关键组分的芳族化合物含量。 包含在催化重整产物中的石蜡通过分离和异构化被保存和升级，降低了获得给定产物辛烷值同时降低链烷烃芳构化和开裂所需的重整严重性。 轻质重整油可以分离和异构化，并且较重的链烷烃通过溶剂萃取或吸附与重整油分离; 回收的重链烷烃异构化，任选地以亚化学计量比的氢气比。 从分离和异构化步骤的净产物中混合相对于相同辛烷值的重整产物具有降低的芳族化合物含量的汽油组分。
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6.发明授权Methods for co-production of alkylbenzene and biofuel from natural oils using hydrocracking 有权使用加氢裂化从天然油共生产烷基苯和生物燃料的方法公开(公告)号：US08507741B2
公开(公告)日：2013-08-13
申请号：US13242825
申请日：2011-09-23
申请人： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Silva Ferreira Alves , Andrea G. Bozzano
发明人： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Silva Ferreira Alves , Andrea G. Bozzano
CPC分类号： C07C2/68 , C07C2/70 , C07C5/333 , C07C7/163 , C07C2527/1206 , C07C2527/126 , C10G3/00 , C10G69/00 , C10G69/123 , C10G69/14 , C10G2300/1014 , C10G2400/30 , Y02P30/20 , C07C15/107 , C07C11/02
摘要： Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form paraffins. A first portion of the paraffins is hydrocracked to form a first stream of normal and lightly branched paraffins in the C9 to C14 range and a second stream of isoparaffins. The first stream is dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins and the isoparaffins are processed to form biofuel.
摘要翻译： 提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。 一种方法包括使天然油脱氧以形成链烷烃的步骤。 将第一部分石蜡加氢裂化以形成C9至C14范围内的第一流和正链和轻度支化的烷烃，第二股异链烷烃流。 将第一流脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 石蜡和异链烷烃的第二部分被处理以形成生物燃料。
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公开(公告)号：US5510564A
公开(公告)日：1996-04-23
申请号：US354192
申请日：1994-12-12
CPC分类号： C10G53/08
摘要： An integrated process for the production of normal paraffins from a feed mixture of normal paraffins, iso-paraffins and aromatics is disclosed. The process integrates a normal paraffin sorption process and an aromatics sorption process. The normal paraffin product of the process of our invention meets the commercial requirements for production of detergents, including sufficiently-low concentrations of both iso-paraffins and aromatics. The process achieves these results without the need for two additional factionation columns that are necessary to prior unintegrated processes.
摘要翻译： 公开了从正链烷烃，异链烷烃和芳族化合物的进料混合物生产正链烷烃的综合方法。 该方法整合了正常的石蜡吸附过程和芳烃吸附过程。 我们发明方法的正常石蜡产品符合生产洗涤剂的商业要求，包括足够低浓度的异链烷烃和芳族化合物。 该过程实现了这些结果，而不需要对先前未整合过程所必需的两个附加派系列。
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8.发明授权
公开(公告)号：US5026951A
公开(公告)日：1991-06-25
申请号：US462262
申请日：1990-01-09
CPC分类号： C07C9/00 , C07C5/2791
摘要： A combination isomerization and liquid phase adsorptive separation process is given increased efficiency and cost effectiveness by the elimination of a column for the separation of desorbent material from selectively retained components. By decreasing the ratio of normal paraffin desorbent to the selective pore volume circulation rate, the extract column can be eliminated without providing other means for the rejection or recovery of desorbent material. This reduction in the ratio of normal paraffin desorbent to selective pore volume circulation rate has been found not to decrease the recovery from the adsorption section. The elimination of the column provides a substantial decrease in the cost of the equipment to operate a combination isomerization zone and liquid phase adsorption section. In an alternate arrangement, the extract column is replaced with a deisohexanizer column. The deisohexanizer column can be used to produce a C.sub.5 -C.sub.6 product stream having research octane numbers of 93 or greater.
摘要翻译： 组合异构化和液相吸附分离方法通过消除用于将解吸剂材料与选择性保留的组分分离的柱来提高效率和成本效益。 通过降低正常石蜡脱附剂与选择孔体积循环速率的比例，可以消除萃取柱而不提供用于排除或回收解吸材料的其它方法。 发现正常石蜡脱附剂与选择性孔体积循环速率之比的这种降低不会降低吸附段的回收率。 柱的消除大大降低了操作组合异构化区和液相吸附段的设备的成本。 在替代布置中，萃取柱用脱乙酸酯柱代替。 脱甲基塔可用于生产具有研究辛烷值为93或更高的C5-C6产物流。
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9.发明申请METHODS FOR CO-PRODUCTION OF ALKYLBENZENE AND BIOFUEL FROM NATURAL OILS USING HYDROCRACKING 有权使用水解法从天然油中生产烷基苯酚和生物油的方法公开(公告)号：US20130079570A1
公开(公告)日：2013-03-28
申请号：US13242825
申请日：2011-09-23
申请人： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Silva Ferreira Alves , Andrea G. Bozzano
发明人： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Silva Ferreira Alves , Andrea G. Bozzano
IPC分类号： C07C1/207
CPC分类号： C07C2/68 , C07C2/70 , C07C5/333 , C07C7/163 , C07C2527/1206 , C07C2527/126 , C10G3/00 , C10G69/00 , C10G69/123 , C10G69/14 , C10G2300/1014 , C10G2400/30 , Y02P30/20 , C07C15/107 , C07C11/02
摘要： Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form paraffins. A first portion of the paraffins is hydrocracked to form a first stream of normal and lightly branched paraffins in the C9 to C14 range and a second stream of isoparaffins. The first stream is dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins and the isoparaffins are processed to form biofuel.
摘要翻译： 提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。 一种方法包括使天然油脱氧以形成链烷烃的步骤。 将第一部分石蜡加氢裂化以形成C9至C14范围内的第一流和正链和轻度支化的烷烃，第二股异链烷烃流。 将第一流脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 石蜡和异链烷烃的第二部分被处理以形成生物燃料。
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公开(公告)号：US5858209A
公开(公告)日：1999-01-12
申请号：US940821
申请日：1997-09-30
IPC分类号： C10G35/095 , C10G61/04 , C10G61/06 , C10G45/00 , C10G45/10
CPC分类号： C10G35/095 , C10G61/04 , C10G61/06
摘要： A processing step is added to an existing catalytic reforming unit to increase the yield of aromatic product. The additional processing comprises separation of product from the reforming unit into an aromatic concentrate and a low-octane recycle stream which is upgraded by aromatization. The separation preferably is effected using a large-pore molecular sieve, and the aromatization with a nonacidic L-zeolite contained within the hydrogen circuit of the existing catalytic reforming unit.
摘要翻译： 将加工步骤加入到现有的催化重整单元中以提高芳族产物的产率。 附加处理包括将产物从重整单元分离成芳族浓缩物和通过芳构化升级的低辛烷值再循环料流。 优选使用大孔分子筛进行分离，并且使用包含在现有催化重整单元的氢回路内的非酸性L-沸石进行芳构化。
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