摘要:
Graft polymeric membranes and methods for making graft polymeric membranes have one or more trifluorovinyl aromatic monomers that are radiation graft polymerized to a polymeric base film. The membranes comprise a polymeric base film to which has been graft polymerized substituted α,α,β-trifluorostyrene and/or α,α,β-trifluorovinylnaphthylene monomers, which are activated towards graft polymerization. As ion-exchange membranes, the membranes are suitable for use in electrode apparatus, including membrane electrode assemblies in, for example, fuel cells. The membranes can also be crosslinked.
摘要:
Graft polymeric membranes and methods for making graft polymeric membranes have one or more trifluorovinyl aromatic monomers that are radiation graft polymerized to a polymeric base film. The membranes comprise a polymeric base film to which has been graft polymerized substituted &agr;,&agr;,&bgr;-trifluorostyrene and/or &agr;,&agr;,&bgr;-trifluorovinylnaphthylene monomers, which are activated towards graft polymerization. As ion-exchange membranes, the membranes are suitable for use in electrode apparatus, including membrane electrode assemblies in, for example, fuel cells. The membranes can also be crosslinked.
摘要:
A water insoluble additive for improving the performance of an ion-exchange membrane, such as in the context of the high temperature operation of electrochemical fuel cells. The insoluble additive comprises a metal oxide cross-linked matrix having acid groups covalently attached to the matrix through linkers. In one embodiment, the metal is silicon and the cross-linked matrix is a siloxane cross-linked matrix containing silicon atoms cross-linked by multiple disiloxy bonds and having acid groups covalently attached to the silicon atoms through alkanediyl linkers.
摘要:
An oscillator and a method for producing an improved oscillator that will generate an accurate frequency when encountering a vibration. The oscillator and method uses a crystal with minimal cross-axis coupling. Further, a first accelerometer produced using MEMS technology is used. The first accelerometer is positioned inside of the oscillator so that the accelerometer accurately measures any vibration encountered by the oscillator. The first accelerometer and the crystal are maintained at constant temperature to minimize phase shifts and gain variations.
摘要:
&agr;,&bgr;,&bgr;-Trifluorostyrene and derivatives thereof synthesized in two steps from 1,1,1,2-tetrafluoroethylene. In the first step, 1,1,1,2-tetrafluoroethylene is reacted with a base, a metal salt such as zinc chloride and an optionally amine to form a trifluorovinyl metal complex. In the second step, the trifluorostyrene or derivative is obtained by reacting the trifluorovinyl metal complex with an aryl transfer agent such as, for example, an aryl triflate or an aryl halide, in the presence of a metal catalyst and optionally a coordinating ligand. Both steps may be carried out in one reactor.
摘要:
A precision oven-controlled crystal oscillator (OCXO) uses an adjustment feedback signal that, when mixed with a reference signal from a stable reference oscillator, accurately controls the generation of an output signal from a voltage controlled crystal oscillator (VCXO). An OCXO according to the invention has high stability and high accuracy. The digital OXCO can be manufactured at low cost, and is particularly beneficial for Code Division Multiple Access (CDMA) base station applications in cellular communication networks an the like.
摘要:
A composite membrane for use in a fuel cell membrane electrode assembly comprises a porous polymeric substrate and an impregnant partially filling the substrate such that the substrate comprises a first region having pores substantially filled with the impregnant, and a second substantially porous region. The impregnant comprises a cation exchange material. The cation exchange material covers one surface of the substrate in a dense surface layer, contiguous with the first region of the substrate. The substrate has greater than 10% residual porosity, and the composite membrane is substantially gas impermeable and has at least one substantially porous major surface.
摘要:
Stripped porous polymer film and a method for making such film from substantially heterogeneous porous polymer film are described. The heterogeneous film has surface characteristics that are different from the characteristics of the interior bulk material, and the method comprises mechanically stripping at least a portion of at least one surface layer from the heterogeneous film. The stripped porous polymer film may be incorporated into composite membranes. Such composite membranes are particularly suitable for incorporation into membrane electrode assemblies for use in electrochemical cells, including electrochemical fuel cells.
摘要:
A composite membrane is provided in which a porous substrate is impregnated with a polymeric composition comprising various combinations of .alpha.,.beta.,.beta.-trifluorostyrene, substituted .alpha.,.beta.,.beta.-trifluorostyrene and ethylene-based monomeric units. Where the polymeric composition includes ion-exchange moieties, the resultant composite membranes are useful in electrochemical applications, particularly as membrane electrolytes in electrochemical fuel cells.
摘要:
An inlet apparatus for gas-aerosol sampling comprises an elutriator column and an impactor member. The elutriator column comprises an inlet and an impact accelerator jet outlet, and the inner surface of the column is provided with a coating of polytetrafluoroethylene-containing polymer. The impactor member includes a housing which surrounds the impact accelerator jet outlet and an impactor surface arranged within the housing and opposite the impact accelerator jet outlet. The inner surface of the housing is also provided with a polytetrafluoroethylene-containing polymer coating.