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公开(公告)号：US06355189B1
公开(公告)日：2002-03-12
申请号：US09504453
申请日：2000-02-16
Applicant: John D. Basil , Robert M. Hunia , Chia-Cheng Lin
Inventor： John D. Basil , Robert M. Hunia , Chia-Cheng Lin
IPC: F21V904
CPC classification number: C09D183/14 , C09D183/04 , C08L2666/54
Abstract: An ultraviolet radiation resistant coating is disclosed comprising cerium oxide in an inorganic oxide matrix formed by the hydrolysis and condensation of an organoalkoxysilanie and/or other metal alkoxide in combination with the reaction product of cerium oxide and tetraalkylsilicate.
Abstract translation: 公开了一种抗紫外线辐射涂层，其包括通过有机烷氧基硅烷和/或其它金属醇盐与氧化铈和四烷基硅酸盐的反应产物的水解和缩合形成的无机氧化物基质中的氧化铈。
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公开(公告)号：US06469119B2
公开(公告)日：2002-10-22
申请号：US09771860
申请日：2001-01-29
Applicant: John D. Basil , Chia-Cheng Lin , Robert M. Hunia , Helmut Franz
Inventor： John D. Basil , Chia-Cheng Lin , Robert M. Hunia , Helmut Franz
IPC: C08G7708
CPC classification number: C09D183/04 , C08F8/42 , C08J7/047 , C08J2483/00 , C08F26/10 , C08L2666/04 , C08L2666/54 , C08L2666/34
Abstract: Siloxane organic hybrid polymers and a method of making them by condensation polymerization reaction of organoalkoxysilane in the presence of organic film-forming polymers are disclosed. Alkali metal carboxylic acid catalyst is also disclosed, as well as the incorporation of cerium oxide for attenuation of ultraviolet radiation.
Abstract translation: 公开了硅氧烷有机杂化聚合物及其在有机成膜聚合物存在下通过有机烷氧基硅烷的缩聚反应制备它们的方法。 还公开了碱金属羧酸催化剂，以及掺入氧化铈以减少紫外线辐射。
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公开(公告)号：US5385964A
公开(公告)日：1995-01-31
申请号：US591921
申请日：1990-10-02
Applicant: John D. Basil , Chia-Cheng Lin , Robert M. Hunia
Inventor： John D. Basil , Chia-Cheng Lin , Robert M. Hunia
IPC: C08J7/04 , C08L83/04 , C09D139/06 , C09D183/06 , C09D183/08 , C08K5/54
CPC classification number: C08J7/047 , C09D139/06 , C09D183/06 , C09D183/08 , C08J2369/00 , C08J2483/00 , C08L83/04
Abstract: A silica-free, abrasion resistant and ultraviolet radiation resistant coating is disclosed comprising an organic UV absorbing compound such as hydroxybenzophenone in an inorganic oxide matrix formed by the hydrolysis and condensation of an organo alkoxysilane and a silicon other metal alkoxide.
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公开(公告)号：US5344712A
公开(公告)日：1994-09-06
申请号：US546484
申请日：1990-06-29
Applicant: John D. Basil , Chia-Cheng Lin
Inventor： John D. Basil , Chia-Cheng Lin
IPC: C08J7/04 , C09D183/04 , B32B27/36
CPC classification number: C09D183/04 , C08J7/047 , C08J2483/00
Abstract: Siloxane organic hybrid polymers and a method of making them by condensation polymerization reaction of organoalkoxysilane in the presence of organic film-forming polymers are disclosed wherein cerium oxide is incorporated for the attenuation of ultraviolet radiation.
Abstract translation: 公开了硅氧烷有机杂化聚合物及其在有机成膜聚合物存在下通过有机烷氧基硅烷的缩聚反应制备它们的方法，其中掺入氧化铈以减少紫外线辐射。
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公开(公告)号：US5328645A
公开(公告)日：1994-07-12
申请号：US293405
申请日：1989-01-04
Applicant: Chia-Cheng Lin , John D. Basil
Inventor： Chia-Cheng Lin , John D. Basil
CPC classification number: C01B33/163
Abstract: An alkoxysilane sol-gel composition and method for its production are disclosed whereby an alkoxysilane of the general formulaSi(OR).sub.4wherein R is an organic radical such as methyl, ethyl, propyl or butyl is hydrolyzed with an acid catalyst and the resulting acidic sol is further hydrolyzed and condensed in the presence of an alkaline component which accelerates gelation to form an inorganic oxide network.
Abstract translation: 公开了一种烷氧基硅烷溶胶 - 凝胶组合物及其制备方法，其中通式为Si（OR）4（其中R为有机基团如甲基，乙基，丙基或丁基）的烷氧基硅烷用酸催化剂水解，得到酸性 溶胶在碱性组分的存在下进一步水解和缩合，其加速凝胶化以形成无机氧化物网络。
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Patent Agency Ranking
公开(公告)号：US06264859B1
公开(公告)日：2001-07-24
申请号：US08048866
申请日：1993-04-14
Applicant: John D. Basil , Robert M. Hunia , Chia-Cheng Lin
Inventor： John D. Basil , Robert M. Hunia , Chia-Cheng Lin
IPC: F21V904
CPC classification number: C09D183/14 , C09D183/04 , C08L2666/54
Abstract: An ultraviolet radiation resistant coating is disclosed comprising cerium oxide in an inorganic oxide matrix formed by the hydrolysis and condensation of an organoalkoxysilane and/or other metal alkoxide in combination with the reaction product of cerium oxide and tetraalkylsilicate.
Abstract translation: 公开了一种抗紫外线辐射涂层，其包括通过有机烷氧基硅烷和/或其它金属醇盐与氧化铈和四烷基硅酸盐的反应产物的水解和缩合形成的无机氧化物基质中的氧化铈。
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公开(公告)号：US5035745A
公开(公告)日：1991-07-30
申请号：US546076
申请日：1990-06-29
Applicant: Chia-Cheng Lin , John D. Basil , Robert M. Hunia
Inventor： Chia-Cheng Lin , John D. Basil , Robert M. Hunia
IPC: C08G77/34 , C09D1/00 , C09D183/00 , C09D183/02 , C09D183/04 , C09D185/00
CPC classification number: C09D1/00 , C08G77/34 , C09D183/04
Abstract: An abrasion resistant and ultraviolet radiation resistant coating is disclosed comprising an inorganic oxide matrix formed by the hydrolysis and condensation of an alkoxysilane and/or other metal alkoxide, further comprising cerium oxide for ultraviolet radiation resistant and/or silica for improved abrasion resistance. A partially hydrolyzed silane sol containing colloidal cerium oxide is ion-exchange with an anion exchange resin in one embodiment. In another a partially hydrolyzed silane sol containing colloidal silica is ion-exchanged to remove sodium ions prior to adding the colloidal ceria resulting in improved properties in the coating composition and resultant coating.
Abstract translation: 公开了一种耐磨和耐紫外线辐射的涂层，其包括通过烷氧基硅烷和/或其它金属醇盐的水解和缩合形成的无机氧化物基质，其还包含用于耐紫外线辐射的氧化铈和/或用于改善耐磨性的二氧化硅。 在一个实施方案中，含有胶体氧化铈的部分水解的硅烷溶胶与阴离子交换树脂进行离子交换。 在另一种含有胶体二氧化硅的部分水解的硅烷溶胶中，在加入胶态二氧化铈之前，将离子交换以除去钠离子，从而改善了涂料组合物和所得涂层的性能。
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公开(公告)号：US06180248B2
公开(公告)日：2001-01-30
申请号：US07799805
申请日：1991-11-29
Applicant: John D. Basil , Chia-Cheng Lin , Robert M. Hunia , Helmut Franz
Inventor： John D. Basil , Chia-Cheng Lin , Robert M. Hunia , Helmut Franz
IPC: B32B904
CPC classification number: C09D183/04 , C08F8/42 , C08J7/047 , C08J2483/00 , C08F26/10 , C08L2666/04 , C08L2666/54 , C08L2666/34
Abstract: Siloxane organic hybrid polymers and a method of making them by condensation polymerization reaction of organoalkoxysilane in the presence of organic film-forming polymers are disclosed. Alkali metal carboxylic acid catalyst is also disclosed, as well as the incorporation of cerium oxide for attenuation of ultraviolet radiation.
Abstract translation: 公开了硅氧烷有机杂化聚合物及其在有机成膜聚合物存在下通过有机烷氧基硅烷的缩聚反应制备它们的方法。 还公开了碱金属羧酸催化剂，以及掺入氧化铈以减少紫外线辐射。
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公开(公告)号：US5401579A
公开(公告)日：1995-03-28
申请号：US500642
申请日：1990-03-28
Applicant: John D. Basil , Chia-Cheng Lin , Robert M. Hunia
Inventor： John D. Basil , Chia-Cheng Lin , Robert M. Hunia
IPC: C08F8/42 , C08J7/04 , C09D183/04 , B32B27/36
CPC classification number: C09D183/04 , C08F8/42 , C08J7/047 , C08J2483/00 , Y10T428/31507 , Y10T428/31663 , Y10T428/31667
Abstract: Siloxane organic hybrid polymers and a method of making them by condensation polymerization reaction of organoalkoxysilane in the presence of organic film-forming polymers are disclosed.
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10.发明授权Glass or quartz articles having high temperature UV absorbing coatings containing ceria 失效具有包含二氧化铈的高温紫外线吸收涂层的玻璃或石英制品
公开(公告)号：US5316854A
公开(公告)日：1994-05-31
申请号：US802914
申请日：1991-12-06
Applicant: Chia-Cheng Lin , John D. Basil , Robert M. Hunia , Peter P. Bihuniak
Inventor： Chia-Cheng Lin , John D. Basil , Robert M. Hunia , Peter P. Bihuniak
IPC: C03C3/04 , C03C4/08 , C03C14/00 , C03C17/00 , C03C17/02 , C03C17/25 , C09D183/04 , G02B5/20 , B32B17/06 , B32B9/00
CPC classification number: G02B5/208 , C03C17/007 , C03C17/25 , C09D183/04 , C03C2217/23 , C03C2217/45 , C03C2217/475 , C03C2217/74 , C03C2218/113 , Y10T428/12993 , Y10T428/256 , Y10T428/265 , Y10T428/31612 , Y10T428/31663
Abstract: An ultraviolet radiation absorbing coating comprising cerium oxide in an inorganic oxide matrix formed by the hydrolysis and condensation of alkoxysilane and/or other metal alkoxide or oxide which has a higher absorbance per unit thickness of coating by virtue of its much higher concentration of colloidal particles in said matrix and a reduced tendency to craze when exposed to temperatures in excess of 1000.degree. C. and/or temperature cycling between ambient temperature and 1000.degree. C. by virtue of heating a coated article at elevated temperature between 500.degree. C. and 1100.degree. C. before cooling the coated article.
Abstract translation: 一种紫外线辐射吸收涂层，其包含通过由烷氧基硅烷和/或其它金属醇盐或氧化物的水解和缩合形成的无机氧化物基质中的氧化铈，其通过其高得多的胶体颗粒浓度具有更高的每单位厚度的涂层的吸光度 并且当暴露于超过1000℃的温度和/或环境温度和1000℃之间的温度循环时，通过在500℃和1100℃之间的升高的温度下加热涂覆的制品，降低了热轧的倾向。 C.在冷却涂层制品之前。
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