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公开(公告)号：US20140371345A1
公开(公告)日：2014-12-18
申请号：US14008832
申请日：2012-03-28
IPC分类号： C08K5/5455 , C08K13/02 , C08K3/36 , C08L7/00 , C08K3/04
摘要： A tire rubber composition based on at least one diene elastomer, an inorganic filler as reinforcing filler, a coupling agent providing the bonding between the inorganic filler and the diene elastomer, wherein the coupling agent is an azosilane compound of formula (I): (G1)3-a(G2)aSi—Z—NH—C(O)—N═N—C(O)—NH—Z—Si(G1)3-a(G2)a (I) wherein: G1, identical to or different, each represent a monovalent hydrocarbon group chosen from branched or unbranched, substituted or unsubstituted alkyls having from 1 to 18 carbon atoms, substituted or unsubstituted cycloalkyls or aryls having from 5 to 18 carbon atoms, G2, identical to or different, each represent a hydroxyl group or a monovalent group chosen from branched or unbranched, substituted or unsubstituted alkoxyls having from 1 to 18 carbon atoms, substituted or unsubstituted cycloalkoxyls having from 5 to 18 carbon atoms, Z represents a divalent linking group having from 1 to 18 carbon atoms, a is equal to 1, 2 or 3.
摘要翻译： 一种基于至少一种二烯弹性体，无机填料作为增强填料的轮胎橡胶组合物，提供无机填料和二烯弹性体之间的结合的偶联剂，其中偶联剂是式（I）的偶氮硅烷化合物：（G1 ）3-a（G2）aSi-Z-NH-C（O）-N = N-C（O）-NH-Z-Si（G1）3-a（G2）a（I）其中：G1， 各自表示选自具有1至18个碳原子的支链或非支链，取代或未取代的烷基，取代或未取代的环烷基或具有5至18个碳原子的芳基，G 2，各自相同或不同的一价烃基 表示选自具有1至18个碳原子的支链或非支链，取代或未取代烷氧基的羟基或一价基团，具有5至18个碳原子的取代或未取代的环烷氧基，Z表示具有1至18个碳原子的二价连接基团 原子a等于1,2或3。
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公开(公告)号：US09624358B2
公开(公告)日：2017-04-18
申请号：US14008620
申请日：2012-03-28
IPC分类号： C08K3/36 , C08K5/5455 , C08L7/00 , C08L21/00 , C08F136/08
CPC分类号： C08K5/5455 , C08F136/08 , C08K3/36 , C08L7/00 , C08L21/00
摘要： The invention relates to a tire rubber composition based on at least one diene elastomer, an inorganic filler as reinforcing filler, a coupling agent providing the bonding between the inorganic filler and the diene elastomer, characterized in that the coupling agent is an azosilane compound of following formula (I): (G1)3-a(G2)aSi—Z—NH—C(O)—N═N—C(O)—NH—Z—Si(G1)3-a(G2)a (I) in which: G1, identical to or different from one another, each represent a monovalent hydrocarbon-based group chosen from branched or unbranched, substituted or unsubstituted alkyls, having from 1 to 18 carbon atoms, substituted or unsubstituted cycloalkyls or aryls, having from 5 to 18 carbon atoms, G2, identical to or different from one another, each represent a hydroxyl group or a monovalent group in the form (G3)n-OG1 in which G3 is a divalent linking group having from 1 to 18 carbon atoms and comprising one or more heteroatoms chosen from O, S, Si and N, n being a number equal to or higher than 0 and less than or equal to 18, Z represents a divalent linking group having from 1 to 18 carbon atoms, a is equal to 1, 2 or 3.
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公开(公告)号：US20140228479A1
公开(公告)日：2014-08-14
申请号：US14008620
申请日：2012-03-28
IPC分类号： C08K5/5455 , C08F136/08 , C08K3/36
CPC分类号： C08K5/5455 , C08F136/08 , C08K3/36 , C08L7/00 , C08L21/00
摘要： The invention relates to a tire rubber composition based on at least one diene elastomer, an inorganic filler as reinforcing filler, a coupling agent providing the bonding between the inorganic filler and the diene elastomer, characterized in that the coupling agent is an azosilane compound of following formula (I): (G1)3-a(G2)aSi—Z—NH—C(O)—N═N—C(O)—NH—Z—Si(G1)3-a(G2)a (I) in which: G1, identical to or different from one another, each represent a monovalent hydrocarbon-based group chosen from branched or unbranched, substituted or unsubstituted alkyls, having from 1 to 18 carbon atoms, substituted or unsubstituted cycloalkyls or aryls, having from 5 to 18 carbon atoms, G2, identical to or different from one another, each represent a hydroxyl group or a monovalent group in the form (G3)n-OG1 in which G3 is a divalent linking group having from 1 to 18 carbon atoms and comprising one or more heteroatoms chosen from O, S, Si and N, n being a number equal to or higher than 0 and less than or equal to 18, Z represents a divalent linking group having from 1 to 18 carbon atoms, a is equal to 1, 2 or 3.
摘要翻译： 本发明涉及一种基于至少一种二烯弹性体，无机填料作为增强填料的轮胎橡胶组合物，提供无机填料和二烯弹性体之间的结合的偶联剂，其特征在于偶联剂是下列的偶氮硅烷化合物 式（I）：（G1）3-a（G2）aSi-Z-NH-C（O）-N = N-C（O）-NH-Z-Si I），其中：G1彼此相同或不同，各自表示选自具有1至18个碳原子的支链或非支链，取代或未取代的烷基，取代或未取代的环烷基或芳基的单价烃基，其具有 5〜18个碳原子，相互相同或不同的G2分别表示（G3）n-OG1中的羟基或一价基团，其中G3为碳原子数为1〜18的二价连接基团 并且包含一个或多个选自O，S，Si和N的杂原子，n等于或高于 r大于0且小于或等于18，Z表示具有1至18个碳原子的二价连接基团，a等于1,2或3。
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公开(公告)号：US20120196976A1
公开(公告)日：2012-08-02
申请号：US13258560
申请日：2010-03-30
CPC分类号： B29C73/10 , B29L2030/00 , C08K5/32 , C09J7/29 , Y10T152/10882 , C08L21/00
摘要： The invention relates to the use of an adhesive composition between a vulcanized rubber part and an uncured or prevulcanized or vulcanized rubber part, based on at least one highly unsaturated elastomer chosen from the group formed by natural rubber, polyisoprene, polybutadiene, styrene-butadiene, styrene-isoprene and butadiene-isoprene copolymers and styrene-butadiene-isoprene terpolymers, an aliphatic solvent and a “curing” system comprising at least one stable aryl dinitrile oxide compound.
摘要翻译： 本发明涉及在硫化橡胶部分与未固化或预硫化或硫化的橡胶部分之间的粘合剂组合物的用途，所述粘合剂组合物基于至少一种选自天然橡胶，聚异戊二烯，聚丁二烯，苯乙烯 - 丁二烯， 苯乙烯 - 异戊二烯和丁二烯 - 异戊二烯共聚物和苯乙烯 - 丁二烯 - 异戊二烯三元共聚物，脂族溶剂和包含至少一种稳定的芳基二腈氧化物化合物的“固化”体系。
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公开(公告)号：US08232338B2
公开(公告)日：2012-07-31
申请号：US12521774
申请日：2007-12-21
IPC分类号： C08K5/098
CPC分类号： C08K3/22 , B60C1/0016 , C08K5/098 , C08L21/00
摘要： A rubber composition based on at least one diene elastomer, containing less than 2 phr of zinc, phr meaning parts per hundred parts of rubber (elastomer), and based on at least one reinforcing filler and one sulphur-based crosslinking system, comprising a zinc carboxylate of formula: (RCOO)2Zn, in which R represents a hydrocarbon group chosen from cyclic or non-cyclic, linear or branched alkyl groups having 1 to 16 carbon atoms, aryl groups, aralkyl groups or alkaryl groups having 1 to 16 carbon atoms. Also disclosed is a process for preparing such a rubber composition which is suitable for manufacturing tires or semi-finished products made of rubber intended for these tires.
摘要翻译： 基于至少一种含有少于2phr锌的二烯弹性体的橡胶组合物，phr表示每百份橡胶（弹性体）的份数，并且基于至少一种增强填料和一种硫基交联体系，其包含锌 羧酸酯，其中R表示选自具有1至16个碳原子的环状或非环状，直链或支链烷基，具有1至16个碳原子的芳基，芳烷基或烷芳基的烃基，（RCOO）2Zn 。 还公开了一种制备这种橡胶组合物的方法，该橡胶组合物适用于制造用于这些轮胎的橡胶制成的轮胎或半成品。
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公开(公告)号：US20130053504A1
公开(公告)日：2013-02-28
申请号：US13501071
申请日：2010-10-08
IPC分类号： C08L9/00
CPC分类号： C08K5/46 , B60C1/0016 , C07D277/16 , C08K5/0025 , C08K5/23 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： A rubber composition for the manufacture of tires, based on a blend of at least one diene elastomer chosen from natural rubber and synthetic polyisoprene and of one or more diene elastomers chosen from the group consisting of polybutadienes, butadiene copolymers and isoprene copolymers, on one or more reinforcing fillers and on a vulcanization system, the said vulcanization system comprising one or more thiazoline compounds of formula:
摘要翻译： 一种用于制造轮胎的橡胶组合物，其基于选自天然橡胶和合成聚异戊二烯的至少一种二烯烃弹性体的共混物和选自聚丁二烯，丁二烯共聚物和异戊二烯共聚物的一种或多种二烯弹性体， 更多的增强填料，并且在硫化体系上，所述硫化体系包含一种或多种下式的噻唑啉化合物：
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公开(公告)号：US09145494B2
公开(公告)日：2015-09-29
申请号：US13496148
申请日：2010-09-13
CPC分类号： C08L21/00 , B60C1/0016 , C08K5/07 , C08L61/06 , Y02T10/862 , C08L2666/16
摘要： A rubber composition which can be used in particular in tires, based on at least one diene elastomer, one reinforcing filler, one crosslinking system, one phenolic resin and one polyaldehyde. The use of a polyaldehyde makes it possible to advantageously replace conventional methylene donors while preventing the production of formaldehyde during the vulcanization of the rubber compositions and thus to limit the environmental impact of these compounds. Furthermore, these polyaldehyde compounds make it possible not only to obtain rubber compositions exhibiting the same low-strain stiffness as conventional rubber compositions using HMT or H3M methylene donors but also, surprisingly, to greatly improve the fatigue strength of the rubber compositions and thus the endurance of the tires.
摘要翻译： 基于至少一种二烯弹性体，一种增强填料，一种交联体系，一种酚醛树脂和一种多醛，可特别用于轮胎的橡胶组合物。 使用聚醛可以有利地代替常规的亚甲基供体，同时防止在橡胶组合物硫化期间产生甲醛，从而限制这些化合物的环境影响。 此外，这些多醛化合物使得不仅可以获得表现出与使用HMT或H3M亚甲基供体的常规橡胶组合物相同的低应变刚度的橡胶组合物，而且令人惊奇的是，大大提高橡胶组合物的疲劳强度，从而耐久性 的轮胎。
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公开(公告)号：US09034969B2
公开(公告)日：2015-05-19
申请号：US13501071
申请日：2010-10-08
CPC分类号： C08K5/46 , B60C1/0016 , C07D277/16 , C08K5/0025 , C08K5/23 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： A rubber composition for the manufacture of tires, based on a blend of at least one diene elastomer chosen from natural rubber and synthetic polyisoprene and of one or more diene elastomers chosen from the group consisting of polybutadienes, butadiene copolymers and isoprene copolymers, on one or more reinforcing fillers and on a vulcanization system, the said vulcanization system comprising one or more thiazoline compounds of formula:
摘要翻译： 一种用于制造轮胎的橡胶组合物，其基于选自天然橡胶和合成聚异戊二烯的至少一种二烯弹性体和一种或多种选自聚丁二烯，丁二烯共聚物和异戊二烯共聚物的二烯弹性体的共混物， 更多的增强填料，并且在硫化体系上，所述硫化体系包含一种或多种下式的噻唑啉化合物：
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公开(公告)号：US20130085223A1
公开(公告)日：2013-04-04
申请号：US13501093
申请日：2010-10-08
IPC分类号： C07D277/36 , C08L7/00
CPC分类号： C07D277/36 , B60C1/00 , B60C1/0016 , C08K3/04 , C08K3/36 , C08K5/0025 , C08K5/47 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： A rubber composition for the manufacture of tires, based on one or more diene elastomers, on one or more reinforcing fillers and on a vulcanization system, the vulcanization system comprising one or more thiazole compounds of formula:
摘要翻译： 一种用于制造基于一种或多种二烯弹性体在一种或多种增强填料和硫化体系上的轮胎的橡胶组合物，所述硫化体系包含一种或多种下式的噻唑化合物：
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公开(公告)号：US20100317795A1
公开(公告)日：2010-12-16
申请号：US12521774
申请日：2007-12-21
CPC分类号： C08K3/22 , B60C1/0016 , C08K5/098 , C08L21/00
摘要： A rubber composition based on at least one diene elastomer, containing less than 2 phr of zinc, phr meaning parts per hundred parts of rubber (elastomer), and based on at least one reinforcing filler and one sulphur-based crosslinking system, comprising a zinc carboxylate of formula: (RCOO)2Zn, in which R represents a hydrocarbon group chosen from cyclic or non-cyclic, linear or branched alkyl groups having 1 to 16 carbon atoms, aryl groups, aralkyl groups or alkaryl groups having 1 to 16 carbon atoms. Also disclosed is a process for preparing such a rubber composition which is suitable for manufacturing tires or semi-finished products made of rubber intended for these tires.
摘要翻译： 基于至少一种含有少于2phr锌的二烯弹性体的橡胶组合物，phr表示每百份橡胶（弹性体）的份数，并且基于至少一种增强填料和一种硫基交联体系，其包含锌 羧酸酯，其中R表示选自具有1至16个碳原子的环状或非环状，直链或支链烷基，具有1至16个碳原子的芳基，芳烷基或烷芳基的烃基，（RCOO）2Zn 。 还公开了一种制备这种橡胶组合物的方法，该橡胶组合物适用于制造用于这些轮胎的橡胶制成的轮胎或半成品。
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