New triazolopyrimidines and their use as initiators
    4.
    发明授权
    New triazolopyrimidines and their use as initiators 失效
    新的三唑并嘧啶及其作为引发剂的用途

    公开(公告)号:US4871850A

    公开(公告)日:1989-10-03

    申请号:US141875

    申请日:1988-01-06

    摘要: Triazolopyrimidines of the formula I ##STR1## in which R.sup.1 denotes CN, alkylsulphonyl, arylsulphonyl or arylR.sup.2 denotes H, alkyl or alkythio,R.sup.3 denotes alkyl, aralkyl, substituted aralkyl, alkenyl or alkynyl,R.sup.4 denotes alkyl, aralkyl or aryl, andR.sup.5 denotes alkyl, aralkyl or aryl, orR.sup.4 and R.sup.5, together with the carbon atom, denote a carbocyclic 5-, 6- or 7-membered ring which may be substituted or bridged,in which R.sup.4 cannot be methyl or aryl when R.sup.1 represents CN, R.sup.2 represents H, R.sup.3 represents methyl and R.sup.5 represents methyl or aryl, and in which alkyl preferably has 1-9 C atoms and aryl preferably has 6-12 C atoms, and also a process for their preparation, and their use as initiators.

    摘要翻译: 式I的三唑并嘧啶其中R1表示CN,烷基磺酰基,芳基磺酰基或芳基R2表示H,烷基或链烯基,R3表示烷基,芳烷基,取代的芳烷基,烯基或炔基,R4表示烷基,芳烷基或芳基, R 5表示烷基,芳烷基或芳基,或者R 4和R 5与碳原子一起表示可以被取代或桥连的碳环5-,6-或7-元环,当R 1不为甲基或芳基时,R 1表示 CN,R 2表示H,R 3表示甲基,R 5表示甲基或芳基,并且其中烷基优选具有1-9个C原子,并且芳基优选具有6-12个C原子,并且其制备方法及其作为引发剂的用途 。

    Process for the preparation of carbonic acid esters of polyester-polyols
    6.
    发明授权
    Process for the preparation of carbonic acid esters of polyester-polyols 失效
    聚酯多元醇碳酸酯的制备方法

    公开(公告)号:US4191705A

    公开(公告)日:1980-03-04

    申请号:US845174

    申请日:1977-10-25

    CPC分类号: C08G63/64 C08G63/916

    摘要: The present invention relates to a process for the preparation of carbonic acid esters of polyester-polyols by transesterifying the polyols with carbonic acid aryl esters at elevated temperatures under vacuum in the presence of a catalyst. The reaction conditions are controlled to avoid the formation of by-products and the chain extension of the polyester-polyols. The present invention is also concerned with the polyester carbonic acid esters so formed, their use in producing polycarbonate block copolymers and the copolymers so produced. The copolymers may be produced by transesterifying the polyester carbonic acid esters with bisphenols and subjecting the bis-hydroxyaryl carbonates so formed to normal polycarbonate synthesis such as interfacial or melt polycondensation.

    摘要翻译: 本发明涉及一种通过在催化剂存在下在真空下在升高的温度下将多元醇与碳酸芳酯酯交换而制备聚酯多元醇的碳酸酯的方法。 控制反应条件以避免副产物的形成和聚酯多元醇的链延长。 本发明还涉及如此形成的聚酯碳酸酯,它们在生产聚碳酸酯嵌段共聚物中的用途以及如此制备的共聚物。 共聚物可以通过将聚酯碳酸酯与双酚酯交换并使如此形成的双羟基芳基碳酸酯进行正常的聚碳酸酯合成如界面或熔融缩聚来制备。

    Process for the production of graft polymers
    9.
    发明授权
    Process for the production of graft polymers 失效
    生产接枝聚合物的方法

    公开(公告)号:US4426499A

    公开(公告)日:1984-01-17

    申请号:US344486

    申请日:1982-02-01

    CPC分类号: C08F265/04 C08F279/02

    摘要: This invention relates to a process for the graft polymerization of (A) from 95 to 40 parts, by weight, of at least one ethylenically unsaturated monomer in the presence of (B) from 5 to 60 parts, by weight, of a partially or completely cross-linked rubber, in which the one or more than one monomer (A) and rubber (B) in the form of a latex or of a dispersion in an organic solvent are polymerized in an aliphatic hydrocarbon as reaction medium at from 30.degree. to 100.degree. C., using a radical forming initiator, and the graft polymerization product obtained as a sedimenting suspension of particles having an average diameter of from 5 to 1,000 .mu.m is isolated.

    摘要翻译: 本发明涉及一种在(B)5〜60重量份的(B)的部分或不饱和单体的存在下(A)95重量份至40重量份的至少一种烯属不饱和单体的接枝聚合方法 完全交联的橡胶,其中一种或多种胶乳形式的单体(A)和橡胶(B)或在有机溶剂中的分散体在脂肪族烃中作为反应介质在30℃下聚合 至100℃,使用自由基形成引发剂,分离得到作为平均直径为5〜1000μm的颗粒的沉降悬浮液得到的接枝聚合产物。