Chromium free treatment before coating metal surfaces
    1.
    发明授权
    Chromium free treatment before coating metal surfaces 失效
    镀金属表面之前无铬处理

    公开(公告)号:US5026440A

    公开(公告)日:1991-06-25

    申请号:US398108

    申请日:1989-08-24

    摘要: The adhesion of, and corrosion protection provided by, organic surface coatings to underlying metal can be significantly improved if the degreased, etched, and pickled metal surfaces to be coated are first treated with an aqueous solution and/or dispersion of aluminum-zirconium complexes, which are obtainable as the reaction-product of a chelated aluminum component, an organo-functional ligand component, and a zirconium oxyhalide component, with the organo-functional ligand being chemically bonded to the chelated aluminum unit and the zirconium unit in the complex, and are subsequently treated with dilute aqueous solutions, emulsions, and/or dispersions of one or more inorganic and/or organic film-forming materials prior to coating the surfaces with conventional organic surface coatings.

    摘要翻译: 如果要涂覆的脱脂,蚀刻和酸洗的金属表面首先用铝 - 锆络合物的水溶液和/或分散体进行处理,则可以显着改善有机表面涂层对底层金属提供的粘合性和腐蚀保护性, 其可以作为螯合铝组分,有机官能配体组分和卤氧化锆组分的反应产物获得,有机官能配体与络合物中的螯合铝单元和锆单元化学键合,以及 在用常规有机表面涂层涂覆表面之前,用一种或多种无机和/或有机成膜材料的稀水溶液,乳液和/或分散体进行处理。

    Short duration hot seal for anodized metal surfaces
    2.
    发明授权
    Short duration hot seal for anodized metal surfaces 失效
    阳极氧化金属表面短时间热封

    公开(公告)号:US5935656A

    公开(公告)日:1999-08-10

    申请号:US51856

    申请日:1998-04-20

    IPC分类号: C25D11/24 B05D7/14

    CPC分类号: C25D11/246

    摘要: A process for sealing anodized metal surfaces is characterized by bringing the anodized metal into contact with an aqueous solution at a temperature from 75.degree. C. to the boiling point of the solution for a time equal to from 0.5 to 2 minutes per micrometer of anodized layer thickness. The solution contains: a) from 0.0001 to 5 g/l of one or more alkali metal and/or alkaline earth metal ions and b) from 0.0005 to 0.5 g/l of one or more organic acids selected from: polycarboxylic acids with from 3 to 6 carboxyl groups; phosphonic acids; and/or polyphosphinocarboxylic acids, the solution containing a greater amount of metal ions of group a) than is needed to insure complete neutralization of the acids of group b).

    摘要翻译: PCT No.PCT / EP96 / 04373 Sec。 371日期:1998年4月20日 102(e)1998年4月20日PCT PCT 1996年10月9日PCT公布。 出版物WO97 / 14828 日期1997年04月24日阳极氧化金属表面的密封方法的特征在于使阳极氧化金属与水溶液在75℃至沸点的溶液中接触0.5秒至2分钟 每微米阳极氧化层厚度。 溶液含有:a)0.0001至5g / l的一种或多种碱金属和/或碱土金属离子,和b)0.0005至0.5g / l的一种或多种选自以下的有机酸:多羧酸与3 至6个羧基; 膦酸; 和/或多聚磷酸羧酸,该溶液含有更多量的组a.3的金属离子,以确保完全中和组b)的酸。

    Chromium-free process for improving paint adhesion after thin-layer
anodization
    3.
    发明授权
    Chromium-free process for improving paint adhesion after thin-layer anodization 失效
    无铬工艺,用于改善薄层阳极氧化后的油漆附着力

    公开(公告)号:US5961809A

    公开(公告)日:1999-10-05

    申请号:US913179

    申请日:1997-09-08

    摘要: A process for improving the adherence of paint applied after thin-film anodization is characterized in that the anodized metal surfaces are brought into contact with an aqueous solution containing one or more of the following components: (a) 200 to 2000 ppm of a homopolymer or copolymer of acrylic acid, methacrylic acid, and/or their esters; (b) 200 to 3000 ppm of a poly(vinyl phenol) compound in which at part of the phenol rings carry an alkylamino substituent; (c) 200 to 3000 ppm of hexafluorotitanic acid, hexafluorozirconic acid, and/or their anions.

    摘要翻译: PCT No.PCT / EP96 / 00829 Sec。 371日期:1997年9月8日 102(e)1997年9月8日PCT PCT 1996年2月29日PCT公布。 WO96 / 27698 PCT出版物 日期1996年9月12日提高在薄膜阳极氧化后施加的涂料粘附性的方法的特征在于阳极氧化金属表面与含有一种或多种以下组分的水溶液接触:(a)200至2000 ppm的丙烯酸,甲基丙烯酸和/或它们的酯的均聚物或共聚物; (b)200-3000ppm的一部分苯酚环带有烷基氨基取代基的聚(乙烯基苯酚)化合物; (c)200-3000ppm的六氟钛酸,六氟锆酸和/或它们的阴离子。

    Method of compacting anodized metals with lithium and
fluoride-containing solutions without using heavy metals
    4.
    发明授权
    Method of compacting anodized metals with lithium and fluoride-containing solutions without using heavy metals 失效
    用不含重金属的含锂和氟化物溶液压制阳极氧化金属的方法

    公开(公告)号:US5891269A

    公开(公告)日:1999-04-06

    申请号:US983130

    申请日:1998-01-07

    IPC分类号: C25D11/18

    CPC分类号: C25D11/18

    摘要: A process for sealing anodized metals without using any heavy metals comprises a first step in which the anodized metal is contacted for a period of between 3 and 30 minutes (for an anodized layer thickness of 20 .mu.m) with an aqueous solution which has a temperature from 15.degree. to 35.degree. C. and a pH between 5.0 and 6.5 and contains from 0.1 to 3 g/l of lithium ions and from 0.1 to 5 g/l of fluoride ions and a second step in which the anodized metal is contacted for a period from 5 to 30 minutes (for an anodized layer thickness of 20 .mu.m) with water or an aqueous solution of substances which prevent the formation of a sealing coating, the solution having a pH from 5.5 to 8.5 and a temperature from 80.degree. to 100.degree. C.

    摘要翻译: PCT No.PCT / EP96 / 02848 Sec。 371日期:1998年1月7日 102(e)1998年1月7日PCT PCT 1996年6月29日PCT公布。 出版物WO97 / 03232 日期1997年1月30日一种不使用任何重金属来密封阳极氧化金属的方法包括第一步骤,其中阳极氧化金属接触时间为3至30分钟(阳极氧化层厚度为20μm) 溶液,其温度为15℃至35℃,pH为5.0至6.5,并含有0.1至3克/升的锂离子和0.1至5克/升的氟离子,第二步骤 阳极氧化金属与水或防止形成密封涂层的物质的水溶液接触5至30分钟(阳极氧化层厚度为20μm),溶液的pH为5.5至8.5, 温度从80℃到100℃

    Fluid, cold-stable, two-component washing compositions and method of
washing textiles
    6.
    发明授权
    Fluid, cold-stable, two-component washing compositions and method of washing textiles 失效
    流体,冷稳定的双组分洗涤组合物和洗涤纺织品的方法

    公开(公告)号:US4288225A

    公开(公告)日:1981-09-08

    申请号:US174560

    申请日:1980-08-04

    摘要: A fluid, two-component washing agent consisting of two components A and B, of which component A is an aqueous dispersion of fatty acids and component B is an alkaline solution, wherein component A is a cold-stable aqueous dispersion consisting essentially of:(a) from 15% to 35% by weight of substantially unsaturated fatty acids, mainly oleic acid,(b) from 2% to 6% by weight of potassium hydroxide and from 2% to 6% by weight of triethanolamine, where the total amount is so selected that at least 50% by weight of the fatty acids are present as potassium and triethanolamine soaps,(c) from 4% to 10% by weight of an ethoxylated primary alcohol having 5 to 12 oxyethylene units,(d) from 4% to 10% by weight of sodium C.sub.10-14 -alkylbenzenesulfonate,(e) from 0.05% to 1% by weight of at least one optical brightener,(f) from 5% to 15% by weight of at least one C.sub.1-3 -alcohol, and(g) from 35% to 50% by weight of water, and wherein component B is an alkaline solution containing alkaline potassium compounds.The two components are combined in a ratio of A to B of 2:1 to 1:4 in the wash solution using water with a hardness degree of less than 10.degree. dH (German hardness), where the total content of wash-active components is from 2 to 8 gm/liter and the goods:liquor ratio is 1:4 to 1:8 and the washing process is carried out in a known manner.

    摘要翻译: 由两种组分A和B组成的流体双组分洗涤剂,其中组分A是脂肪酸和组分B的水分散体是碱性溶液,其中组分A是基本上由以下组成的冷稳定水性分散体:( a)15重量%至35重量%的基本不饱和脂肪酸,主要是油酸,(b)2重量%至6重量%的氢氧化钾和2重量%至6重量%的三乙醇胺,其中总量 选择为至少50重量%的脂肪酸​​作为钾和三乙醇胺皂,(c)4重量%至10重量%的具有5至12个氧化乙烯单元的乙氧基化伯醇,(d)4 %至10重量%的C 10-14烷基苯磺酸钠,(e)0.05重量%至1重量%的至少一种荧光增白剂,(f)5重量%至15重量%的至少一种C1-3 (g)35〜50重量%的水,其中B成分为含有碱性钾的碱性溶液 化合物。 使用硬度小于10°dH(德国硬度)的水,洗涤液中两种组分的A与B的比例为2:1至1:4,其中洗涤活性组分 为2至8克/升,商品:液比为1:4至1:8,洗涤过程以已知方式进行。

    Nickel-free phosphating process
    7.
    发明授权
    Nickel-free phosphating process 失效
    无镍磷化工艺

    公开(公告)号:US5792283A

    公开(公告)日:1998-08-11

    申请号:US612925

    申请日:1996-03-06

    摘要: A process for phosphating surfaces of steel, galvanized or alloy-galvanized steel, aluminum, aluminized or alloy-aluminized steel. The process is particularly useful for treating metal surfaces which are to be cathodic electrocoated. The process uses a nickel, cobalt, copper, nitrite and oxo-anion of halogen free phosphating solution containing 0.3 to 2.0 g/l Zn(II), 0.3 to 4 g/l Mn(II), 5 to 40 g/l phosphate ions and at least one of 0.5 to 5 g/l hydroxylamine and 0.2 to 2 g/l m-nitrobenzene sulfonate wherein the ratio by weight of Zn(II) to Mn(II) is not greater than 2.

    摘要翻译: PCT No.PCT / EP94 / 02848 Sec。 371日期1996年3月6日 102(e)1996年3月6日PCT PCT 1994年8月29日PCT公布。 公开号WO95 / 07370 日期1995年3月16日钢,镀锌或合金镀锌钢,铝,镀铝或合金镀铝钢表面磷化处理。 该方法对于处理要被阴极电涂覆的金属表面特别有用。 该方法使用含0.3〜2.0g / l Zn(II),0.3〜4g / l Mn(II),5〜40g / l磷酸盐的无卤磷酸盐溶液的镍,钴,铜,亚硝酸盐和氧阴离子 离子和0.5至5g / l羟胺和0.2至2g / l间硝基苯磺酸盐中的至少一种,其中Zn(II)与Mn(II)的重量比不大于2。

    Composition and process for activating metal surfaces prior to zinc
phosphating and process for making said composition
    9.
    发明授权
    Composition and process for activating metal surfaces prior to zinc phosphating and process for making said composition 失效
    在锌磷化之前活化金属表面的组合物和方法以及用于制备所述组合物的方法

    公开(公告)号:US4957568A

    公开(公告)日:1990-09-18

    申请号:US345063

    申请日:1989-04-28

    IPC分类号: C01B25/38 C01B25/40 C23C22/80

    CPC分类号: C01B25/40 C23C22/80

    摘要: Activation of metal surfaces prior to phosphating can be improved by using aqueous dispersions of polymeric titanium(IV) phosphates in which at least 95% by weight of the polymeric particles have a particle diameter of less than 200 nm. This low particle diameter is attained by adding a titanium(IV)-complexing agent before or during an otherwise conventional reaction between a titanium(IV) compound, acid or phosphate, and water. The complexing agent is used in an amount of less than the stoichiometric amount, based on the titanium(IV) content. The best complexing agents are poly(aldehydocarboxylic acids), 1,1-diphosphonic acids, and/or the alkali metal salts of these types of acids.

    摘要翻译: 通过使用其中至少95重量%的聚合物颗粒具有小于200nm的聚合物的聚合钛(IV)磷酸盐的水分散体,可以改善在磷化之前激活金属表面。 通过在钛(IV)化合物,酸或磷酸盐和水之间的常规反应之前或期间加入钛(IV)络合剂来实现该低的粒径。 基于钛(IV)含量,络合剂的用量小于化学计量量。 最好的络合剂是这些类型的酸的聚(醛脱羧酸),1,1-二膦酸和/或碱金属盐。