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公开(公告)号:US20160137765A1
公开(公告)日:2016-05-19
申请号:US14901334
申请日:2014-06-18
IPC分类号: C08F216/14 , D06M15/356 , D06M15/277 , C11D7/30
CPC分类号: C08F216/1408 , C08F220/22 , C08G77/14 , C08G77/20 , C09D183/10 , C11D7/30 , D06M15/277 , D06M15/3568 , C08F220/30 , C08F2220/1891 , C08F230/08 , C08F220/34 , C08F222/06
摘要: A fluorine-containing polymer having (a) a repeating unit derived from a fluorine-containing monomer indicated by the formula CH2═C(—X)—C(═O)—Y—Z—Rf, (b) a repeating unit derived from a cyclic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH2═CQ11-C(═O)—O-Q12, and (c) a repeating unit derived from an aliphatic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH2═CQ21-C(═O)—O-Q22. The fluorine-containing polymer is produced by polymerizing in the presence of one or both of (d) a silicon-containing monomer and a silicon-containing chain transfer agent.
摘要翻译: 具有(a)由式CH 2 = C(-X)-C(= O)-Y-Z-Rf表示的含氟单体的重复单元的含氟聚合物,(b)衍生自 由式CH2 = CQ11-C(ΟO)-O-Q12表示的含环烃基的丙烯酸酯单体和(c)衍生自含脂肪族烃基的丙烯酸酯单体的重复单元 由式CH2 = CQ21-C(ΟO)-O-Q22表示。 含氟聚合物通过在(d)含硅单体和含硅链转移剂中的一种或两种的存在下聚合来制备。
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公开(公告)号:US20200299441A1
公开(公告)日:2020-09-24
申请号:US16084681
申请日:2017-03-15
发明人: Rumi KAWABE , Masaki FUKUMORI , Ryosuke HARA , Masahiro MIYAHARA , Shinichi MINAMI , Ikuo YAMAMOTO , Yasuhiro MITTA , Akifumi MITAKE
IPC分类号: C08F220/18 , C08F220/20 , C08F236/20 , C08F214/06 , C08F214/08 , C08F265/04 , C08F2/38 , C08L33/08 , D06M15/248 , D06M15/263
摘要: Provided is a surface treatment agent which does not use fluorine-containing monomers, particularly fluoroalkyl group-containing monomers. Additionally, provided is a copolymer which includes a first polymer formed from first monomers, and a second polymer formed from second monomers. The copolymer does not include fluorine. The second polymer is polymerized in the presence of the first polymer. The first monomers include a long-chain acrylate ester monomer (a) represented by the formula CH2=CA11-C(═O)—O-A12 (in the formula, A11 represents hydrogen, a monovalent organic group, or a halogen, and A12 represents a C18-30 straight-chain or branched hydrocarbon group). The first monomers and the second monomers both include a halogenated olefin monomer (b).
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公开(公告)号:US20200055970A1
公开(公告)日:2020-02-20
申请号:US16345984
申请日:2017-10-31
发明人: Shinichi MINAMI , Masaki FUKUMORI , Takashi ENOMOTO , Takuya YOSHIOKA , Ikuo YAMAMOTO , Bin ZHOU , Min ZHU
IPC分类号: C08F214/18 , C08F220/18 , D06M15/256
摘要: Provided is a fluorinated polymer that can impart excellent washing durability and water- and oil-repellency to fibers, said fluorinated polymer having a repeating unit derived from a fluorinated monomer (a) that comprises a first fluorinated monomer (a1) represented by the formula: CH2═C(—X1)—C(═O)—Y1—Z1—Rf1 [wherein X1 represents a halogen atom; Y1 represents —O— or —NH—; Z1 represents a direct bond or a bivalent organic group; and Rf1 represents a fluoroalkyl group having 1 to 20 carbon atoms] and a second fluorinated monomer (a2) represented by the formula: CH2═C(—X2)—C(═O)—Y2—Z2—Rf2 [wherein X2 represents a monovalent organic group or a hydrogen atom; Y2 represents —O— or —NH—; Z2 represents a direct bond or a bivalent organic group; and Rf2 represents a fluoroalkyl group having 1 to 20 carbon atoms].
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公开(公告)号:US20210032493A1
公开(公告)日:2021-02-04
申请号:US17075944
申请日:2020-10-21
发明人: Masato IOKI , Masahiro MIYAHARA , Tetsuya UEHARA , Yuuki YAMAMOTO , Masaki FUKUMORI , Masahiro HIMURO
IPC分类号: C09D133/16 , C08F220/22 , C09D5/00 , C09D7/20 , D06M15/256 , D06M15/277
摘要: A water- and oil-repellent agent including: (a) a fluorine-containing monomer represented by the general formula CH2═C(—X)—C(═O)—Y—Z—Rf [where X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or13 NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1-20 carbon atoms]; and (b) a fluorine-containing copolymer containing a repeating unit derived from nonyl(meth)acrylate. Also disclosed is a textile product including a fibrous substrate treated with the water- and oil-repellent agent.
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公开(公告)号:US20190352237A1
公开(公告)日:2019-11-21
申请号:US16528425
申请日:2019-07-31
发明人: Kanako TAKAHASHI , Masaki FUKUMORI , Ikuo YAMAMOTO
IPC分类号: C04B41/48 , C08F220/22 , C09K3/18 , C08F220/28 , C04B41/63 , C04B24/26 , C04B41/00 , C08F220/24
摘要: Provided is a masonry treatment composition containing a fluorine-containing polymer, which contains, as essential components, a fluorine-containing monomer having a fluoroalkyl group represented by the formula (a) CH2═C(—X)—C(═O)—Y—Z—Rf, a first hydrophilic monomer represented by formula (b) CH2═CX11C(═O)—O—RO—X12, a second hydrophilic monomer represented by formula (c) CH2═CX21C(═O)—O—(RO)n—X22 or CH2═CX31C(═O)—O—(RO)n—C(═O)CX32═CH2, and (d) repeating units derived from a monomer having an anion donor and an ethylenic unsaturated double bond. Provided is a treatment composition which can impart outstanding water repellency, oil repellency and anti-fouling properties to a masonry substrate.
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公开(公告)号:US20240060233A1
公开(公告)日:2024-02-22
申请号:US18267668
申请日:2022-01-14
IPC分类号: D06M15/27 , D06M15/267 , D06M15/71
CPC分类号: D06M15/27 , D06M15/267 , D06M15/71 , D06M2101/32
摘要: A system and method for applying a polymer surface treatment to carpets and other textiles is provided. The system and method include the use of a surfactant-free emulsion of a surface treatment polymer. The use of the surfactant-free emulsion of a surface treatment polymer reduces or eliminates the need to use pH adjusting agents and/or ionic salt solutions when applying surface treatment polymers to carpets or other textiles. By reducing the need to remove surfactants, emulsifiers, pH adjusting agents, and/or salts, the total volume of water used in treating carpets or other textiles is reduced.
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公开(公告)号:US20190077984A1
公开(公告)日:2019-03-14
申请号:US16085157
申请日:2017-03-15
发明人: Rumi KAWABE , Masaki FUKUMORI , Ryosuke HARA , Masahiro MIYAHARA , Shinichi MINAMI , Ikuo YAMAMOTO
IPC分类号: C09D151/06 , D06M15/248 , D06M15/263 , D06M13/165
摘要: Provided is a surface treatment agent which does not use fluorine-containing monomers, particularly fluoroalkyl group-containing monomers. The surface treatment agent is a water-based emulsion which includes: a copolymer (1) which includes a first polymer formed from first monomers, and a second polymer formed from second monomers, wherein the second polymer is polymerized in the presence of the first polymer, the first monomers include a long-chain acrylate ester monomer (a) represented by the formula CH2═CA11-C(═O)—O-A12 (in the formula, A11 represents hydrogen, a monovalent organic group, or a halogen, and A12 represents a C18-30 straight-chain or branched hydrocarbon group), the first monomers do not include a halogenated olefin monomer (b), and the second monomers include the halogenated olefin monomer (b); a surfactant (2) including a nonionic surfactant; and a liquid medium (3) including water.
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公开(公告)号:US20180038044A1
公开(公告)日:2018-02-08
申请号:US15662437
申请日:2017-07-28
发明人: Shinichi MINAMI , Masaki FUKUMORI , Takashi ENOMOTO , Ikuo YAMAMOTO , Min ZHU
IPC分类号: D06M15/277 , D01F6/32 , D01F6/16 , D06M15/267
CPC分类号: D06M15/277 , D01F6/16 , D01F6/32 , D06M15/244 , D06M15/248 , D06M15/263 , D06M15/267 , D06M15/295 , D06M2101/06 , D06M2101/22 , D06M2101/32 , D06M2200/01 , D06M2200/10 , D06M2200/11 , D06M2200/12
摘要: Disclosed is a nonwoven fabric formed from (i) a nonwoven fabric substrate and (ii) a fluorine-containing polymer adhering to the nonwoven fabric substrate, wherein the fluorine-containing polymer contains:(a) repeating units formed from a fluorine-containing monomer which is alpha-chloro acrylate or alpha-chloro acrylamide containing a fluoroalkyl group, and (b) repeating units formed from a halogenated olefin monomer, and the fluorine-containing polymer is free from repeating units formed from a (meth)acrylate containing a linear or branched hydrocarbon group having at least 18 carbon atoms.
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公开(公告)号:US20170197888A1
公开(公告)日:2017-07-13
申请号:US15313594
申请日:2015-05-21
发明人: Kanako TAKAHASHI , Masaki FUKUMORI , Ikuo YAMAMOTO
CPC分类号: C04B41/4842 , C04B24/2688 , C04B41/009 , C04B41/48 , C04B41/63 , C04B2103/0051 , C04B2103/60 , C04B2103/65 , C04B2111/203 , C04B2111/27 , C08F220/22 , C08F220/24 , C08F220/28 , C09K3/18
摘要: Provided is a masonry treatment composition containing a fluorine-containing polymer, which contains, as essential components, a fluorine-containing monomer having a fluoroalkyl group represented by the formula (a) CH2═C(—X)—C(═O)—Y—Z—Rf, a first hydrophilic monomer represented by formula (b) CH2═CX11C(═O)—O—RO—X12, a second hydrophilic monomer represented by formula (c) CH2═CX21C(═O)—O—(RO)n—X22 or CH2═CX31C(═O)—O—(RO)n—C(═O)CX32═CH2, and (d) repeating units derived from a monomer having an anion donor and an ethylenic unsaturated double bond. Provided is a treatment composition which can impart outstanding water repellency, oil repellency and anti-fouling properties to a masonry substrate.
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