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公开(公告)号:US20220410094A1
公开(公告)日:2022-12-29
申请号:US17778072
申请日:2020-11-20
发明人: Bizhong ZHU , Stanley YEE , Matthew HILDNER , Jeffrey PLOTT , Albert SHIH
IPC分类号: B01F25/4314 , B01F25/432 , B01F25/431 , B01F35/92 , B33Y30/00 , B33Y40/00 , B29C64/314 , B29B7/32 , B29B7/72
摘要: A static mixer is disclosed. The static mixer comprises a housing (22) defining an internal mixing cavity (36) that longitudinally extends along a central axis between an inlet (38) and an outlet (40) and is adapted for axial flow of a fluid therethrough. The static mixer also comprises a mixing element (42) disposed within the mixing cavity (36). The mixing element (42) is configured to be free from an impingement surface oriented substantially perpendicular to a main direction of fluid flow through the internal mixing cavity (36). The mixing element (42) comprises an elongated mixing blade that is oriented longitudinally within the mixing cavity (36) and comprises a nose axially oriented toward the inlet (38). The static mixer may comprise a heat-exchanging jacket integrally formed with the housing (22). An additive manufacturing system comprising the static mixer, and methods of making and using the same, are also disclosed.
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公开(公告)号:US20210129443A1
公开(公告)日:2021-05-06
申请号:US17053498
申请日:2019-05-10
发明人: Jeffrey PLOTT , Albert J. SHIH , Bizhong ZHU
IPC分类号: B29C64/393 , B29C64/118 , B29C64/245 , B33Y10/00 , B33Y50/02 , B33Y80/00
摘要: A method of forming a three-dimensional (3D) article is disclosed. The method comprises (I) printing a first composition (14) on a deformable substrate (18) at a volumetric flow rate with a 3D printer to forma deformable first filament (16) comprising the first composition on the deformable substrate. The method further comprises (II) controlling the volumetric flow rate to reduce a deformation force applied by a nozzle (12) of the 3D printer to the deformable substrate (18) and give a first layer comprising the deformable first filament (16) on the deformable substrate. In the method, (I) and (II) may optionally be repeated with independently selected composition(s) to form any additional deformable filament(s) and corresponding layer(s). Finally, the method comprises (III) exposing the layer(s) to a solidification condition. A 3D article formed in accordance with the method is also disclosed.
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公开(公告)号:US20200047404A1
公开(公告)日:2020-02-13
申请号:US16499005
申请日:2018-03-30
发明人: Jeffrey PLOTT , Herschel Henry REESE , Albert J. SHIH , Xiaoqing TIAN , Hongjun WANG , Bizhong ZHU
IPC分类号: B29C64/118 , B33Y10/00
摘要: A method of forming a porous three-dimensional (3D) is disclosed. The method comprises (I) printing a first composition on a substrate (16) with the nozzle (12) of the apparatus (10) to form at least one first filament (14) comprising the first composition, (II) selectively controlling the distance and/or the speed such that the at least one first filament coils on the substrate to give a first layer on the substrate, the first layer comprising a coiled filament, optionally repeating steps I) and II) with independently selected composition(s) for any additional layer(s), and (III) exposing the layer(s) to a solidification condition. A porous three-dimensional (3D) article formed in accordance with the method is also disclosed.
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公开(公告)号:US20200324464A1
公开(公告)日:2020-10-15
申请号:US16498985
申请日:2018-03-30
发明人: Herschel Henry REESE , Bizhong ZHU
IPC分类号: B29C64/124
摘要: A method of forming a porous three-dimensional (3D) silicone article is disclosed. The method comprises I) printing a first composition with a 3D printer to form a first layer from the first composition. The method further comprises II) printing a second composition on the first layer with the 3D printer to form a second layer from the second composition on the first layer. At least one of the first and second compositions comprises a silicone composition. In the method, step II) may optionally be repeated with independently selected composition(s) for any additional layer(s). At least one of the first and second layers does not consist of linear filaments. Finally, the method comprises III) exposing the layers to a solidification condition. The porous three-dimensional (3D) silicone article defines a plurality of voids.
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公开(公告)号:US20190106593A1
公开(公告)日:2019-04-11
申请号:US16159268
申请日:2018-10-12
发明人: James Andrew KENNEY , Bizhong ZHU
IPC分类号: C09D183/04 , B33Y70/00 , C09D183/08 , C08G77/04 , C08G77/08 , B33Y10/00 , B29C64/106 , C08G77/28 , C08L83/04 , C08L83/08 , B33Y80/00 , C08K3/36 , C08G77/20 , C08G77/12 , C08G77/00 , B29K83/00
摘要: A method of forming a three-dimensional (3D) article comprises the steps of I) printing a first photocurable silicone composition with a 3D printer to form a layer, II) irradiating the layer with an energy source to form an at least partially cured layer, III) printing a second photocurable silicone composition on the at least partially cured layer with the 3D printer to form a subsequent layer, and IV) irradiating the subsequent layer with the energy source to form an at least partially cured subsequent layer. Optionally, steps III) and IV) can be repeated with independently selected photocurable silicone compositions for any additional layer(s) to form the 3D article. The first and second photocurable silicone compositions are the same as or different from one another. Various photocurable silicone compositions can be utilized for the inventive method, including the inventive photocurable silicone compositions described herein.
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公开(公告)号:US20220411587A1
公开(公告)日:2022-12-29
申请号:US17764700
申请日:2020-09-24
发明人: Bizhong ZHU , Kaila M. MATTSON
IPC分类号: C08G77/04
摘要: A networked silicone is disclosed. The networked silicone comprises crosslinked strands of hindered organosilicon compounds. A composition for preparing the networked silicone is also disclosed, and comprises (A) a hindered organosilicon compound, (B) a crosslinking compound, and optionally (C) a catalyst. Additionally, a method of preparing the networked silicone is disclosed, and comprises reacting the hindered organosilicon compound (A) and the crosslinking compound (B), optionally in the presence of the catalyst (C), to give the networked silicone. A reaction product comprising the networked silicone is also disclosed. The reaction product is prepared from the composition and/or in accordance with the method, and may be a cured product. Additionally, a composite article and a method of forming the same are disclosed. The composite article is formed by disposing a networked silicone composition on the substrate and curing the networked silicone composition, thereby preparing the composite article.
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公开(公告)号:US20220267535A1
公开(公告)日:2022-08-25
申请号:US17743343
申请日:2022-05-12
发明人: Martin GRASMANN , David HAGAN , Brian HARKNESS , William H. HEATH , Stephen Michael HLINKA, II , Eric JOFFRE , William JOHNSON , Bindu KRISHNAN , Jeanette YOUNG , Bizhong ZHU
摘要: A silicone-polyether copolymer has the formula (X-D2)g-Y, where each X is an independently selected silicone moiety having a particular structure, D2 is a divalent hydrocarbon group, subscript g is greater than 1, and Y is a linear or branched polyether moiety. A method of preparing the silicone-polyether copolymer comprising reacting a polyether compound and an organosilicon compound in the presence of a hydrosilylation-reaction catalyst. A sealant is also disclosed, the sealant comprising the silicone-polyether copolymer and a condensation-reaction catalyst.
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公开(公告)号:US20210317311A1
公开(公告)日:2021-10-14
申请号:US17272108
申请日:2019-08-28
发明人: Jon V. DEGROOT, JR. , Eun Sil JANG , Eric JOFFRE , Bizhong ZHU
IPC分类号: C08L83/04 , C09D11/30 , C09D11/102 , B33Y10/00 , B33Y70/00 , B29C64/112
摘要: A composition for forming a silicone elastomer is disclosed. The composition comprises: A) a linear organopolysiloxane having at least two silicon-bonded ethylenically unsaturated groups per molecule; B) a linear organohydrogensiloxane having at least two silicon-bonded hydrogen atoms per molecule; C) at least one cross-linker; and D) a hydrosilylation catalyst. The cross-linker C) is selected from the group consisting of: C1) an organopolysiloxane having at least three silicon-bonded ethylenically unsaturated groups per molecule; and C2) an organopolysiloxane having at least three silicon-bonded hydrogen atoms per molecule. At least one of the silicon-bonded ethylenically unsaturated groups of component C1) has a lower reactivity relative to the silicon-bonded ethylenically unsaturated groups of component A). Moreover, at least one of the silicon-bonded hydrogen atoms of component C2) has a lower reactivity relative to the silicon-bonded hydrogen atoms of component B). Methods of forming three-dimensional (3D) articles utilizing the compositions are also disclosed.
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公开(公告)号:US20200131368A1
公开(公告)日:2020-04-30
申请号:US16626385
申请日:2018-06-26
发明人: Martin GRASMANN , David HAGAN , Brian HARKNESS , William H. HEATH , Stephen Michael HLINKA, II , Eric JOFFRE , William JOHNSON , Bindu KRISHNAN , Qiuyun XU , Bizhong ZHU
摘要: An isocyanate-functional silicone-polyether copolymer having a particular structure is disclosed. A method of preparing the isocyanate-functional silicone-polyether copolymer is also disclosed, the method comprising reacting a polyether compound and an organosilicon compound to give the isocyanate-functional silicone-polyether copolymer. A silicone-polyether-urethane copolymer formed therewith, as well as a method of preparing the silicone-polyether-urethane copolymer, are also disclosed. Sealants comprising the isocyanate-functional silicone-polyether copolymer and/or the silicone-polyether-urethane copolymer are further disclosed.
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公开(公告)号:US20220064482A1
公开(公告)日:2022-03-03
申请号:US17416475
申请日:2019-12-16
发明人: Emmanuel DUQUESNE , Michael S. FERRITO , Martin GRASMANN , Brian HARKNESS , William JOHNSON , Bindu KRISHNAN , Elizabeth SANTOS , Justin SCHERZER , Jeanette YOUNG , Bizhong ZHU
IPC分类号: C09D183/10 , C08G77/445 , C08G77/448 , C08G77/442
摘要: A silicone-organic copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyacrylate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0
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